Chemometric evaluation of binary mixtures of alginate and polysaccharide biopolymers as carriers for microencapsulation of green tea polyphenols

In this study principal component analysis and artificial neural networks were used to evaluate the potential of using binary mixtures of sodium alginate and other polysaccharide biopolymers as the carriers for microencapsulation of green tea bioactive compounds. Using binary mixtures of alginate and adjunct biopolymers increased the particle size (from 722 to 1344 µm) and textural parameters of the microbeads. Chemometric techniques revealed the combination of biopolymers and their ratio as the main factors influencing the encapsulation performance. The combination of alginate with hydroxypropyl methylcellulose and locust bean gum enabled to retain the highest (-)-epigallocatechin gallate and caffeine contents, the highest total phenols encapsulation efficiency, and their most retarded release in water, confirming these as the best delivery systems of polyphenol-type active compounds and signifying their potent food applications.     

Quality characteristics of sunflower Halawa

Chemical analysis showed that sunflower halawa contained higher crude ether extract than sesame halawa, while the protein, ash and crude fiber were practically similar in both. The chemical analysis emphasized the high energy value of sunflower halawa (23.3 kJ/g). The in vitro digestibility of sunflower and sesame halawas amounted to 98.9% and 98.4%, being close to that of casein (99.6%). Oil separation in sunflower halawa was followed during storage at room temperature. Although the peroxide value of sunflower halawa oil increased with prolonged storage time, rancid taste was not detected. Sensory evaluation showed no significant difference between sunflower and sesame halawas, except that the former was dark in colour. The introduction of 50% of each of sunflower and sesame tahinas in halawa manufacture is suggested to improve the quality characteristics as a means of doubling its production and reduction of importation of sesame seeds.     

New Mononuclear Cu(II) Complexes and 1D Chains with 4-Amino-4H-1,2,4-triazole

The crystal structures of two mononuclear Cu(II) NH₂trz complexes [Cu(NH₂trz)₄(H₂O)](AsF₆)₂ (I) and [Cu(NH₂trz)₄(H₂O)](PF₆)₂ (II) as well as two coordination polymers [Cu(μ₂-NH₂trz)₂Cl]Cl·H₂O (III) and [Cu(μ₂-NH₂trz)₂Cl] (SiF₆)_0.5·1.5H₂O (IV) are presented. Cationic 1D chains with bridging bis-monodentate μ₂-coordinated NH₂trz and bridging μ₂-coordinated chloride ligands are present in III and IV. In these coordination polymers, the Cu(II) ions are strongly antiferromagnetically coupled with J = −128.4 cm⁻¹ for III and J = −143 cm⁻¹ for IV (H = −J∑S_iS_i+1), due to the nature of the bridges between spin centers. Inter-chain interactions present in the crystal structures were taken into consideration, as well as g factors, which were determined experimentally, for the quantitative modeling of their magnetic properties.     

How to Manage Complex,Multinational R&D Projects Successfully

Abstract

The globalization of markets, mergers of international companies, and integration of managerial and business processes in global corporations are changing project management fundamentals. A clearly recognizable trend in multinational companies since the mid-1980s has been globalization of R&D and competence portfolios.

Applied development is usually conducted in the form of a distributed project organization. A project team is formed across geographical, organizational, and cultural boundaries, engaging in a project with a global focus. Although a multinational project organization has great potential in many dimensions, there is no doubt that the execution of a distributed high technological project is still a great challenge.

This article identifies success factors in the management of distributed projects with global goals. The authors have focused on the practical experiences of the execution of complex multinational projects in the area of applied system development for power industry.     

Effect of Liquid Hot Isostatic Pressing on Structure and Mechanical Properties of a Sand-Cast A356.02 Alloy

The effect of liquid hot isostatic pressing (LHIP) on the structure and mechanical properties of an A356.02 alloy was examined. It was shown that LHIP provides a porosity decrease from ~0.9 to 0.2 pct due to the elimination of shrinkage voids. As a result, the yield stress (YS) increases from 200 to ~230 MPa, the ultimate tensile strength (UTS) increases from ~275 to 310 MPa, the total elongation increases from ~4 to ~7.5 pct, and the fatigue strength increases from ~88 to ~140 MPa. It was found that the sequence of LHIP and homogenization annealing highly affects the hardness and variability in fatigue strength. LHIP followed by homogenization annealing provides the lowest scattering of fatigue strength and, therefore, the fabrication of the most reliable casting components.     

