Patterning of Nanoparticle‐Based Aerogels and Xerogels by Inkjet Printing

Nanoparticle‐based voluminous 3D networks with low densities are a unique class of materials and are commonly known as aerogels. Due to the high surface‐to‐volume ratio, aerogels and xerogels might be suitable materials for applications in different fields, e.g. photocatalysis, catalysis, or sensing. One major difficulty in the handling of nanoparticle‐based aerogels and xerogels is the defined patterning of these structures on different substrates and surfaces. The automated manufacturing of nanoparticle‐based aerogel‐ or xerogel‐coated electrodes can easily be realized via inkjet printing. The main focus of this work is the implementation of the standard nanoparticle‐based gelation process in a commercial inkjet printing system. By simultaneously printing semiconductor nanoparticles and a destabilization agent, a 3D network on a conducting and transparent surface is obtained. First spectro‐electrochemical measurements are recorded to investigate the charge–carrier mobility within these 3D semiconductor‐based xerogel networks.     

NDE of degradation of thermal barrier coating by means of impedance spectroscopy

Nondestructive evaluation of thermal barrier coating (TBC) degradation during service operation has received a wide attention for service life prediction of advanced gas turbines. In this work, TBC on nickel base superalloy degraded at various degrees by thermal aging is investigated. Particularly, TBC and Metal–Chromium–Aluminum–Yttrium alloy (McrAlY) (M indicates iron (Fe), cobalt (Co), nickel (Ni) or these combinations) bond coating interface where a detrimental reaction takes place and forms various reaction products during thermal aging, is studied in detail. Formation kinetics and physical properties of the reaction layer are evaluated by means of Impedance Spectroscopy (IS). Specimens aged at higher temperature and a longer aging time shows larger impedance. The impedance behavior of TBC and bond coating is found to be markedly changed by the formation of the reaction layer. Physical properties and thickness of the reaction layer are evaluated using the change of the impedance. A mechanistic interpretation of the cause of change in the physical properties and IS behavior are described.     

Charge‐Transfer Interactions: An Efficient Tool for Recycling Bis(oxazoline)‐Copper Complexes in Asymmetric Henry Reactions

An anthracenyl‐modified chiral bis(oxazoline) copper complex has been demonstrated to efficiently promote nitroaldol reactions between structurally varying aldehydes and nitromethane or nitroethane. The catalyst was recovered through formation of a charge transfer complex between the chiral ligand and trinitrofluorenone and its subsequent precipitation with pentane. The efficiency of this procedure was proved through several consecutive catalytic cycles that allowed the sturdy formation of the expected product with a high enantioselectivity. The catalyst′s stability was also put to the test in an original multi‐substrate procedure. Following the same recovery concept, a new heterogeneous procedure was tested for which trinitrofluorenone was covalently linked to a silica support. Asymmetric heterogeneous catalysis was performed under these conditions as one of the few examples demonstrating the potential catalyst recycling in nitroaldol reactions through reversible, non‐covalent interactions.     

Performance of digital filtering methods in orthotic and prosthetic CAD/CAM.

This report characterizes the performance of three digital filters, when applied to residual limb shape maps. The three filters were an averaging filter, a uniform window Fourier filter, and a Hamming window Fourier filter. The frequency responses of the three filters were calculated from theory, and experimentally observed. Experimental observations consisted of responses on single-frequency lobed shapes, and on residual limb shapes. Seven trans-tibial limb molds were digitized, three times each. Each resulting shape was then passed through each of the three filters. The before and after shapes were then compared. A Hamming window filter (low-pass frequency of 10 cycles per revolution, 24 coefficients, Hamming number of 0.25) achieved the best performance based on maintained amount of residual limb frequencies, and on visual observation.     

Challenges and opportunities of delivering IP-based residential television services

This article describes the main challenges of implementing an end-to-end architecture for delivery of high-quality, IP-based residential TV services to residential customers. The IP-based approach can be implemented with an IP multicast overlay network with traditional routers or use IP-multicast-aware ATM switching systems. Both approaches use IP multicast to transport MPEG-2 broadcast video and can work on any access architecture, especially on copper-based architectures (xDSL) such as ASDL and VDSL. The main challenges met while implementing the IP-based architecture are competitive positioning relative to traditional CATV architectures, overall architecture, head-end architecture and quality issues, traffic engineering for stringent QoS requirements, IP multicast requirements, and business case considerations. The IP-based approach described leverages Internet technology advancements and capitalizes on the impacts of Internet on interactive entertainment. Video channel manipulation at the head-end is dependent on access bandwidth and affects video quality. Video traffic management to meet stringent QoS requirements is challenging at the IP layer. High-capacity, responsive IP multicasting is essential to achieving high service quality. Cost-effective IP multicasting is a critical component of the business case.     

Experiences in building a Grid-based platform to serve Earth observation training activities

Earth observation data processing and storing can be done nowadays only using distributed systems. Experiments dealing with a large amount of data are possible within the timeframe of a lesson and can give trainees the freedom to innovate. Following these trends and ideas, we have built a proof-of-the-concept platform, named GiSHEO, for Earth observation educational tasks. It uses Grid computing technologies to analyze and store remote sensing data, and combines them with eLearning facilities. This paper provides an overview of the GiSHEO's platform architecture and of its technical and innovative solutions.     

Elucidation of Dimethylalkylpyrazines from the Ant Streblognathus aethiopicus by GC-FTIR

The presumed mandibular gland secretions from the workers and gamergates of two colonies of Streblognathus aethiopicus have been found to contain a homologous series of 3,5-dimethyl-2-alkylpyrazines (3,5-dimethyl-2-butylpyrazine, 1; 3,5-dimethyl-2-pentylpyrazine, 2; and 3,5-dimethyl-2-hexylpyrazine, 3). The structures of these compounds were determined from their mass spectra along with a comparison of their GC-FTIR spectra with those of all the isomers of a lower homolog. This is the first time that this combination of techniques has been applied to the study of insect pyrazines. The relative amounts and proportions of these compounds were different for gamergates and workers, with the latter containing 2–10 times more total pyrazines and having a higher proportion of 2 and 3. The possible significance of this finding is discussed.     

A practical study of white‐clawed crayfish (Austropotamobius pallipes) mitigation during in‐channel construction works,North‐East England

The article provides a unique opportunity to study a large white‐clawed crayfish mitigation exercise on the River Wansbeck, Northumberland in North East England. The translation was necessary to allow the construction of a dam on the river to reduce flood risk to the town of Morpeth. The study provides an assessment of the methodology used for the capture and translocation activities, and provides an insight into the speed of colonisation and population establishment in a 300‐m diversion channel and the structure of translocated populations. Over 3500 + white‐clawed crayfish were caught when the natural channel was dewatered, with 5400 animals removed the following year when the diversion channel was closed. Average density based on the number of white‐clawed crayfish caught was estimated as in excess of 5 per 1 m². The study demonstrates the importance of the River Wansbeck for white‐clawed crayfish.