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21.
K. Bouzek R. Chmelíková M. Paidar H. Bergmann 《Journal of Applied Electrochemistry》2003,33(2):205-215
A study was made of the influence of process parameters on the mass-transfer coefficient in a flow-through cell with a cascade of rotating drums partially filled with conductive particles (called the vertically moving particle bed). Copper deposition from an acidic sodium sulphate solution was used as the model reaction. To evaluate the experimental data a macrohomogeneous mathematical model of potential and current density distribution inside the cell was developed. The electrolyte flow distribution between the empty space above the particle bed and through the bed was evaluated. On the basis of these results the following correlation is proposed:
where the first term corresponds to the packed bed electrode and the second term represents the contribution of bed rotation. It is valid for bed porosity of 45%, cathode drum rotation rates between 0.047 and 0.120 Hz (i.e., 2.8 to 7.2 rpm) and a Re
p range of 0.003 to 0.013. 相似文献
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Flame Assisted Chemical Vapor Deposition (FACVD), a novel technique that shows an enormous potential in porous oxides deposition, was employed for the first time aiming to obtain hydroxyapatite (HA) coatings on 316 L stainless steel metallic substrates. Calcium acetate and ammonium phosphate diluted in ethanol were employed as precursor salts. A Ca/P molar ratio of 1.66 was employed in precursor solution, which is equivalent to stoichiometric hydroxyapatite. A porous coating, formed by an open and interconnected network, was observed by scanning electronic microscopy (SEM) and associated with homogenous reactions. Thickness of hydroxyapatite coating was 412 ± 3 μm. X-ray diffraction (XRD) analysis indicated the presence of crystalline coatings, mainly constituted by hydroxyapatite phase and traces of tricalcium phosphate (β-TCP). Carbonate in the hydroxyapatite coatings was identified by Fourier transform-infrared (FTIR) spectroscopy. 相似文献
25.
Alisher Mirzabaev Dawit Guta Jann Goedecke Varun Gaur Jan Börner Detlef Virchow 《国际水》2015,40(5-6):772-790
This article provides a review of trade-offs and synergies of bioenergy within the water–energy–food security nexus, with emphasis on developing countries. It explores the links of bioenergy with food security, poverty reduction, environmental sustainability, health, and gender equity. It concludes that applying the nexus perspective to analyses of bioenergy widens the scope for achieving multiple-win outcomes along the above aspects. 相似文献
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Multifunctional Gadolinium‐Doped Mesoporous TiO2 Nanobeads: Photoluminescence,Enhanced Spin Relaxation,and Reactive Oxygen Species Photogeneration,Beneficial for Cancer Diagnosis and Treatment
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Roghayeh Imani Ralf Dillert Detlef W. Bahnemann Meysam Pazoki Tomaž Apih Veno Kononenko Neža Repar Veronika Kralj‐Iglič Gerrit Boschloo Damjana Drobne Tomas Edvinsson Aleš Iglič 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(20)
Materials with controllable multifunctional abilities for optical imaging (OI) and magnetic resonant imaging (MRI) that also can be used in photodynamic therapy are very interesting for future applications. Mesoporous TiO2 sub‐micrometer particles are doped with gadolinium to improve photoluminescence functionality and spin relaxation for MRI, with the added benefit of enhanced generation of reactive oxygen species (ROS). The Gd‐doped TiO2 exhibits red emission at 637 nm that is beneficial for OI and significantly improves MRI relaxation times, with a beneficial decrease in spin–lattice and spin–spin relaxation times. Density functional theory calculations show that Gd3+ ions introduce impurity energy levels inside the bandgap of anatase TiO2, and also create dipoles that are beneficial for charge separation and decreased electron–hole recombination in the doped lattice. The Gd‐doped TiO2 nanobeads (NBs) show enhanced ability for ROS monitored via ?OH radical photogeneration, in comparison with undoped TiO2 nanobeads and TiO2 P25, for Gd‐doping up to 10%. Cellular internalization and biocompatibility of TiO2@x Gd NBs are tested in vitro on MG‐63 human osteosarcoma cells, showing full biocompatibility. After photoactivation of the particles, anticancer trace by means of ROS photogeneration is observed just after 3 min irradiation. 相似文献
28.
Recent developments in cellular imaging now permit the minimally invasive study of protein interactions in living cells. These advances are of enormous interest to cell biologists, as proteins rarely act in isolation, but rather in concert with others in forming cellular machinery. Up until recently, all protein interactions had to be determined in vitro using biochemical approaches. This biochemical legacy has provided cell biologists with the basis to test defined protein-protein interactions not only inside cells, but now also with spatial resolution. More recent developments in TCSPC imaging are now also driving towards being able to determine protein interaction rates with similar spatial resolution, and together, these experimental advances allow investigators to perform biochemical experiments inside living cells. Here, we discuss some findings we have made along the way which may be useful for physiologists to consider. 相似文献
29.
A Comparison of Free BDDs and Transformed BDDs 总被引:2,自引:0,他引:2
Ordered binary decision diagrams (OBDDs) introduced by Bryant (IEEE Trans. on Computers, Vol. 35, pp. 677–691, 1986) have found a lot of applications in verification and CAD. Their use is limited if the OBDD size of the considered functions is too large. Therefore, a variety of generalized BDD models has been presented, among them FBDDs (free BDDs) and TBDDs (transformed BDDs). Here the quite tight relations between these models are revealed and their advantages and disadvantages are discussed. 相似文献
30.
Summary The complements of an AFL form an AFL if and only if is closed under length-preserving universal quantification. The complements of the context-sensitive languages form a principal AFL with a hardest set L
1. The context-sensitive languages are closed under complementation if and only if L
1 is context-sensitive.This research was supported in part by the National Science Foundation under Grants MCS76-10076 and DCR74-15091 相似文献