Gas-diffusion layer's structural anisotropy induced localized instability of nafion membrane in polymer electrolyte fuel cell

The design of robust polymer electrolyte fuel cell requires a thorough understanding of the materials' response of the cell components to the operational conditions such as temperature and hydration. As the electrolyte membrane's mechanical properties are temperature, hydration and rate dependent, its response under cyclic loading is of significant importance to predict the damage onset and thus the membrane lifetime. This article reports on the variation in stress levels in the membrane induced due to the gas-diffusion layer's (GDL) anisotropic mechanical properties while accurately capturing the membrane's mechanical response under time dependent hygrothermomechanical conditions. An observation is made on the evolution of negative strain in the membrane under the bipolar plate channel area, which is an indication of membrane thinning, and the magnitude of this strain found to depend upon the GDL's in-plane mechanical properties. In order to come up with a strategy that reduces the magnitude of tensile stresses evolved in the membrane during the hygrothermal unloading and to increase the membrane's lifetime, we numerically show that by employing a fast hygrothermal loading rate and unloading rate strategy, significant reduction (in this study, nearly 100%) in the magnitude of tensile stresses is achievable. The present study assists in understanding the relation between materials compatibility and durability of fuel cell components.     

Investigation of the Reduction/Oxidation Behavior of Cobalt Supported on Nano-ceria

The oxidation and reduction behavior of cobalt catalysts supported on nano-ceria (5–8 nm) was investigated under hydrogen, oxygen and water atmospheres. A novel quantitative isothermal reduction (QIR) technique was introduced to analyze the kinetics and activation barrier of Co reduction. CoO to Co reduction was found to be of first order in the 250–350 °C temperature range. Temperature programmed reduction and oxidation experiments were conducted and the Kissinger method was used to obtain apparent activation energies for reduction and oxidation with O₂. The apparent activation energy for CoO reduction was found to agree with that obtained from the QIR technique. Re-oxidation of Co metal was found to have a slightly lower activation energy barrier than the reduction. The reduction and oxidation behavior was further investigated with in situ XANES where the reaction order for reduction was observed to change at 450 °C. The pre-reduced samples were seen to re-oxidize under a water atmosphere, where the oxidation followed first order kinetics. Re-oxidation by water yielded a higher activation energy when compared to re-oxidation under oxygen.     

Mechanistic investigation and selectivity of the grafting onto C60 of macroradicals prepared by cobalt-mediated radical polymerization

The grafting mechanism of poly(vinyl acetate) macroradicals prepared by cobalt-mediated radical polymerization onto C₆₀ is investigated. The experimental conditions directly impact the nature and stability of the PVAc/C₆₀ adducts. In the presence of residual initiating radicals that can compete with PVAc° macroradicals for addition onto C₆₀, mixtures of PVAc/C₆₀ adducts having between one and eight polymer chains per C₆₀ are formed. PVAc/C₆₀ adducts prepared with low [PVAc]:[C₆₀] ratios may contain weak C₆₀–C₆₀ bonds that further dissociate and account for the instability of the products. The formation of such dimers can be lessened by increasing the temperature from 30 °C to 100 °C. The temperature increase also allows a complete dissociation of the PVAc-Co dormant species into PVAc° macroradicals and an almost quantitative grafting of eight PVAc chains onto C₆₀, leading to well-defined C₆₀(PVAc)₈ octa-adducts. These results might shed new light on the grafting onto C₆₀ of macroradicals prepared by other CRP techniques.     

PLLA/Flax Mat/Balsa Bio-Sandwich—Environmental Impact and Simplified Life Cycle Analysis

In the present paper the environmental impact of biocomposites and bio-sandwich materials production are evaluated, using simplified Life Cycle Analysis (LCA) following the procedure recommended in the ISO 14044 standard. The materials are dimensioned and evaluated by comparing with reference materials, glass mat reinforced unsatured polyester and glass mat/unsatured polyester/balsa sandwich. The results indicate that bio-sandwich materials are very attractive in terms environmental impact. However further improvements in biocomposite and bio-sandwich mechanical strength are necessary if they are to be used in transport application compared to glass/polyester and glass/polyester/balsa sandwich.     

A priori checking inconsistencies among strategic constraints for assembly plan generation

This paper is related to the field of assembly plan generation. It describes a new approach to a priori check the consistency of an assembly strategy that is given by the assembly system designers before running an assembly plan generation algorithm. The aim of this work is to improve the assembly plan designer’s efficiency by reducing the research space while proving the existence of acceptable solutions. The assembly strategy combined with the product’s model implies a set of constraints on the assembly processes. The proposed method determines whether the given assembly strategy produces possible assembly processes. In case of inconsistencies among the strategic constraints, the method will help the designer to identify the contradictory constraints. The set of constraints can be expressed by a Boolean equation. First we present the key concepts and models related to the product, processes, and added values in the field of assembly plan generation. Second we define existing strategic constraints, and propose three new ones and a classification of strategic assembly constraints. The originality of the proposed method consists in defining an elementary strategic constraint that is used to describe every other constraint. The proposed method leads to model an assembly strategy by a single Boolean equation that is used to check the inconsistencies. An industrial case study is provided to highlight and to demonstrate the interests of this approach.     

Vision-based arm gesture recognition for a long-range human–robot interaction

This paper proposes a vision-based human arm gesture recognition method for human–robot interaction, particularly at a long distance where speech information is not available. We define four meaningful arm gestures for a long-range interaction. The proposed method is capable of recognizing the defined gestures only with 320×240 pixel-sized low-resolution input images captured from a single camera at a long distance, approximately five meters from the camera. In addition, the system differentiates the target gestures from the users’ normal actions that occur in daily life without any constraints. For human detection at a long distance, the proposed approach combines results from mean-shift color tracking, short- and long-range face detection, and omega shape detection. The system then detects arm blocks using a background subtraction method with a background updating module and recognizes the target gestures based on information about the region, periodical motion, and shape of the arm blocks. From experiments using a large realistic database, a recognition rate of 97.235% is achieved, which is a sufficiently practical level for various pervasive and ubiquitous applications based on human gestures.