Efficiency evaluation of the photocatalytic degradation of zinc oxide nanoparticles immobilized on modified zeolites in the removal of styrene vapor from air

Styrene monomer is a volatile organic compound that has many applications in plastics, rubber, and paint manufacturing industries. Exposure to styrene vapor has certain effects, including suppression of the central nervous system, loss of concentration, weakness and fatigue, and nausea and there is a possibility of carcinogenesis in long-term exposure. Therefore, it is necessary to control and eliminate this vapor. The aim of this study was to investigate the performance of zinc oxide nanoparticles on modified natural zeolites in removing styrene vapor from the air. Natural zeolites of clinoptilolite were modified using hydrochloric acid and diphenyldichlorosilane. Next, zinc oxide nanoparticles with different ratios of 3, 5, and 10 wt% were stabilized on the zeolites. To determine their characteristics, samples were used from BET, SEM and XRD analyses. The input styrene concentration and the ratio of nanoparticles stabilized on zeolites were studied as effective functional parameters on the removal process. The efficiency results of natural zeolites (Ze) and modified zeolites (Mze) in styrene adsorption from the air show that the styrene breakthrough in the bed of MZe compared to that of Ze increases approximately two times. Also, the results showed that the removal by the process of UV/MZe-ZnO 3%, UV/MZe-ZnO 5%, and UV/MZe-ZnO 10%, was 36.5%, 40%, and 26%, respectively. From the results it can be concluded that MZe can increase the efficiency of photocatalytic degradation. Clinoptilolites of Iran can be used as an adsorbent to remove polluted air in industries that have low concentrations and flow rates.     

Thermo-mechanical vibration analysis of rotating nonlocal nanoplates applying generalized differential quadrature method

In this study, thermal and small-scale effects on the flapwise bending vibrations of a rotating nanoplate, which can be the basis of nano-turbine design, have been analyzed. The nano-turbine is made of an orthotropic nanoplate with a setting angle that is modeled based on the classical plate theory (CPT) with cantilever boundary conditions. The axial forces are also included in the model as the true spatial variation due to the rotation and temperature change. The governing equations and boundary conditions are derived according to Hamilton's principle and the governing equations are solved with the aid of the generalized differential quadrature method. The effects of small-scale parameter, nondimensional angular velocity, temperature change, and setting angles in the first four nondimensional frequencies are discussed. Due to the consideration of the rotating effects, results of this study are applicable in nano-machines, such as nano-motors, nano-rotor, and other rotating nano-structures. Also, by considering the effect of thermal loading on rotation of a nanoplate, the results are useful in the design of nano-turbines.     

A model of homeless migration: homeless men in Skid Row,Los Angeles

"In this paper a conceptual model of homeless migration is developed that links migration behavior with the coping status of homeless individuals. The model is evaluated by using data drawn from a recent random probability sample of men surveyed in Skid Row, Los Angeles, [California]. Results indicate that homeless migrants tended to be young, never married, white, mentally disabled, and either newly or cyclically homeless individuals. Long-term residents, in contrast, were apt to be older, physically disabled or suffering from a health-related problem, and had been homeless for some time. The dominant reason given for moving was to find a job...." Coping strategies and migration behaviors are also described.     

Accelerating development with agent components

As the demand for more flexible, adaptable, extensible, and robust Web based enterprise application systems accelerates, adopting new software engineering methodologies and development strategies becomes critical. These strategies must support the construction of enterprise software systems that assemble highly flexible software components written at different times by various developers. Traditional software development strategies and engineering methodologies, which require development of software systems from scratch, fall short in this regard. Component based software engineering offers an attractive alternative for building Web based enterprise application systems. CBSE works by developing and evolving software from selected reusable software components, then assembling them within appropriate software architectures. By promoting the use of software components that commercial vendors or in-house developers build, the component based software development approach promises large scale software reuse     

In-situ EQCM evaluation of the formation of UPD and OPD during electrodeposition of Pb on gold

Underpotential (UPD) and overpotential (OPD) deposition of Pb from a perchlorate solution on gold substrate was studied using in-situ electrochemical quartz crystal microbalance (EQCM) method. Cyclic voltammograms and current-transients recorded during potentiostatic electrochemical deposition were measured simultaneously with EQCM data including frequency and resistance. Results show that underpotential deposition (UPD) of Pb occurs before overpotential deposition (OPD) of Pb starts to grow, based on both massogram and cyclic voltammogram. The OPD of Pb grows at higher overpotentials which significantly influence the mechanism of nucleation and growth. EQCM reveals that the mass to charge ratio of OPD is different at different overpotentials, owing to the mechanism of nucleation and growth and possible roughening of grown Pb or hydrogen evolution. A comparison between our experimental data with the Scharifker-Hills theory based on non-dimensional plots shows an instantaneous mechanism. Scanning electron microscope taken from the electrodeposited lead on gold confirms the behaviour exhibiting almost same size of nuclei.     

