全文获取类型
收费全文 | 499篇 |
免费 | 30篇 |
专业分类
电工技术 | 7篇 |
综合类 | 1篇 |
化学工业 | 123篇 |
金属工艺 | 16篇 |
机械仪表 | 18篇 |
建筑科学 | 27篇 |
矿业工程 | 5篇 |
能源动力 | 16篇 |
轻工业 | 61篇 |
水利工程 | 4篇 |
无线电 | 36篇 |
一般工业技术 | 90篇 |
冶金工业 | 35篇 |
自动化技术 | 90篇 |
出版年
2024年 | 2篇 |
2023年 | 10篇 |
2022年 | 8篇 |
2021年 | 27篇 |
2020年 | 14篇 |
2019年 | 22篇 |
2018年 | 20篇 |
2017年 | 13篇 |
2016年 | 25篇 |
2015年 | 22篇 |
2014年 | 29篇 |
2013年 | 30篇 |
2012年 | 24篇 |
2011年 | 43篇 |
2010年 | 27篇 |
2009年 | 32篇 |
2008年 | 30篇 |
2007年 | 17篇 |
2006年 | 16篇 |
2005年 | 13篇 |
2004年 | 13篇 |
2003年 | 11篇 |
2002年 | 7篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 9篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 10篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1963年 | 3篇 |
排序方式: 共有529条查询结果,搜索用时 15 毫秒
41.
This article deals with the extension of the quarry “Fischbach” in Upper Bavaria. In the quarry primarily limestone is mined, which is further transported to Rohrdorf for cement production. For the planned expansion firstly a geotechnical mapping of all benches is made. All benches are divided into segments, then gap data are taken. In addition, rock samples are taken from the mining area and uniaxial compressive tests are carried out. This data is basis of a differentiated geomechanical classification of the benches and slopes. The subsequent rock classification defines the rock strength of individual bench-areas. Furthermore, the slopes are tested on stability in actual condition and after enlargement. This happens on the one hand through a regional breakdown, on the other hand through a local viewing on benches. These stability considerations yield factors of safety and let assume a safe slope height. 相似文献
42.
Jasmin Hofstetter Carlos del Caizo Hannes Wagner Sergio Castellanos Tonio Buonassisi 《Progress in Photovoltaics: Research and Applications》2016,24(1):122-132
Silicon wafers comprise approximately 40% of crystalline silicon module cost and represent an area of great technological innovation potential. Paradoxically, unconventional wafer‐growth techniques have thus far failed to displace multicrystalline and Czochralski silicon, despite four decades of innovation. One of the shortcomings of most unconventional materials has been a persistent carrier lifetime deficit in comparison to established wafer technologies, which limits the device efficiency potential. In this perspective article, we review a defect‐management framework that has proven successful in enabling millisecond lifetimes in kerfless and cast materials. Control of dislocations and slowly diffusing metal point defects during growth, coupled to effective control of fast‐diffusing species during cell processing, is critical to enable high cell efficiencies. To accelerate the pace of novel wafer development, we discuss approaches to rapidly evaluate the device efficiency potential of unconventional wafers from injection‐dependent lifetime measurements. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
43.
采用冷却速率为0.01~3K/s的差示扫描量热法(DSC)和冷却速率更高的淬火膨胀法研究铸态Al-7Si-0.3Mg合金淬火的析出行为。在合金冷却的过程中发生了两种析出反应,高温反应开始于淬火起始温度540℃,低温反应始于400℃左右。3K/s的淬火冷却速率已经显著抑制淬火过程中相的析出。合金T6态的硬度随着淬火速率的增快而增加,这是由合金过饱和固溶度增加而导致的。通过膨胀实验和硬度实验的结果可以估计临界冷却速率大约为60K/s。通过光学显微镜观察淬火态的铸态Al-7Si-0.3Mg合金的显微组织。结果表明:根据淬火冷却速率的不同合金的显微组织由铝一硅共晶组织、铝固溶体枝晶及枝晶间的析出相组成。 相似文献
44.
Hannes Verlinde Martine De Cock Raymond Boute 《IEEE transactions on systems, man, and cybernetics. Part B, Cybernetics》2006,36(3):679-684
As opposed to quantitative association rule mining, fuzzy association rule mining is said to prevent the overestimation of boundary cases, as can be shown by small examples. Rule mining, however, becomes interesting in large databases, where the problem of boundary cases is less apparent and can be further suppressed by using sensible partitioning methods. A data-driven approach is used to investigate if there is a significant difference between quantitative and fuzzy association rules in large databases. The influence of the choice of a particular triangular norm in this respect is also examined. 相似文献
45.
Olivier Guillon Christian Elsässer Oliver Gutfleisch Jürgen Janek Sandra Korte-Kerzel Dierk Raabe Cynthia A. Volkert 《Materials Today》2018,21(5):527-536
The use of external electric and magnetic fields for the synthesis and processing of inorganic materials such as metals and ceramics has seen renewed interest in recent years. Electromagnetic energy can be utilized in different ways to improve or accelerate phase formation and stabilization, chemical ordering, densification and coarsening of particle-based materials (pore elimination and grain growth), and mechanical deformation (plasticity and creep). In these new synthesis and processing routes, the resulting microstructures and macroscopic material behavior are determined by the interaction of the applied fields with defects such as single or clustered point defects, dislocation networks, and interfaces. Multiscale experimental investigations and modeling are necessary to unveil the mechanisms underlying this field-assisted manipulation of matter. 相似文献
46.
