Basic studies leading to the development of an ultrahigh strength,high fracture toughness low-alloy steel

Ultrahigh strength steels have been used increasingly in recent years for critical aircraft and aerospace structural applications. In such applications, though materials performance is of prime consideration, cost and availability makes the low-alloy steels an attractive option. This paper describes the development of an ultrahigh strength NiSiCrCoMo low-alloy steel, supported by significant findings obtained from the basic studies that were aimed at understanding how solute additions influence fracture resistance of iron, with and without the presence of carbon. The results of the basic studies, in combination with the work of Garrison (1986) on a NiSiCr steel, have profitably been employed in the development of a NiSiCrCoMo low-alloy steel possessing a strength-toughness combination quite comparable to the highly alloyed 250-grade maraging steel. Reproducibility of attractive strength and toughness properties has been established in tonnage scale melts. This steel, in the softened condition, has good formability and machinability. Weld parameters have also been established. The NiSiCrCoMo low-alloy steel thus meets the requirements of performance and cost rendering it an attractive option for advanced structural applications.     

A comparative evaluation of low-cycle fatigue behavior of type 316LN base metal, 316 weld metal,and 316LN/316 weld joint

A comparative evaluation of the low-cycle fatigue (LCF) behavior of type 316LN base metal, 316 weld metal, and 316LN/316 weld joints was carried out at 773 and 873 K. Total strain-controlled LCF tests were conducted at a constant strain rate of 3 × 10⁻³ s⁻¹ with strain amplitudes in the range ±0.20 to ±1.0 pct. Weld pads with single V and double V configuration were prepared by the shielded metal-arc welding (SMAW) process using 316 electrodes for weld-metal and weld-joint specimens. Optical microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) of the untested and tested samples were carried out to elucidate the deformation and the fracture behavior. The cyclic stress response of the base metal shows a very rapid hardening to a maximum stress followed by a saturated stress response. Weld metal undergoes a relatively short initial hardening followed by a gradual softening regime. Weld joints exhibit an initial hardening and a subsequent softening regime at all strain amplitudes, except at low strain amplitudes where a saturation regime is noticed. The initial hardening observed in base metal has been attributed to interaction between dislocations and solute atoms/complexes and cyclic saturation to saturation in the number density of slip bands. From TEM, the cyclic softening in weld metal was ascribed to the annihilation of dislocations during LCF. Type 316LN base metal exhibits better fatigue resistance than weld metal at 773 K, whereas the reverse holds true at 873 K. The weld joint shows the lowest life at both temperatures. The better fatigue resistance of weld metal is related to the brittle transformed delta ferrite structure and the high density of dislocations at the interface, which inhibits the growth rate of cracks by deflecting the crack path. The lower fatigue endurance of the weld joint was ascribed to the shortening of the crack initiation phase caused by surface intergranular crack initiation and to the poor crack propagation resistance of the coarse-grained region in the heat-affected zone.     

Characterization of poly(vinyl alcohol)/sodium bromide polymer electrolytes for electrochemical cell applications

Sodium‐ion conducting polymer electrolytes based on poly(vinyl alcohol) complexed with sodium bromide were prepared with a solution‐casting technique. The structure of these films was determined with X‐ray diffraction, and the complexation of the salt with the polymer was confirmed with Fourier transform infrared spectroscopy studies. Electrical conductivity was measured with an alternating‐current impedance analyzer in the frequency range of 100 Hz to 1 MHz and in the temperature range of 303–373 K. It was observed that the magnitude of conductivity increased with the increase in the salt concentration as well as the temperature. The nature of the charge transport in these polymer electrolyte films was determined with both Wagner's polarization technique and the Watanabe technique. The dominant conducting species were found to be ions, particularly anions. Optical absorption studies were performed in the wavelength range of 200–600 nm, and the absorption edge, direct band gap, and indirect band gap values were evaluated. Electrochemical cells were fabricated, and their discharge characteristics were studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

媒体服务中流式拷贝性能分析

随着网络带宽的进一步提高,视频点播的瓶颈基本卡在视频服务器端。文章提供的服务器端的流式拷贝,能进一步提高整个系统的服务能力。文章对流式拷贝的过程进行描述,对其中的数学模型进行分析,并与没有流式拷贝的系统进行比较分析。     

Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios

Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, ²⁷Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH₃. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH₃ adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities.     

利用串行RapidIO连接功能增强DSP协处理能力

SRIO IP解决方案提供真实双向数据流,大大增强连接功能。目前,对高速通信与超快计算的需求正与日俱增。有线和无线通信标准的应用随处可见,数据处理架构每天都在扩展。较为普遍的有线通信方式是以太网(LAN、WAN和MAN网络)。手机通信是最为常见的无线通信方式,由应用了DSP的     

A new chip-thickness model for performance assessment of silicon carbide grinding

The chip-thickness models, used to assess the performance of grinding processes, play a major role in predicting the surface quality. In the present paper, an attempt has been made to develop a new chip-thickness model for the performance assessment of silicon carbide grinding by incorporating the modulus of elasticities of the grinding wheel and the workpiece in the existing basic chip-thickness model to account for elastic deformation. The new model has been validated by conducting experiments, taking the surface roughness as a parameter of evaluation .     

Chrestenson函数序列的生成方法及其数学分析

本文提出了适于三种序号的Ｃｈｒｅｓｔｅｎｓｏｎ函数序列的复制方法，对其复制过程进行了数学分析，并指出当Ｃｈｒｅｓｔｅｎｓｏｎ函数退化为Ｗａｌｓｈ函数时，此方法即为复制理论中的平移复制方法。