Stereospecific synthesis ofcis andtrans fatty esters

Theerythro andthreo isomers of methyl 9,10-dihydroxyoctadecanoate and thethreo isomer of methyl 12,13-dihydroxy-cis-9-octadecenoate were converted into methylcis- andtrans-9-octadecenoate and methylcis-9,rans-12-octadecadienoate, respectively, by reaction of the dihydroxy ester with triethyl orthoformate to give the 2-ethoxy-1,3-dioxolane which was thermally decomposed to the unsaturated ester.     

Fat,cholesterol, and atherosclerosis

Summary Cholesterol is a universal constituent of all animal cells and therefore occurs in all foods of animal origin. Cholesterol is the mother substance of bile acid and of sex hormones and has other important physiological roles. Cholesterol is synthesized in the body from acetate obtainable from ingested carbohydrate, fat. or protein, of animal or vegetable origin. The fate of cholesterol in the body has not been definitely established. The cause of atherosclerosis is unknown. Atherosclerosis occurs in young as well as old individuals. Atherosclerosis is the number-one killer today. Diagnosis of atherosclerosis in the healthy individual is not possible. Treatment of atherosclerosis is empirical. Reduction of blood cholesterol levels by dietary means is difficult under conditions consonant with good nutrition. A well-balanced intake of all available foods on a modified total caloric basis appears to be the practical approach to the problem of fat, cholesterol, and atherosclerosis. Presented at the 47th Annual, Meeting, American Oil Chemists’ Society, Houston, Tex., April 23–25, 1956.     

A facile chemical synthesis of cholest-4-en-3-one. Carbon-13 nuclear magnetic resonance spectral properties of cholest-4-en-3-one and cholest-5-en-3-one

This paper presents a simplified method for the chemical synthesis of cholest-4-en-3-one, which is a naturally occurring steroid and a salient intermediate in steroid chemistry. Pyridinium chlorochromate (PCC) in refluxing benzene has been found to be an effective and convenient reagent for the oxidation and concomitant isomerization of cholest-5-en-3β-ol (cholesterol) to cholest-4-en-3-one in high yield. Also described are the carbon-13 nuclear magnetic resonance spectral properties of cholest-4-en-3-one and of the isolated reaction intermediate cholest-5-en-3-one. Based on a paper presented at the Symposium on Plant and Fungal Sterols: Biosynthesis Metabolism and function held at the AOCS Annual Meeting, Baltimore, MD, April 1990.     

时尚

时尚是有规律的.它不是以进步的形式运动,而是在循环中运动.外在的一致性通常会破坏内在的一致性.本文就时尚的规律、时尚的产生与运动过程、时尚与限制性规则、现代时尚的新变革等方面展开讨论.     

Pressureless low temperature sintering of nanocrystalline zirconia ceramics via dry powder processing

Pressureless sintering approaches provide a simple avenue to manufacture dense ceramic parts with minimal processing equipment, but current pressureless sintering techniques have yet to demonstrate capabilities of producing dense ceramics while maintaining sub-50 nm grain sizes. Nanocrystalline yttria stablized zirconia ceramics were process from 4 mol% yttria stablized zirconia (4YSZ) nanopowders with a crystallite size of 7.5 nm using dry cold isostatic pressing (CIP) where powders are dried immediately prior to green compact formation and CIP vacuum bagging. It is shown that CIP pressures >75 000 psi (517 MPa) effectively remove pores larger than 100 nm and that pressureless sintering occurs at reduced temperatures for green densities ≥50%. Though the sintering kinetics are shown to be similar to other zirconia nanopowder sintering studies, the small initial crystallize size and reduced sintering temperature allowed densities as high as 97.2%, while retaining a ceramic grain size at or below 40 nm. Produced nanocrystalline 4YSZ ceramics with a grain size of 30.3 nm and a density of 96.3% had Vicker's hardnesses as high as 14.2 GPa and Vicker's indentation fracture resistance of 3.43 MPa·, demonstrating that simple processing approaches can be refined to fabricate nanocrystalline ceramics while maintaining high hardness and indentation fracture resistance.     

Effect of Molybdenum on the Structure and on the Crystallization of SiO2–Na2O–CaO–B2O3 Glasses

Crystallization of the poorly durable Na₂MoO₄ phase able to incorporate radioactive cesium must be avoided in SiO₂–Al₂O₃–B₂O₃–Na₂O–CaO glasses developed for the immobilization of Mo-rich nuclear wastes. Increasing amounts of B₂O₃ and MoO₃ were added to a SiO₂–Na₂O–CaO glass, and crystallization tendency was studied. Na₂MoO₄ crystallization tendency decreased with the increase of B₂O₃ concentration whereas the tendency of CaMoO₄ to crystallize increased due to preferential charge compensation of BO₄⁻ entities by Na⁺ ions. ²⁹Si MAS NMR showed that molybdenum acts as a reticulating agent in glass structure. Trivalent actinides surrogate (Nd³⁺) were shown to enter into CaMoO₄ crystals formed in glasses.     

ABSORPTION AND DESORPTION TO AND FROM LIQUID FILMS ON INCLINED PLANES

Two published theoretical models are examined and applied to experimental results for absorption and desorption. The system used was CO₂/H₂O and studies were made for liquid film flow down inclined planes. Experimental results give “Reduced” values of mass ransfer rates.

Interferometric studies give interfacial concentration, penetration and film depths, and take-up of carbon dioxide. In the case of desorption the interferograms are distorted by “deflections.”

All the experimental values for absorption and desorption differ from those calculated from theoretical models.

Desorption is not a mirror image of absorption, and it is approximately 75% of the transfer rate of absorption over a wide operating range.

A comparison is made of the behaviour of static pools and flowing liquid films.     

Microstructure of high modulus solid state extruded polyethylene: 2. X-ray scattering studies of 12, 24 and 36 extrusion draw ratio

The microstructure of a series of solid state extruded polyethylene fibres was examined by wide- and small-angle X-ray scattering. By measuring absolute intensities using a two dimensional position sensitive detector, accurate values of the small-angle invariant for anisotropic samples were obtained. This measurement coupled with wide-angle X-ray scattering and d.s.c. permitted determination of the density of the noncrystalline component. The use of a two phase model for solid state extruded polyethylene is justified if consideration is given to the effective densities of the crystalline and noncrystalline phases, which change with deformation. The effective density of the crystalline phase decreases by 1% (0.999–0.990 g cm^?3) from the unextruded billet compared to a 36 draw ratio extrudate, while the noncrystalline phase density increases by 6% (0.84–0.89 g cm^?3). These changes lead to an overall decrease in the mean squared electron density fluctuation of 63%. The average axial crystallite length measured by wide-angle X-ray scattering increases with extrusion draw ratio while the SAXS long period decreases and weakens considerably. These observations and the electron microscopy results from the previous paper, (Polymer, 1982, 23, 1069), are fully consistent with the key features of the Peterlin model of fibre microstructure.     

Synthesis and photo-induced solution properties of new rigid-rod polyimides

A series of new, substituted pyromellitic dianhydrides were synthesized from 1,2,4,5-tetramethylbenzene. New soluble rigid-rod polyimides were obtained from the dianhydrides and 2,2′-bis(trifluoromethyl)-4,4′-biphenyl (PFMB) in phenolic solvents in the presence of isoquinoline as a catalyst. The polyimides are soluble in N-methyl-2-pyrrolidone (NMP), N,N-dimethylacetamide (DMAc), m-cresol and other solvents, in spite of having no bending in their rigid structures.

UV irradiation changed color of the polyimide solutions and also their viscosity. We observed new absorbance in the 700-nm region and an ESR signal by UV irradiation. The new visible absorbance and the ESR signal are derived from the same origin. They are attributed to the anion radical of the diimide moiety in the polyimide as deduced from the hyper fine structure of the ESR signal. In addition, UV irradiation diminishes the solution viscosity.     

Sustainable end-of-life vehicle recycling: R&;D collaboration between industry and the U.S. DOE

Approximately 15 million cars and trucks reach the end of their useful life in the United States each year. More than 75% of the materials from end-of-life vehicles are profitably recovered and recycled by the private sector; automotive materials recycling is a success story. To achieve greater fuel efficiency and safety, today’s cars incorporate an increasing share of innovative light-weight materials. While these materials greatly enhance efficiency during vehicle use, they can present special challenges for recycling. These challenges will persist as automotive designs and the mix of materials used in vehicles continue evolving to further improve safety and performance. To meet the challenges of automotive materials recycling, the U.S. Department of Energy has recently expanded its collaborative research with industry in this area. This article discusses this collaborative government/industry approach to sustainable end-of-life vehicle recycling. For more information, contact Edward J. Daniels, Argonne National Laboratory, 9700 S. Cass Avenue, Building 362, Room C393, Argonne, IL 60439-4815; (630) 252-5279; fax (630) 252-1342; e-mail edaniels@anl.gov.