Volker Kahlenberg Richard Albrecht Daniela Schmidmair Hannes Krüger Biljana Krüger Martina Tribus Anuschka Pauluhn 《Journal of the American Ceramic Society》2019,102(4):2084-2093
In a sequence of temperature-dependent solid-state reactions in the system CaO–Al2O3–MgO the formation of the ternary phase Ca3Al4MgO10 or C3A2M has been studied. Whereas the compound could not be prepared at 1200°C, a yield of 85 wt.-% of Ca3Al4MgO10 was obtained at 1320°C (incongruent melting point: 1330°C). Powder diffraction data compare well with results of previous investigations from the 1960s. Single crystals of Ca3Al4MgO10 could be retrieved from the sinter-pellets. Basic crystallographic data are as follows: orthorhombic symmetry, space group Pbcm, a = 5.14073(8), b = 16.7576(2), c = 10.70977(16) Å, V = 922.61(2) Å3, Z = 4. Using synchrotron diffraction data it was possible to solve the crystal structure. Least-squares refinements resulted in a residual of R(|F|) = 0.021 for 1000 independent observed reflections with I > 2σ(I) and 97 parameters. The structure contains [TO4]-tetrahedra (T=Al,Mg) forming a three-dimensional (3-D) framework whose topological characteristics have been determined. Al-Mg distributions on the different T-sites have been studied. The calcium cations are located in voids of the network. More than 50 years after its first observation our investigation clarifies the crystal structure of a compound belonging to a system that is of relevance for several fields of materials science. 相似文献
47.
Performance limits of electron holography 总被引:1,自引:0,他引:1
Lichte H 《Ultramicroscopy》2008,108(3):256-262
Transmission electron microscopy is wave optics. The object exit wave contains the full object information. However, in the usual intensity images, recorded either in real space or in Fourier space, the phases are missing. In many applications at medium and at high resolution, electron holography has shown its unique ability of solving the “missing phase problem” and utilizing the recovered phase for complete interpretation of the object structure. The question is “What are the performance limits?” with respect to field of view, lateral resolution and signal resolution. In this article, the performance limits are derived and discussed. 相似文献
48.
Daniel Kleine Manfred Mürtz Jörg Lauterbach Hannes Dahnke Wolfgang Urban Peter Hering Karl Kleinermanns 《Israel journal of chemistry》2001,41(2):111-116
Cavity ring-down spectroscopy (CRDS) is a highly sensitive laser absorption method. It can be used for quantitative analysis of molecular species at the sub-ppb level. The absorption cell (cavity) is sealed by two high-reflective mirrors on each side, which results in an effective absorption path-length of some kilometers. Our experiments for atmospheric gas analysis have been carried out so far with an Excimer pumped dye laser in the UV-VIS and a CO overtone sideband laser in the wavelength region around 3 μm. Experiments with an all solid-state difference frequency laser system will follow. In the UV-VIS region, we measured trace gas molecules like SO2, NO2, and CH2O. In the mid-infrared, around 3 μm, we measured hydrocarbons like CH4, C2H6, and C2H4 with a detection limit of less than 1 ppb. The noise equivalent absorption coefficients in the MIR are in the order of 1.7·10−9 cm−1. Due to the high data acquisition rate and the high sensitivity, CRDS enables real-time detection of trace gases in ambient air. 相似文献
49.
Volker Kahlenberg Johan P.R. de Villiers Dirk Odendaal Hannes Krüger Shengqiang Song Mithun Nath 《Journal of the American Ceramic Society》2019,102(11):6968-6979
Polycrystalline material of a novel phase in the system CaO–Al2O3–Cr2O3 has been obtained by solid-state reactions. Chemical analysis indicated the composition CaAl2Cr2O7. Single-crystal growth of the new compound using borax as a mineralizer was successful. Diffraction experiments at ambient conditions on a crystal with composition CaAl2.13Cr1.87O7 yielded the following basic crystallographic data: space group P 3, a = 7.7690(5) Å, c = 7.6463(5) Å, V = 399.68(6) Å3, Z = 3. Structure determination and subsequent least-squares refinements resulted in a residual of R(|F|) = 2.3% for 1440 independent observed reflections and 113 parameters. To the best of our knowledge, the structure of CaAl2.13Cr1.87O7 or CaAl2Cr2O7 represents a new structure type. It belongs to the group of double layer structures where individual double layers contain octahedrally and tetrahedrally coordinated cation positions. Linkage between neighboring sheet packages is provided by additional calcium cations. Furthermore, thermal expansion has been studied in the interval between 29 and 790°C using in situ high-temperature single-crystal diffraction. No indications for a structural phase transition were observed. From the evolution of the lattice parameters the thermal expansion tensor has been obtained. A pronounced anisotropy is evident. The response of structural building units to variable temperature has been discussed. 相似文献
50.
Low‐Temperature Chemical Synthesis of High‐Purity Diacylglycerols (DAG) from Monoacylglycerols (MAG)
A chemical method was developed for low‐temperature synthesis of DAG from MAG followed by an easy purification procedure in order to obtain high‐purity DAG. Solvent‐assisted and solvent‐free reaction conditions were used, combined with different catalysts (sodium methoxide, p‐toluenesulfonic acid, methanesulfonic acid, and sulfuric acid). All reactions were performed at 35 and 70 °C. By increasing both acidity and polarity of the catalyst the equilibrium shifts towards the formation of DAG. When using sulfuric acid in solvent‐assisted condition at 70 °C, 88 % conversion was obtained after 20 min of reaction (77 % w/w DAG in the reaction mixture after evaporation of the solvent). After purifying by means of column chromatography, 96 % pure DAG were obtained. The overall yield of DAG was 81 %. 相似文献