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排序方式: 共有600条查询结果,搜索用时 15 毫秒
101.
ukasz Szeleszczuk Anna Helena Mazurek Katarzyna Milcarz Ewa Napirkowska Dariusz Maciej Pisklak 《International journal of molecular sciences》2021,22(18)
Isosymmetric structural phase transition (IPT, type 0), in which there are no changes in the occupation of Wyckoff positions, the number of atoms in the unit cell, and the space group symmetry, is relatively uncommon. Chlorothiazide, a diuretic agent with a secondary function as an antihypertensive, has been proven to undergo pressure-induced IPT of Form I to Form II at 4.2 GPa. For that reason, it has been chosen as a model compound in this study to determine if IPT can be predicted in silico using periodic DFT calculations. The transformation of Form II into Form I, occurring under decompression, was observed in geometry optimization calculations. However, the reverse transition was not detected, although the calculated differences in the DFT energies and thermodynamic parameters indicated that Form II should be more stable at increased pressure. Finally, the IPT was successfully simulated using ab initio molecular dynamics calculations. 相似文献
102.
In this paper, a Goursat–Darboux control system is considered. In the first part, the bang-bang principle and some approximation results concerning the piecewise constant controls, for a linear system with distributed and boundary controls, are proved. In the second part, an approximation result concerning the bang-bang controls, for a special case of nonlinear (in a state) system with distributed controls, is derived. 相似文献
103.
Dariusz Idczak 《International journal of control》2013,86(11):1089-1094
In this paper, the bang-bang principle for a control system described by a system of non-linear (in control) non-autonomous partial differential equations of hyperbolic type (the so-called Goursat-Darboux problem) is proved. As a particular case the bang-bang principle for a linear system is obtained. The method used for the proof is based on some properties of the Aumann integral. 相似文献
104.
Edgar Cordruwisch Dariusz Kaczorowski Peter Rogl Adriana Saccone Riccardo Ferro 《Journal of Alloys and Compounds》2001,320(2):308-319
Phase relations were established for the Ce–Ag–Si system at 850°C by means of X-ray diffraction, light optical microscopy and quantitative electron probe microanalysis. Phase equilibria are characterised by the existence of extended solid solutions starting from the binaries: Ce(AgxSi1−x)2−y (ThSi2-type), Ce(Ag1−xSix)1−y (unknown structure type) and Ce(Ag1−xSix)2−y (unknown structure type). Three ternary phases were found to exist, CeAg2Si2 (ThCr2Si2-type), Ce(AgxSi1−x)2−y (AlB2-type) and the new ternary compound CeAgSi2 with unknown structure type. Magnetic behaviour was studied from magnetic susceptibility and magnetisation measurements down to 1.7 K and employing magnetic fields up to 5 T. Soft ferromagnetism is observed for CeAgxSi2−x (AlB2-type) below 5 K. Alloys Ce(AgxSi1−x)2−y with 0.08<xAg<0.30 (ThSi2-type) encounter ferromagnetic order below 7 K. For xAg=0.31 the ferromagnetic interaction changes to antiferromagnetism with TN=5.7 K. For CeAgSi2 ferrimagnetic or canted antiferromagnetic order is indicated below 7 K. 相似文献
105.
The paper presents an idea for the enhancement of a building's thermal insulation component by adding into the structure a thin layer of a phase-change material (PCM). The proposed solution can be dedicated, for example, to an external partition of lightweight construction. The capacity for latent heat storage allowed it to stabilize the temperature inside the insulation layer in a daily cycle and to minimize the temperature difference between the internal and external surfaces. In this paper, different positions of a PCM layer in the thermal insulation of an external wall were analysed. The main goal of this work was to find the best position of the PCM layer, taking into account the indoor temperature and the meteorological conditions. The authors propose two parameters: the amount of stored energy and the dynamism of the charging/discharging processes. Taking into account large temperature fluctuations on the external surface during summer and winter, it was concluded that, for this specific case, the most appropriate solution would be an external position of the PCM with a melting temperature of 20°C. 相似文献
106.
Application of mechanics of multi-phase porous media for modeling cement based materials at high temperature is presented.
The considerations are based on the mathematical model of mechanistic type, developed by the authors within recent years.
The model has been previously experimentally validated and successfully applied for analyzing performance of various concrete
structures at high temperature. Physical phenomena in a concrete element heated during a fire are described and analyzed,
confirming multi-phase nature of concrete in these conditions. Main stages of the mathematical model development by means
of hygro-thermo-mechanics of porous media are briefly presented. The mass, energy and linear momentum conservation equations
at micro-scale are given and averaged in space to obtain the macroscopic form of the equations. Some main key-points in modeling
cement-based materials at high temperature are discussed. Final form of the model equations and method of their numerical
solution are presented. The model is validated by comparison with some published results of experimental studies. Two examples
of the model application for numerical simulation of concrete structures exposed to fire conditions, including also a cooling
phase, are analyzed. 相似文献
107.
Erika Kozma Dariusz KotowskiFrancesco Galeotti Marinella CatellaniSilvia Luzzati Fabio Bertini 《Materials Chemistry and Physics》2014
Two solution processable donor–acceptor, π-conjugated molecules that consist of diketopyrrolopyrrole (DPP) central acceptor unit with dibenzofuran (DPP-DBF) or acenaphtene (DPP-ACN) donor substituents, were prepared by Suzuki coupling reaction. The optical, electrochemical and film forming properties of these D–A–D molecules were investigated and used as active materials in bulk heterojunction solar cells. 相似文献
108.
109.
Joanna A. Bartkowska Dariusz Bochenek 《Journal of Materials Science: Materials in Electronics》2018,29(20):17262-17268
Multiferroics with negative value of dielectric constant are very promising materials because of their modern applicability. These materials can be used as materials for the construction of electromagnetic radiation shields. The subject of the research is multiferroic BiFeO3–PbFe1/2Nb1/2O3 (BF–PFN) ceramics. For all multiferroic materials the following studies are conducted: SEM, EDS and the temperature dependence of dielectric constant ε′(T). Above a certain temperature (different for different chemical compositions) the value of dielectric constant reaches negative values. Such the behavior of the dielectric constant may indicate that the polarization inside the material has a reverse direction to the external electric field. That is, the electric field inside the material counteracts the applied external electric field. The obtaining materials also show negative dielectric losses. The Axelrod model is used to explain the mechanism that causes negative dielectric loss. 相似文献
110.
We present an approach based on three-dimensional Monte Carlo radiative transfer simulations for estimating scattering error in measurements of light absorption by aquatic particles with a typical laboratory double-beam spectrophotometer. The scattering error is calculated by combining the weighting function describing the angular distribution of photon losses that are due to scattering on suspended particles with the volume scattering function of particles. We applied this method to absorption measurements made on marine phytoplankton, a diatom Thalassiosira pseudonana and a cyanobacterium Synechococcus. Assuming that the scattering phase function is described by the Henyey-Greenstein formula, we determined the backscatter probability of phytoplankton, which yields the best correction for scattering error at a light wavelength of 750 nm, where true absorption is null. The backscattering ratio estimated for both phytoplankton species is significantly higher than previously reported data based on Mie-scattering calculations for homogeneous spheres. Depending on the type of particles, the corrected absorption spectra obtained with our method may be similar or significantly different from spectra obtained with the null-point correction based on wavelength-independent scattering error. 相似文献