Study on the inhibiting behavior of AMT on bronze in 5% citric acid solution

The corrosion behavior of bronze in the presence of 2-amino-5-mercapto-1,3,4-thiadiazole (AMT) has been investigated in 5% citric acid by electrochemical measurements such as potentiodynamic polarization method and electrochemical impedance spectroscopy (EIS). It has been revealed that AMT is a good inhibitor for bronze. Both cathodic process and anodic process on bronze treated with AMT were different from that on the bronze without AMT treatment. Fourier transform infrared (FTIR) analysis was carried out to characterize the protective film, which revealed that the composition of the protective film was polymeric Cu(I)-inhibitor complex. AMT acted as bidentate ligand through the aminic nitrogen atom and the closed ring nitrogen in the complex.     

典型电子现金系统的分析及其安全需求

文章设计了一种电子现金系统,关键是对安全性、效率、成本等进行综合考虑。从这些方面入手,论文分析了三种典型的电子现金系统—D.Chaum方案、S.Brands方案和T.okamoto方案。然后,结合匿名通信协议,提出如何更好地满足顾客利用公开网络进行安全通信的需求。     

基于模式理论光栅椭偏参数反演的数值模拟

将一种广泛用于求解系统优化问题的方法——正单纯形法，求解光栅的椭偏方程。首先，利用求解光栅的傅立叶模式理论对TE和TM波的复反射系数进行求解。然后计算出其相应的椭偏参数(△，Ψ)，并在该值的基础上加入不同偏差的随机高斯噪声，将加入噪声后的值(△m，Ψm)作为模拟测量值。最后使用优化算法进行反演。通过对几种常用面形光栅椭偏参数的数值模拟，一方面表明傅立叶模式理论计算光栅的椭偏参数不仅精度高。而且速度快；另一方面表明利用正单纯形法得到的光栅参数值很接近于正演时假设的参数值，从而从理论上证明了利用椭偏法测量光栅各种光学参数的可行性。     

一种计算机实时控制系统的分析及其DCS实现

简述了计算机实时控制及分布式控制系统(DCS)的一般特点．并以某型水下机器人的控制系统为例，详细介绍了一种小型实时DCS系统的具体实现。     

系统仿真技术在控制系统中的应用

系统仿真技术是一种以对实际系统建立正确的数学模型为基础，以计算机为工具的对实际系统进行模拟的技术。计算机技术的高速发展，使系统仿真技术在各个领域中都得到了广泛的应用。以化工及工业锅炉自动控制系统中水箱系统的液位控制问题为例，阐述了系统仿真技术在自动控制领域中的应用。     

Preparation, patterning and luminescent properties of nanocrystalline Gd2O3:A (A=Eu, Dy, Sm, Er) phosphor films via Pechini sol–gel soft lithography

Nanocrystalline Gd₂O₃:A (A=Eu³⁺, Dy³⁺, Sm³⁺, Er³⁺) phosphor films and their patterning were fabricated by a Pechini sol–gel process combined with a soft lithography. X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM) and optical microscopy, UV/vis transmission and photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting films. The results of XRD indicated that the films began to crystallize at 500 °C and that the crystallinity increased with the elevation of annealing temperatures. Uniform and crack free non-patterned phosphor films were obtained by optimizing the composition of the coating sol, which mainly consisted of grains with an average size of 70 nm and a thickness of 550 nm. Using micro-molding in capillaries technique, we obtained homogeneous and defects-free patterned gel and crystalline phosphor films with different stripe widths (5, 10, 20 and 50 μm). Significant shrinkage (50%) was observed in the patterned films during the heat treatment process. The doped rare earth ions (A) showed their characteristic emission in crystalline Gd₂O₃ phosphor films due to an efficient energy transfer from Gd₂O₃ host to them. Both the lifetimes and PL intensity of the rare earth ions increased with increasing the annealing temperature from 500 to 900 °C, and the optimum concentrations for Eu³⁺, Dy³⁺, Sm³⁺, Er³⁺ were determined to be 5, 0.25, 1 and 1.5 mol% of Gd³⁺ in Gd₂O₃ films, respectively.     

Gamma-irradiation-induced Ag/SiO2 composite films and their optical absorption properties

Small Ag particles or clusters dispersed mesoporous SiO₂ composite films were prepared by a new method: First the matrix SiO₂ films were prepared by sol-gel process combined with the dip-coating technique, then they were soaked in AgNO₃ solutions followed by irradiation of γ-ray at room temperature and in ambient pressure. The structures of these films were examined by X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), and optical absorption spectroscopy. It has been shown that the Ag particles grown within the porous SiO₂ films are very small, and they are isolated and dispersed from each other with very narrow size distributions. With increasing the soaking concentration and an additional annealing, an opposite peakshift effect of the surface plasmon resonance (SPR) was observed in the optical absorption measurements.     

光通信技术发展的新亮点

自光通信问世以来，经历了研究探索、实用化、推广应用、快速发展等时期，直至2001年，达到急剧发展的高潮。随着世界经济的滑坡，通信行业的不景气，使光通信也进入了寒冷的冬天。实际上，即使在经济低速的时期，光通信的技术依然没有停止发展，而且出现了不少继续将光通信推向前进的新亮点。从技术和应用的角度，简要介绍一些光通信的新技术。     

油井封堵注水泥一次不留管柱堵水工具

吉林油田开发到中后期,油井出水现象日趋复杂,以往的注水泥堵水技术均不能满足现状的要求。鉴于此,研制出油井封堵注水泥一次不留管柱堵水工具,并形成了水泥堵水新工艺。该工具的核心为封堵注水泥装置,由打压坐封总成、胶塞座丢手总成、注水泥器本体总成和单流定压器总成等4部分组成,具有打压坐封、注水泥、投胶塞和丢手等一次性功能。经过现场6口井的施工,无一口井发生卡井事故,施工有效率100%,成功率100%。