Fatty acid profiles in tissues of mice fed conjugated linoleic acid

The incorporation of vaccenic acid (VA, 0.5 and 1.2%), conjugated linoleic acid (CLA, mixture of primarily c9,t11‐ and t10,c12‐CLA, 1.2%), linoleic acid (LA, 1.2%) and oleic acid (OA, 1.2%) into different tissues of mice was examined. The effects on the fatty acid composition of triacylglycerols (TAG) and phospholipids (PL) in kidney, spleen, liver and adipose tissue were investigated. VA and CLA (c9,t11‐ and t10,c12‐CLA) were primarily found in TAG, especially in kidney and adipose tissue, respectively. Conversion of VA to c9,t11‐CLA was indicated by our results, as both fatty acids were incorporated into all the analyzed tissues when a diet containing VA but not c9,t11‐CLA was fed. Most of the observed effects on the fatty acid profiles were seen in the CLA group, whereas only minor effects were observed in the VA groups compared with the OA group. Thus, CLA increased n‐3 polyunsaturated fatty acids (PUFA) in PL from kidney and spleen and lowered the ratio of n‐6/n‐3 PUFA in these tissues. Furthermore, CLA increased C₂₂ PUFA in the PL fraction of kidney, spleen and liver, but reduced the level of arachidonic acid in PL of liver and spleen and lowered the Δ⁹‐desaturation indexes in all analyzed tissue TAG.     

Preparation of glycol derivatives of partially hydrogenated soybean oil fatty acids and their potential as lubricants

Glycol diesters and mixtures of mono- and diesters have been prepared from methyl esters of partially hydrogenated soybean oil fatty acids and diethylene, dipropylene, neopentyl and triethylene glycols. The catalyst used in these reactions was a mixture of calcium acetate/barium acetate (3∶1, w/w). The reactions were carried out under nitrogen with 0.5% catalyst at temperatures in the range of 190–275°C. Borated esters of mixed mono- and diesters were prepared with 0.33 equivalent of boric acid per 1.0 equivalent hydroxyl group on the ester. Refractive indices, viscosities, and flash and fire points were determined for diesters, mixed mono- and diesters, and mixed diesters and borated esters. The viscosities, flash points and fire points indicate that these esters can be used as a component of lubricating oils. Wear-prevention characteristics of mixed diesters and borated esters indicated that they can be used as antifriction additives in lubricating oils. Lecture presented at the joint meeting of the International Society for Fat Research and the American Oil Chemists' Society in Toronto, May 10, 1992.     

Characterizing multiple memory deficits and their relation to everyday functioning in individuals with mild cognitive impairment.

The authors evaluated multiple memory processes and explored their contributions to everyday functional limitations in persons with mild cognitive impairment (MCI). Participants included individuals with amnestic MCI, nonamnestic MCI, and healthy older adults. As expected, the amnestic MCI group performed more poorly than the control and nonamnestic MCI groups on a content memory measure. Both MCI groups, however, performed more poorly than controls on the noncontent memory measures of prospective memory, temporal order memory, and source memory. Informants also reported that the MCI groups were experiencing greater difficulty than controls completing instrumental activities of daily living (IADLs). Noncontent memory measures were found to make an independent contribution to IADL performances over and above that of content memory. These findings demonstrate that impairments in memory beyond the traditionally assessed content memory are present in individuals with amnestic MCI and with nonamnestic MCI. The results further show that these noncontent memory processes, which have been linked with executive functioning, play a role in supporting IADLs. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Musical expertise, bilingualism, and executive functioning.

The authors investigated whether intensive musical experience leads to enhancements in executive processing, as has been shown for bilingualism. Young adults who were bilinguals, musical performers (instrumentalists or vocalists), or neither completed 3 cognitive measures and 2 executive function tasks based on conflict. Both executive function tasks included control conditions that assessed performance in the absence of conflict. All participants performed equivalently for the cognitive measures and the control conditions of the executive function tasks, but performance diverged in the conflict conditions. In a version of the Simon task involving spatial conflict between a target cue and its position, bilinguals and musicians outperformed monolinguals, replicating earlier research with bilinguals. In a version of the Stroop task involving auditory and linguistic conflict between a word and its pitch, the musicians performed better than the other participants. Instrumentalists and vocalists did not differ on any measure. Results demonstrate that extended musical experience enhances executive control on a nonverbal spatial task, as previously shown for bilingualism, but also enhances control in a more specialized auditory task, although the effect of bilingualism did not extend to that domain. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Interpersonal psychotherapy for co-occurring depression and chronic pain.

Up to 37% of individuals experience chronic pain during their lifetimes. Approximately one fourth of primary care patients with chronic pain also meet criteria for major depression. Many of these individuals fail to receive psychotherapy or other treatment for their depression; moreover, when they do, physical pain is often not addressed directly. Women, socioeconomically disadvantaged individuals, African Americans, and Latinos all report higher rates of pain and depression compared with other groups. This article describes a version of interpersonal psychotherapy tailored for patients with comorbid depression and chronic pain, interpersonal psychotherapy for depression and pain (IPT-P). IPT-P potentially could be delivered to many patient populations in a range of clinical settings, but this article focuses on its delivery within primary care settings for socioeconomically disadvantaged women. Adaptations include a brief 8-session protocol that incorporates strategies for anticipating barriers to psychotherapy, accepting patients' conceptualization of their difficulties, encouraging patients to consider the impact of their pain on their roles and relationships, emphasizing self-care, incorporating pain management techniques, and flexible scheduling. In addition, IPT-P is designed as an adjunct to usual medical pain treatment, and seeks to engage non–treatment-seeking patients in psychotherapy by focusing on accessibility and relevance of the intervention to concerns common among patients with pain. Identifying patients with comorbid depression and chronic pain and offering IPT-P as a treatment option have the potential to improve clinical outcomes for individuals with depression and chronic pain. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Dielectric properties and tunability of BST and BZT thick films for microwave applications

Abstract

Dielectric properties and tunability of Ba_0.60Sr_0.40TiO₃ (BST) and BaZr_0.25Ti_0.75O₃ (BZT) thick films and bulk ceramics have been investigated as a function of temperature (90 K - 320 K) in the kHz region. Thick films show compared to bulk ceramics low permittivity and a very broad ferroelectric phase transition which leads to low temperature dependence of tunability. Tunability of 30% can be achieved with an external field of 2 kV/mm. Measurements in the microwave region adumbrate that the dielectric losses of BZT are about three times higher than that of BST thick films.     

Relationship between strength of organic sorbate interactions in NOM and hydration effect on sorption

According to a recent conceptual model for hydration-assisted sorption of organic compounds in natural organic matter (NOM), certain polar moieties of dry NOM are unavailable for compound sorption due to strong intra- and intermolecular NOM interactions. Water molecules solvate these moieties creating new sorption sites at solvated contacts. It is expected that the greater a compound's ability to undergo specific interactions with NOM, the greater will be the hydration-assisted sorption effect, because penetration of compounds into solvated contacts must involve competition with water at the solvated contact. To test this model, we compare the hydration effect on sorption kinetics and equilibrium for 4 compounds with differing abilities to undergo specific interactions with NOM. Sorption measured on Pahokee peat in aqueous systems was fast compared with n-hexadecane (dry) systems. No concentration effect on attainment of sorption equilibrium was observed. m-Nitrophenol exhibited the greatest hydration-assisted sorption effect, benzyl alcohol showed an intermediate effect and acetophenone and nitrobenzene showed no hydration-assisted sorption, on an activity scale. The extent of hydration-assisted sorption effect correlates with compound ability to undergo specific interactions. These results support the conceptual model and demonstrate the importance of polar NOM noncovalent links in organizing the NOM phase and in controlling the hydration effect on sorption of organic compounds.     

Sorption-desorption of ionogenic compounds at the mineral-water interface: study of metal oxide-rich soils and pure-phase minerals

Sorption of the ionic compounds 2,4-D and quinmerac onto iron oxide-rich, variable charged soils was strongly influenced by mineralogy, particularly soil iron and aluminum oxides, whereas sorption of the neutral norflurazon was only related to total soil C. An appreciable fraction of the mass sorbed in stirred-flow studies was easily desorbed by deionized water, and desorption of ionic compounds was initially more rapid than sorption. This sorption-desorption behavior, although contrary to desorption hysteresis commonly observed in batch studies, suggests that the reversibly sorbed fraction is weakly bound to the soil surface. 2,4-D sorption to iron oxide-rich soils and pure-phase metal oxides appears to be driven by nonspecific electrostatic attraction, with specific electrostatic attraction and van der Waals interactions being secondary. Both the carboxylate and the heterocyclic N groups may participate in sorption of quinmerac, facilitated by specific and nonspecific electrostatic attraction and surface complexation. The heterocyclic N, amine, and carbonyl groups of norflurazon do not appear to interact with soil minerals.