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91.
An electrochemical method for the determination of azinphos-methyl and parathion-methyl in honey is presented. The determination is established by adsorptive stripping differential pulse voltammetry at hanging mercury working electrode.In contrast to the chromatographic methods for the determination of pesticide residues, the sample preparation of the proposed method is minimal; analytes were extracted from honey samples with a mixture of (acetone):(Britton-Robinson buffer) and then were analyzed without any additional pretreatment.The response of the analytes either individually or as a mixture was studied for a series of deposition time and molar ratio. Two quantitation protocols were compared, using either the external calibration or the standard addition method. Accuracy was tested with spiked honey samples obtaining good recovery values. The limit of detection for the honey sample (for deposition time of 10 s) was calculated 51.71 μg kg−1 for MeP and 65.87 μg kg−1 for AzMet. 相似文献
92.
Anthony Walker Matthew Driller Christos Argus Julie Cooke Ben Rattray 《Ergonomics》2014,57(4):612-621
Currently, there is no enforcement of physical standards within Australian fire services post-recruitment, possibly leading to inappropriate fitness and body composition. This study evaluated the impacts of ageing on physical standards of Australian firefighters. Seventy-three firefighters from three different 10-year age groups [25–34 years (n = 27), 35–44 years (n = 27), 45–54 years (n = 19)] volunteered for physical testing using dual-energy X-ray analysis and existing fitness tests used for recruitment by an Australian fire service. Older (45–54 years) participants demonstrated significantly poorer physical standards compared with younger participants including cardiovascular fitness (p < 0.05), strength (p = 0.001) and simulated operational power testing tasks (p < 0.001). Age-related body composition changes were also observed independent of body mass index. Minimum recruitment standards and fitness programs need to account for age-related declines in physical capabilities to ensure that the minimum standard is maintained regardless of age.
Practitioner Summary: Using dual-energy X-ray analysis and established fitness testing protocols, this study aimed to gain an appreciation of the current standards of body composition and fitness of Australian firefighters and the effects of ageing on their physical abilities post-recruitment. The study demonstrated a significant decline in physical standards due to age. 相似文献
93.
Christos S. Christoforou Lynn G. Salmon Glen R. Cass 《Aerosol science and technology》2013,47(6):530-544
Air exchange between interior spaces and the outdoor atmosphere can occur due to a variety of processes, including wind-driven flows and natural convectiondriven flows. As air is exchanged with the outdoors, airborne particles can be brought inside. Depending on the use of the indoor space, the presence of particles in indoor air could be a nuisance to the occupants or could be damaging to materials kept indoors. While one obvious solution to such problems is to install a mechanical air filtration system, that is not always practical. In particular, the character of some historical houses and some archaeological sites would be degraded by the presence of a mechanical air distribution system, and in some parts of the world the reliable electrical power supply needed for such a filtration system may not be available. In the present paper we consider principles for the design of passive filtration systems in which air motion through the filter material is induced by a natural convection flow rather than by a mechanical fan. A fluid mechanical model first is described for predicting the air flow through an interior space that acts as a thermal siphon. The effect of placing filter material in the path of such air flows is examined next. The indoor-outdoor air quality model of Nazaroff and Cass (1989a) is matched to the natural convection air exchange model, and calculations are performed to determine the relationship between the outdoor particle size distribution and indoor particle size distributions and particle deposition rates given a passive filtration system. Example calculations are worked for the case of a passive particle filtration system that could be installed to protect the interior of the Buddhist cave temples at Yungang, China. These are a collection of manmade cave temples dating from the 5th century AD, now situated in the middle of one of China's largest coal-mining regions with its accompanying air pollution problems. 相似文献
94.
Stefan Schafföner Jens Fruhstorfer Susann Ludwig Christos G. Aneziris 《Ceramics International》2018,44(8):9027-9036
This study investigated the cold isostatic pressing of coarse grained alumina refractories applying either a cyclic pressure increase or a cycling at maximum pressure. Additionally the effects of the maximum pressure and the particle size distribution on physical, mechanical and thermomechanical properties were analyzed. The cyclic pressure increase resulted in a slightly higher apparent density and lower apparent porosity. A cycling at maximum pressure decreased the median pore size to some extent. Remarkably, an optimized particle size distribution resulted in a lower apparent porosity, lower median pore size and in a higher Young's modulus before and after thermal shock together with a slightly lower relative decrease of the Young's modulus. A higher pressing pressure which decreased the apparent porosity did not affect the Young's modulus. Thus, apparently the optimized particle size distribution improved the particle packing which was associated with a smaller median pore size. This smaller pore size increased the number of pores relative to the total porosity, which then acted as points of crack initiation and crack deflection limiting the length of propagating cracks in case of thermal shock. Thus, tailoring the pore size distribution is a promising starting point to improve the thermomechanical properties of refractories. 相似文献
95.
