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101.
苯乙烯与1-(2-叔丁基过氧异丙基)-3-异丙烯基苯(D120)能进行自由基共聚合反应,聚合后过氧基团以侧基的形成被保留在共聚物大分子链上,凝胶色谱分析发现,随原料单体中D120比例增加,共聚物的分子量减小,分子量分布变窄,DSC分析发现共聚物中过氧基团的分解温度随D120结构单元含量的增加而下降,但仍高于D120单体过氧基团的分解温度,苯乙烯与D120的竞聚率为:rD120=0.700,rSt=0.714。 相似文献
102.
We consider a special growth-curve (SGC) model with a known steering matrix and generalized waveform in the presence of unknown interference and noise. Several estimators of the complex amplitude based on this model are derived, including the methods of approximate maximum likelihood (AML), minimum variance distortionless response (MVDR), and amplitude and phase estimation (APES). We analyze the statistical properties of these estimators and show that in the presence of temporally white but spatially correlated noise and interference, AML is asymptotically statistically efficient for a large snapshot number while MVDR and APES are asymptotically equivalent but not statistically efficient. Via several numerical examples, we also show that when the noise and interference are both spatially and temporally correlated, the APES estimator can achieve better estimation accuracy and exhibit greater robustness than the other methods. 相似文献
103.
Lin-Ping Shen Wei-Ping Huang Shui-Sheng Jian 《Lightwave Technology, Journal of》2003,21(7):1644-1651
A general procedure for design of photonic crystal fibers (PCFs) with desirable dispersion properties is presented. The design model is based on the combination of a rigorous vector mode solver and a scaling transformation for the dispersion properties of the PCFs. In comparison with the conventional design method, the new design procedure is more efficient and can be readily automated for the purpose of design optimization. Several applications of the design procedure, e.g., the design optimization for dispersion shifted fibers, dispersion flattened fibers, and dispersion compensation fibers, are demonstrated and discussed. 相似文献
104.
Orthogonal space-time block codes: maximum likelihood detection for unknown channels and unstructured interferences 总被引:3,自引:0,他引:3
Space-time coding (STC) schemes for communication systems employing multiple transmit and receive antennas have been attracting increased attention. The so-called orthogonal space-time block codes (OSTBCs) have been of particular interest due to their good performance and low decoding complexity. In this paper, we take a systematic maximum-likelihood (ML) approach to the decoding of OSTBC for unknown propagation channels and unknown noise and interference conditions. We derive a low-complexity ML decoding algorithm based on cyclic minimization and assisted by a minimum amount of training data. Furthermore, we discuss the design of optimal training sequences and optimal information transfer to an outer decoder. Numerical examples demonstrate the performance of our algorithm. 相似文献
105.
Ultraviolet (UV) disinfection is becoming increasingly popular as an alternative disinfection technology to chlorination in recent years. In this study, we investigated the photoreactivation of Escherichia coli following medium-pressure (MP) UV disinfection of synthetic water by a bench-scale collimated beam apparatus. The UV doses ranged from 1.6 -19.7 mWs/cm2 and photoreactivation was investigated for 6 hours under fluorescent light. In addition, chloramination was applied after UV disinfection to investigate its ability to control photoreactivation. It was found that photoreactivation occurred for all UV doses tested and the increase in bacteria numbers ranged from 0.04 to 1.35 log10. However, the degree of photoreactivation decreased with increased UV doses. Chloramination experiments revealed that the addition of 0.5 mg/l of monochloramine resulted in suppression of photoreactivation for 1 hour only. An increased monochloramine dose of 1 mg/l was found to prevent photoreactivation for the entire duration of the experiment. The results of this study have shown that photoreactivation occurs even after MP UV disinfection, although it is of a lesser extent at higher UV doses. This study has also established that secondary chloramination can effectively suppress and eliminate photoreactivation with a chloramine dose of 1 mg/l. 相似文献
106.
T. H. Chang K. F. Pao S. H. Chen K. R. Chu 《Journal of Infrared, Millimeter and Terahertz Waves》2003,24(9):1415-1420
Self-consistent effects on the starting current of gyrotron oscillators are examined. Field profiles in the open cavity are shown to be sensitive to the interaction dynamics. This can either significantly raise or lower the oscillation threshold, particularly for the low-Q modes. The transition from resonant-mode oscillations at the low magnetic field to backward-wave oscillations at the high magnetic field is demonstrated. 相似文献
107.
In this paper, we report on a novel family of monodisperse thermo‐sensitive core–shell hydrogel microspheres that is featured with high monodispersity and positively thermo‐responsive volume phase transition characteristics with tunable swelling kinetics, i.e., the particle swelling is induced by an increase rather than a decrease in temperature. The microspheres were fabricated in a three‐step process. In the first step, monodisperse poly(acrylamide‐co‐styrene) seeds were prepared by emulsifier‐free emulsion polymerization. In the second step, poly(acrylamide) or poly[acrylamide‐co‐(butyl methacrylate)] shells were fabricated on the microsphere seeds by free radical polymerization. In the third step, the core–shell microspheres with poly‐ (acrylamide)/poly(acrylic acid) based interpenetrating polymer network (IPN) shells were finished by a method of sequential IPN synthesis. The proposed monodisperse core–shell microspheres provide a new mode of the phase transition behavior for thermo‐sensitive “smart” or “intelligent” monodisperse micro‐actuators that is highly attractive for targeting drug delivery systems, chemical separations, sensors, and so on. 相似文献
108.
109.
W. Chen S. -H. Wang R. Chu F. King T. R. Jack R. R. Fessler 《Metallurgical and Materials Transactions A》2003,34(11):2601-2608
A study was carried out to understand the effect of precyclic loading on stress-corrosion-crack initiation in an X-65 pipeline
steel exposed to a near-neutral-pH soil environment. The test specimens were precyclically loaded before corrosion exposure
to represent a service history of up to about 20 years, depending on the severity of pressure fluctuation. Microcracks had
initiated on the polished surface of the X-65 pipeline steel after long-time exposure at open-circuit potential (OCP) in a
near-neutral-pH synthetic soil solution. These microcracks were mostly initiated from pits at metallurgical discontinuities
such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed
along planes of the banded structures in the steel. The selective corrosion attack at these metallurgical discontinuities
is attributed to the galvanic nature of those areas to their neighbors. Cyclic loading prior to corrosion exposure had significant
effects on microcrack initiation and propagation during subsequent corrosion exposure. Cyclic loading prior to corrosion exposure
either reduced or increased the probability of crack initiation and the rate of crack propagation, depending upon the magnitude
of the stress cycles. The largest reduction was seen at a peak cyclic stress of about 0.8 of the yield strength. This cyclic-loading-dependent
cracking behavior might be related to the alteration of the substructures and the residual stress in the steel as a result
of precyclic loading. 相似文献
110.
介绍了一个基于Windows操作系统的数据采集软件,该软件用于使用重心法确定的位置信息的位置灵敏探测器,具有方便的人机交互界面,使用专用驱动程序采集数据。 相似文献