High‐pressure recovery of anthocyanins from grape skin pomace (Vitis vinifera cv. Teran) at moderate temperature

The objective was to evaluate the influences of the high hydrostatic pressure extraction parameters on the recovery of anthocyanins from the grape skin pomace extracts (Vitis vinifera cv. Teran) under moderate temperatures. Studied parameters were: solvents (methanol and ethanol); solvent concentrations (30, 50, and 70%); pressures (300, 400, and 500 MPa); times (3, 6.5, 10 min); and temperatures (22, 26, 30 °C). Predominant anthocyanins in all extracts were malvidins (malvidin‐3‐glucoside as the main compound) representing 55.77% of overall anthocyanin content. The type of solvent did not significantly influence anthocyanin extraction yield, while decreased solvent concentration (increased solvent‐to‐water ratio) significantly improved extraction of anthocyanins. Increase of pressure enhanced extraction yield of the anthocyanins but temperature showed stronger impact on the anthocyanins recovery. This investigation evidenced that the best conditions for HHPE of anthocyanins from grape pomace were extraction time 3.39 min, extraction temperature 29.48 °C, pressure 268.44 MPa and solvent concentration 70%.

Practical applications

Due to increased interest for the use of cheap winery byproducts as a source of expensive polyphenols for functional food production, skins from grape pomace became valuable raw material. Therefore, there is a need to evaluate the influence of HHPE innovative extraction technology on its nutritive value during processing. Optimizing parameters for polyphenolic recovery from grape pomace is directly related with nutritional value and economics of food engineering during industrial processing. Obtained results showed that the HHPE under lower temperatures is suitable for the extraction process of anthocyanins from grape skin pomace, but more research is needed to identify other food‐grade solvents with their corresponding concentrations that are useful for the extraction assisted with high hydrostatic pressure.     

Maximum independent set in planning freight railway transportation

This work is devoted to the problem of planning of freight railway transportation. We define a special conflict graph on the basis of a set of acceptable train routes. The investigation aims to solve the classical combinatorial optimization problem in relation to the maximum independent set of vertices in undirected graphs. The level representation of the graph and its tree are introduced. With use of these constructions, the lower and upper bounds for the number of vertices in the maximum independent set are obtained.     

Comparison of glass hydration layer thickness measured by transmission electron microscopy and nanoindentation

The thicknesses of the hydration layers on the surfaces of 2 silicate glasses have been assessed using a) a combination of focused ion beam milling and transmission electron microscopy and b) nanoindentation; the two approaches give consistent layer thicknesses. Lighter contrast of the hydrated layers in TEM suggests that the layers have reduced density when compared to the bulk glasses; this is consistent with the reduced near surface modulus and hardness of hydrated glasses observed in nanoindentation.     

Suzuki Cross-Coupling Reaction Catalyzed by the Palladium Complex Pd[N-MorphC(S)NP(O)(OiPr)2-O,S]2

Suzuki cross-coupling reaction between phenyl bromide and phenylboronic acid, catalyzed by the palladium complex Pd[N-MorphC(S)NP(O)(OiPr)₂-1,5-O,S)]₂ in acetonitrile, toluene, THF or DMF has been investigated. Bases employed for the reaction were Na₂CO₃, K₂CO₃ or Cs₂CO₃. Varying largely the experimental conditions we found that excellent yields of the product were obtained using toluene and K₂CO₃ at 100 °C at the catalyst amount of 0.02 mmol.     

Acoustics of a viscoelastic medium with encapsulated bubbles

In this paper,a modified Rayleigh-Lamb equation is derived that takes into account the radial vibrations of a gas bubble coated with a viscoelastic shell and located in an elastic medium.For small oscillations of inclusion,the problem of heat exchange between a gas,a liquid phase,a viscoelastic shell,and an elastic medium is solved.The energy integral is determined.In the case of small disturbances,the dispersion relation is found from the Rayleigh-Lamb equations,energy,and the known wave equation for the bubbly medium.An analytical expression of the equilibrium speed of sound is written out and its dependence on the size of the viscoelastic shell and the disturbance frequency is established.An example of a mixture of polydimethylsiloxane with air bubbles coated with a rubber shell illustrates the influence of the elasticity of the carrier medium and the shell of the bubbles on the dependence of the phase velocity and attenuation coefficient on the perturbation frequency.For a mixture of water with air bubbles coated with a rubber shell,the influence of the dependences of the shear modulus and viscosity of butyl rubber on the frequency of disturbances at different temperature on the dispersion curves is shown.A comparison of the theory with experimental data is given.