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Zusammenfassung In grünem (Taiwan Gunpowder) und schwarzem (Ceylon high OP) Tee sind beträchtliche Mengen an Aromastoffen in glykosidischer Bindung vorhanden; ihr Anteil ist sogar höher als der an freien Aromastoffen. Hauptkomponenten sind in beiden Teesorten cis-3-Hexen-1-ol, Benzylalkohol und 2-Phenylethanol in gebundener Form, dazu im Schwarztee Linalool und im grünen Tee Geraniol. Die unterschiedlichen Anteile dieser beiden Terpenalkohole spiegeln die unterschiedlichen Tee-Varietäten wieder, denen die untersuchten Teesorten angehören: der Ceylon-Tee ist der Varietätassamica zuzuordnen, der Tee aus Taiwan der Varietätsinensis. Die Zusammensetzung der aus gebundenen Formen freisetzbaren Aromastoffe war ähnlich komplex wie die der freien Aromastoffe, wobei die Unterschiede zwischen den beiden Teesorten auf den verschiedenen Herstellungsverfahren beruhen. Das Auftreten gebundener Formen solcher Aromastoffe, die nicht originär vorhanden sind, sondern erst während der Welk- oder der Fermentationsphase gebildet werden, impliziert das Vorhandensein glykosidierender Aktivitäten im Teeblatt noch in relativ späten Stadien der Schwarzteeherstellung. Die Untersuchung der gebundenen Anteile an Aromastoffen trägt neben der Analyse der freien Aromastoffe wesentlich zum Verständnis der Reaktionen im Teeblatt wahrend der verschiedenen Produktionsstadien bei.
Bound flavour compounds in plants 2. Part. Free and bound flavour compounds in green and black tea
Summary Green and black tea contains considerable amounts of flavour compounds which are present in glycosidic bonds, their portion being even higher than that of free flavour compounds. The main components in both of these tea varieties are 3-hexene-1-ol, benzylalcohol and 2-phenylethanol, which are present in the bound forms, and additionally linalool in black tea and geraniol in green tea. The different amounts of these terpene alcohols reflect the different varieties the teas under investigation belong to: the Ceylon tea belongs to the variety assamica, and the Taiwan tea to the variety sinensis. The composition of the flavour compounds liberated from bound forms had a similar complexity to that of the free flavour compounds, the difference being based upon the different production procedures. The occurrence of bound forms of such components that are not originally present but are produced during the withering or fermentation stage implies that glycosidating activities are still present in the tea leaf, even in a relatively late stage of the black tea production process. The investigation of the bound parts of flavour compounds delivers a valuable contribution to a better understanding of the reactions occurring in the tea leaf during the different stages of tea production.


Auszug aus der Dissertation von N. Fischer, Technische Universitat München 1986

1. Mitteilung Chem Mikrobiol Technol Lebensm 9:87 (1985)  相似文献   
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For an assessment of the risk potential of existing structures, where in the case of prestressing steel damage the load-bearing capacity could be significantly affected, non-destructive testing techniques which enable reliable evaluation of the condition of the prestressing steels are of utmost importance. During the demolition of a post-tensioned concrete bridge in Berlin where damage of prestressing wires due to hydrogen-induced stress corrosion cracking were found in former investigations, parts of the girders of the bridge superstructure could be taken out. After non-destructive investigations by means of two testing techniques based on magnetic leakage flux measurement and one technique based on electromagnetic resonance measurement, subsequent removal of the concrete cover up to the ducts, opening the ducts and evaluation of the prestressing steels allowed a verification of the results obtained by the NDT methods. From the results it can be concluded that areas with fractures of several wires can be detected by the two techniques based on magnetic leakage flux measurement.  相似文献   
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This study investigated the Stages of Change Readiness and Treatment Eagerness Scale (SOCRATES: W. R. Miller & J. S. Tonigan, 1996) in adolescents presenting for treatment of alcohol use disorder (AUD). The participants were 80 males and 43 females (mean age=16.8 years) who presented for AUD treatment (95.1% outpatient, 4.9% inpatient). Participants completed assessments at baseline and 1 year and provided information on alcohol use and related variables monthly between these 2 assessments. Principal-components and confirmatory factor analyses of the baseline SOCRATES identified 2 factors, Taking Steps and Recognition, which showed good internal consistency and concurrent and predictive evidence of validity. The results were interpreted as supporting the use of the SOCRATES with clinical samples of adolescents. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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In this paper, we summarize our recent efforts to analyze transmission probabilities of extremely thin SiO2 gate oxides using microscopic models of Si[100]-SiO2-Si[100] heterojunctions. We predict energy-dependent tunneling masses and their influence on transmission coefficients, discuss tunneling probabilities and analyze effects arising from the violation of parallel momentum conservation. As an application of the present method, gate currents in short bulk MOSFETs are calculated, including elastic defect-assisted contributions.  相似文献   