Effects of high fat diet and cholecystokinin receptor blockade on pancreatic growth and tumor initiation in the hamster

The mechanism by which high-fat diet potentiates pancreatic cancer is not known, but trophic hormones may be involved. In preliminary growth studies, hamsters fed a high fat diet (17.5% lard, 17.5% corn oil) for 14 days showed a 16.3% increase (P < 0.01) in pancreatic weight compared to controls on low fat diet (2.5% lard, 2.5% corn oil). A significant increase was also seen at 28 days. Similar increases were seen in pancreatic DNA (29%, P < 0.01) and pancreatic RNA (22%, P < 0.05) at 14 days. Plasma cholecystokinin (CCK) levels at 14 days were 2.5 fold higher in the animals fed high fat (P < 0.01). Infusion of the CCK antagonist MK329 (25 nmol/kg/h) completely abolished the increase in pancreatic weight, pancreatic DNA and pancreatic RNA. The effect of CCK receptor blockade during the initiation period of carcinogenesis was investigated in hamsters fed the same diets used in the growth studies. One hundred animals received a single injection of N-nitrosobis(2-oxopropyl)amine, (BOP, 20 mg/kg). Half of the hamsters in each diet group received a 2 week infusion of MK329 (25 nmol/kg/h), beginning 8 days before carcinogen administration. At the time of death, 55 weeks after carcinogen administration, non-fasting plasma CCK levels were 31% higher in the high fat fed hamsters than in the low fat fed animals (P < 0.01). The high-fat diet group had a 3-fold increase in total cancer incidence and a 5-fold increase in advanced lesions (adenocarcinomas). Tumor incidence and yield were not changed in either diet group by CCK-receptor blockade during the initiation period. Cholecystokinin appears to mediate the short-term trophic effect that high-fat feeding has on the pancreas. However, potentiation of pancreatic cancer by high-fat diet in the hamster cancer model does not appear to be influenced by endogenous cholecystokinin at the time of tumor induction.     

A mathemathical model for the calculation of the concentration at the outlet of an ozone generator

A mathematical model was generated to predict the composition of the outlet gas of ozone generators. In order to make the modelling possible it was important to predict the occurrence time and the exact location of each individual discharge zone. This was done by connecting a specially constructed ozone generator, which would locate the discharge zones, to a nanosecond pulse generator which would impose regular occurrence times for discharge columns. The experimental and theoretical outlet concentrations of this ozone generator were compared. The result was an excellent match which justified the assumptions made in the model. The mathematical model was also used to study the effect of different factors affecting the production of ozone.     

Pancreatic neoplasms induced in Syrian golden hamsters. I. Scanning electron microscopic observations

Pancreases from Syrian golden hamsters treated with N-nitrosobis(2-hydroxy-proply)amine for 10 to 25 weeks were examined under scanning electron microscopy (SEM). Findings indicate that the neoplasms originated from the ductal epithelium and developed progressively. Adenomas were lined by epithelium of differing cells types, ranging from a flat singly ciliated form to cuboidal-columnar types, or to mixed cell populations. The epithelial lining of the ductal carcinomas exhibited tubular and papillary cystic spaces, and cell surfaces were similar to the cuboidal and columnar epithelium of adenomas and of ductal epithelial hyperplasia. However, microvilli were dense and of varied lengths. The SEM observations correlated with patterns seen in routine histologic preparations.     

Elastic buckling of circular annular plate reinforced with carbon nanotubes

The buckling analysis of circular annular plate reinforced by carbon nanotubes (CNTs) subjected to compressive and torsional loads with various axially symmetric boundary conditions are studied in this paper. The developed model is based on the classical laminated plate theory (CLPT). The Mori‐Tanaka method is employed to calculate the effective elastic modulus of composites having aligned oriented straight CNTs. The eigenvalues of the problem are obtained by means of an analytical approach based on the optimized Rayleigh‐Ritz method. The effects of CNTs orientation angles, edge conditions, geometric ratio of plate and agglomeration of the randomly oriented straight CNTs are investigated on the critical buckling loads. Extensive studies validity of the results based on available data have been carried out prior to the presentation of salient results of this analysis. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers