The Impact of Sequential Fluorination of π‐Conjugated Polymers on Charge Generation in All‐Polymer Solar Cells

The performance of all‐polymer solar cells (all‐PSCs) is often limited by the poor exciton dissociation process. Here, the design of a series of polymer donors ( P1 – P3 ) with different numbers of fluorine atoms on their backbone is presented and the influence of fluorination on charge generation in all‐PSCs is investigated. Sequential fluorination of the polymer backbones increases the dipole moment difference between the ground and excited states (Δµ_ge) from P1 (18.40 D) to P2 (25.11 D) and to P3 (28.47 D). The large Δµ_ge of P3 leads to efficient exciton dissociation with greatly suppressed charge recombination in P3 ‐based all‐PSCs. Additionally, the fluorination lowers the highest occupied molecular orbital energy level of P3 and P2 , leading to higher open‐circuit voltage (V_OC). The power conversion efficiency of the P3 ‐based all‐PSCs (6.42%) outperforms those of the P2 and P1 (5.00% and 2.65%)‐based devices. The reduced charge recombination and the enhanced polymer exciton lifetime in P3 ‐based all‐PSCs are confirmed by the measurements of light‐intensity dependent short‐circuit current density (J_SC) and V_OC, and time‐resolved photoluminescence. The results provide reciprocal understanding of the charge generation process associated with Δµ_ge in all‐PSCs and suggest an effective strategy for designing π‐conjugated polymers for high performance all‐PSCs.     

Thermal annealing effect on zinc nitride thin films deposited by reactive rf-magnetron sputtering process

Zinc nitride films were deposited by reactive radio-frequency magnetron sputtering using a zinc target in a nitrogen and argon plasma. The deposited films were annealed in either air or O₂ at 300 °C to investigate the annealing effect on the microstructure, optical properties, and electronic characteristics of zinc nitride films. It was found that the annealing process decreased the crystallinity of zinc nitride films. It was also found that the optical band gap decreased from 1.33 eV to 1.14 eV after annealing. The analysis of film composition suggested that the concentration of oxygen increased slightly after annealing. Although the conduction type of both as-deposited and annealed films were n-type, the annealed films exhibited a higher resistivity, lower carrier concentration and lower mobility than the as-deposited films. Also, it was found that the as-deposited films did not exhibit any photoconducting behavior whereas the annealed films exhibited a pronounced photoconducting behavior.     

Template Deformation‐Tailored ZnO Nanorod/Nanowire Arrays: Full Growth Control and Optimization of Field‐Emission

Here, a facile and effective route toward full control of vertical ZnO nanorod (NR)/nanowire (NW) arrays in centimeter‐scale areas and considerable improvement of field‐emission (FE) performance is reported. Controlled deformation of colloidal crystal monolayer templates is introduced by heating near glass‐transition temperature. The NR/NW density, uniformity, and tapering were all adjusted through selection of template size and deformation, and electrolyte composition. In line with the adjustments, the field‐emission performance of the arrays is significantly improved. A low turn‐on electric field of 1.8 V µm^?1, a field‐enhancement factor of up to 5 750, and an emitting current density of up to 2.5 mA cm^?2 were obtained. These improved parameters would benefit their potential application in cold‐cathode‐based electronics.     

Development of a Highly Selective,Sensitive, and Fast Response Upconversion Luminescent Platform for Hydrogen Sulfide Detection

Hydrogen sulfide (H₂S) has been recognized as one of most important gaseous signaling molecules mediated by a variety of physiological and pathological processes. Yet, its functions remain largely elusive due to the lack of potent monitoring methods. Hereby this issue is addressed with a powerful new platform—dye‐assembled upconversion nanoparticles (UCNPs). A series of chromophores with different absorption bands and fast responses towards H₂S is combined with UCNPs and results in a library of H₂S sensors with responsive emission signals ranging from the visible to the near‐infrared (NIR) region. These nanoprobes demonstrate highly selective and rapid responses to H₂S in vitro and in cells. Furthermore, H₂S levels in blood can be detected using the developed nanoprobes. Hence the reported H₂S sensing platform can serve as a powerful diagnostic tool to research H₂S functions and to investigate H₂S‐related diseases.     