The investigation of phase transformations in metastable ceramic systems such as zirconia often requires local phase analysis within the areas of interest. Electron backscatter diffraction is a suitable method in combination with focused ion beam sample preparation. The interaction between ion beam and sample has to be carefully considered. In case of metastable Y-PSZ and Mg-PSZ, phase transformations were observed after FIB preparation with 30?kV, 30?nA and 5° incidence angle. Damage was the dominating effect for angles of 72°. The expected local temperature increase due to the ion bombardment with 30?kV and 30?nA is 700?K for ZrO2. Thus, the observed phase transformations can be explained on the basis of the temperature increase in the corresponding Y-PSZ phase diagram. In case of Mg-PSZ, the transition temperature is 1083?°C. The local temperature increase was obviously lower. The excitation energy for the observed phase transformation was smaller than expected from the phase diagrams of the thermodynamic equilibrium. Using 5?kV, 4.8?nA and 5° incidence angle, no phase transformations and no damage were observed. Thus, these conditions are well suited for the FIB preparation of metastable zirconia. 相似文献
96.
Quality changes of cuttlefish stored under various atmosphere modifications and vacuum packaging 下载免费PDF全文
97.
George D. Panagiotou Manolis D. Tzirakis John Vakros Loukia Loukatzikou Michael Orfanopoulos Christos Kordulis Alexis Lycourghiotis 《Applied Catalysis A: General》2010,372(1):16-25
Simple or successive incipient wetness impregnation followed by heating at 180 °C is proved an efficient preparation method for dispersing effectively onto the silica surface various amounts of C60 in the range 1–4% (w/w). BET, XRD, DRS, TGA, microelectrophoresis and photoluminescence have been used to characterize the photocatalysts prepared. A high dispersion was obtained for the quite stable supported C60 phase, comprised mainly from relatively small or medium size C60 clusters/aggregates. The photocatalytic activity was assessed in the singlet oxygen oxidation of alkenes by examining the photo-oxygenation of 2-methyl-2-heptene as a probe reaction. The catalytic tests were carried out at 0–5 °C in CH3CN, under oxygen atmosphere and using a 300 W xenon lamp as the light source. The heterogeneous catalysts obtained were proved to be active in the photocatalytic oxidation of olefins via a 1O2 ene reaction. The catalysts exhibited significant conversion, turnover number and turnover frequency values, substantially higher than those achieved over the unsupported C60. The conversion increases with the amount of the supported C60 up to a value equal to 3% (w/w) and then it decreases whereas turnover number and turnover frequency decreases monotonically as the amount of the supported C60 increases. The easy separation of these solid catalysts from the reaction mixture, the high activity and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis of fine chemicals. 相似文献
98.
Vasileios Alevizakos Christos Koukouvinos 《Quality and Reliability Engineering International》2020,36(1):88-111
The zero-inflated Poisson (ZIP) distribution is an extension of the ordinary Poisson distribution and is used to model count data with an excessive number of zeros. In ZIP models, it is assumed that random shocks occur with probability p, and upon the occurrence of random shock, the number of nonconformities in a product follows the Poisson distribution with parameter λ. In this article, we study in more detail the exponentially weighted moving average control chart based on the ZIP distribution (regarded as ZIP-EWMA) and we also propose a double EWMA chart with an upper time-varying control limit to monitor ZIP processes (regarded as ZIP-DEWMA chart). The two charts are studied to detect upward shifts not only in each parameter individually but also in both parameters simultaneously. The steady-state performance and the performance with estimated parameters are also investigated. The performance of the two charts has been evaluated in terms of the average and standard deviation of the run length, and compared with Shewhart-type and CUSUM schemes for ZIP distribution, it is shown that the proposed chart is very effective especially in detecting shifts in p when λ remains in control (IC) and in both parameters simultaneously. Finally, one real example is given to display the application of the ZIP charts on practitioners. 相似文献
99.
Horst Biermann Ulrich Martin Christos G. Aneziris Anja Kolbe Angelika Müller Wolfgang Schärfl Mathias Herrmann 《Advanced Engineering Materials》2009,11(12):1000-1006
Novel composites on basis of austenitic stainless TRIP‐steel as matrix with reinforcements of Mg‐PSZ are presented. Compact rods were produced by cold isostatic pressing and sintering, square honeycomb samples by the ceramic extrusion technique. The samples are characterized by optical and scanning electron microscopy before and after deformation, showing the microstructure and the deformation‐ induced martensite formation. The mechanical properties of samples with 5 vol% zirconia are superior compared to zirconia‐free samples and composites with higher zirconia contents in terms of bending and compression tests. The honeycomb samples exhibit extraordinary high specific energy absorption in compression. 相似文献
100.
Harry Berek Uta Ballaschk Christos G. Aneziris 《Advanced Engineering Materials》2011,13(12):1101-1107
An experimental setup for in situ investigations under compressive stress using laboratory X‐ray computed tomography (XCT) was developed and successfully tested. Complete deformation curves can be taken. It could be shown that XCT scans are possible during brakes of the stopped in situ experiments. In this way the deformation behavior of defined sample regions can be investigated. This kind of experiments is well suited to investigate the deformation behavior of foams and other samples which are transferable for the X‐rays used. The compression of metal matrix composite foams lead to the cooperative collapse of connected cells. We observed deformation bands arising in regions of smaller cell wall thicknesses. The deformation was dependent on size, shape, and orientation of the cells under consideration. Obviously deformation bands start at bigger cells with a small cell wall thickness and some extension perpendicular to the deformation direction. The rising of this kind of deformation bands can be explained by the dramatic change of the stress distribution in the neighbor cells after the first brake of a cell wall. 相似文献