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The parasitic bipolar transistor inherent in the power vertical Double Diffused MOSFET (DMOSFET) structure can have a significant impact on its performance and reliability. Selectively formed TiSi2 films on source contacts were used to reduce the contact resistance to n + source diffusion. These devices exhibit “kinks” in the output I-V characteristics. High contact resistance of TiSi2 to moderately doped p-body diffusion causes high output conductance. Detailed two-dimensional numerical simulations are used to investigate the effect of the parasitic bipolar transistor on the static characteristics of scaled silicided DMOSFET's. The high contact resistance of TiSi2-p-body interface leads to a floating potential and causes significant reduction in the MOS gate threshold voltage and results in a premature bipolar turn-on. It is shown that the parasitic bipolar turn-on places an important constraint on the scalability of the device into the submicron regime. A novel self-aligned DMOSFET structure with a shallow diffused p+ region is shown to eliminate this effect. Numerical simulations are shown to be in excellent agreement with the measured data at various temperatures  相似文献   
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The purpose of this study was to determine the etiologic factors of denture stomatitis. Fifteen subjects with clinical evidence of localized simple denture stomatitis, fifteen subjects without clinical signs of denture stomatitis, and forty-five subjects with clinical evidence of generalized simple denture stomatitis were investigated clinically and mycologically. Subjects were evaluated according to age, sex, duration of denture usage, smoking habits, frequency of denture brushing, overnight denture wearing, pH level of saliva and degree of candidal colonization and candidal formation. Salivary samples and swabs were taken from the palate and the mucosal surfaces of the dentures investigated mycologically in order to identify the yeast colonies. Smears were taken from the palate and investigated in order to identify candidal formation. No statistically significant relationship was found between denture stomatitis and age, sex, duration of denture usage, frequency of denture brushing, overnight denture wearing or pH level of saliva. There was however, a statistically significant relationship between denture stomatitis and denture hygiene, smoking habits, candidal colonization and candidal formation.  相似文献   
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A test designed to separate those undergoing thoracic surgery without complications and those with complications must be both highly specific and sensitive. Clearly, the difference between patients at opposite ends of the population curves is easy to identify. Spirometry can be helpful for screening, although it is not a very discriminating test. If patients fall in the overlap region between the populations, however, it is impossible to discern the risks with any certainty using low-yield tests. A test with higher sensitivity, specificity, and predictive values is necessary to ascertain such marginal differences. With this kind of analysis at hand, preoperative testing can be divided into three predictive value groups. Calculating the predictive value of each preoperative test can provide a comparative measure of usefulness of discriminative power (Table 1). In this way, spirometry, blood gas analysis, and stair climbing tolerance are shown to be poor predictors of outcome. An intermediate predictive value can be achieved using diffusion capacity, exercise-induced decreases in O2 saturation, and exercise PVR. High predictive value can be accomplished with combination indexes (PPP, possibly PRQ), measurement of VO2 at 40 watts of exercise, or VO2max. Logic dictates a step-wise preoperative evaluation using prediction value analysis (Fig.4). A flow decision chart for the preoperative evaluation of patients for pulmonary resection begins with exercise oximetry, spirometry, and blood gas analysis as general screening tests to separate those patients at minimal or no risks for complications from those patients that require further evaluation. Functional indexes (PPP, PRQ) or exercise testing can aid further in the selection of those patients in whom a nonsurgical option should be considered. Flow decision chart for the preoperative evaluation of patients for pulmonary resection should continue to evolve as new information about outcome studies is gathered. Examination of outcome data will provide us with reduction of the size of the nonoperable population, so that we can deny only those patients who truly pose a prohibitive risk.  相似文献   
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