Simulation model for sizing of stand-alone solar PV system with interconnected array

Solar PV arrays made of interconnected modules are comparatively less susceptible to shadow problem and power degradation resulting from the aging of solar cells. This paper presents a simulation model for the sizing of stand-alone solar PV systems with interconnected arrays. It considers the electricity generation in the array and its storage in the battery bank serving the fluctuating load demand. The loss of power supply probability (LPSP) is used to connote the risk of not satisfying the load demand. The non-tracking (e.g., fixed and tilted) and single-axis tracking aperture arrays having cross-connected modules of single crystalline silicon solar cells in a (6×6) modular configuration are considered. The simulation results are illustrated with the help of a numerical example wherein the load demand is assumed to follow uniform probabilistic distribution. For a given load, the numbers of solar PV modules and batteries corresponding to zero values of LPSP on diurnal basis during the year round cycle of operation are presented. The results corresponding to the surplus and deficit of energy as a function of LPSP are also presented and discussed to assess the engineering design trade offs in the system components.Furthermore, a simple cost analysis has also been carried out, which indicates that for Delhi the stand-alone solar PV systems with fixed and tilted aperture arrays are better option than those with single-axis tracking aperture (with north–south oriented tracking axis) arrays.     

Development of Apparels from Silk Waste and Pineapple Leaf Fiber

The degummed mulberry silk waste and eri silk waste were blended with degummed and bleached pineapple leaf fibers (PALF) at fiber stage in different proportions, and spun into yarn in a jute spinning system. The 90-tex blended yarn thus developed was analyzed for different physico-mechanical properties. Properties of fabric developed in a traditional handloom using 2/40-s cotton as warp and blended yarn as weft were also analyzed. The quality parameters, viz., tensile property, crease recovery, fabric cover, stiffness, drape, and thickness of the developed fabric, met essential apparel requirements. A comparative subjective evaluation of the fabric quality, viz., aesthetic appearance, luster, and texture, was made with the help of a group of people from different age, educational, and occupational background to examine its marketability; all respondents felt that appearance of PALF with silk waste was excellent. Texture and luster were found to be from medium to moderate. About 95% of respondents felt that fabric was crispy.     

Potentiality of Indian pineapple leaf fiber for apparels

The use of textile-grade fiber extracted from the Indian pineapple leaf is an unexplored area. Pineapple leaf fiber (PALF) is fine, soft, and moderately strong and is much acceptable for fashion garment. An attempt has been made to extract and soften Indian PALF from the pineapple leaves by decortication and subsequent water retting. Decorticated cum retted fiber has shown better physicomechanical and surface appearance properties than decorticated fiber. Fine yarn (38 tex) was spun in a suitable spinning system, and the property performance was found to be suitable to make eco-sustainable novelty fabric. Fabric was developed by using cotton as warp yarn and PALF-based yarn as weft in a handloom. The developed fabric shows very good physical and mechanical properties, desired for apparels. This inferred that Indian PALF may be successfully used to make eco-niche apparel quality fabric as well as novelty textiles.     

Microbial Decontamination of Tea (Camellia sinensis) by Gamma Radiation

ABSTRACT:  Processed dry tea leaves are prone to microbial contamination during post-processing handling and storage. The dry tea leaves may thus carry bacteria and fungi of potential health risk to consumers. Also, during storage under high humidity, absorption of moisture may encourage fungal growth and result in caking of the product. Gamma radiation processing was tried as a method for microbial decontamination. A radiation dose of 5 kGy was found to be effective for this purpose. No significant effect was observed on total phenolics in radiation-processed tea leaves. The antioxidant and biological properties of tea such as free radical scavenging activity, inhibition of xanthine oxidase and lipid peroxidation, and superoxide and nitrite scavenging activities were not affected due to radiation treatment within a dose of 10 kGy. The antimicrobial and sensory properties were also unaffected by the radiation treatment.     

Shelf-Life Extension of Fresh Ginger (Zingiberofficinale) by Gamma Irradiation

ABSTRACT: Gamma irradiation was found to extend the shelf life of farm fresh ginger. A 5-kGy radiation dose and 10 °C storage temperature were found to keep peeled ginger samples microbe free and acceptable until 70 d of storage, whereas nonirradiated (control) peeled ginger spoiled within 40 d under similar storage conditions. The decrease in 6-gingerol, the compound responsible for the pungency of ginger, was found to be insignificant after irradiation.