An approximate elastoplastic analysis of the effect of plane strain at the surface of a notch

An approximate elastoplastic analysis of a notch in plane strain is developed using an extended Neuber approach. The multiaxial stress/strain state at the notch surface is dependent upon a parameter which is readily obtained from the numerical solution of a transcendental equation for each level of the net section stress. Excellent agreement with the results of a finite element analysis of a double-edge-notched specimen was obtained.     

J-R curve determination of magnesium hydroxide filled polypropylene using the normalization method

The normalization method is applied to different magnesium hydroxide filled polypropylenes. As the load separation principle is the basis of the method, its validity is checked using the load separation criterion developed by Sharobeam and Landes. Load separability is checked for all the materials when the condition of stationary crack length is fulfilled. During the determination of the deformation function using the normalization method, the large decrease of the load value of highly filled materials make it impossible to describe the load normalization variation with plastic displacement by a power law equation. Nevertheless, for the lower-filled materials, i.e. up to 40 wt% with copolymer PP and 20 wt% with homopolymer PP, the J-R curve can be determined and high concordance is found with the J-R curve obtained by multiple specimen method. The applicability of the normalization method is discussed in terms of the geometry of the plastic deformation zone. It is found that the materials that are not suitable for normalization method application are characterized by a very small plastic zone, due to the restriction of plastic flow caused by mineral filler.     

Applying Projection‐Based Methods to the Asymmetric Traffic Assignment Problem

This article examines the application of a path‐based algorithm to the static and fixed demand asymmetric traffic assignment problem. The algorithm is of the simplicial decomposition type and it solves the equilibration or master problem step by means of five existing projection methods for variational inequality problems to evaluate their performance on real traffic networks. The projection methods evaluated are: (1) a cost approximation‐based method for minimizing the Fukushima's gap function, (2) the modified descent method of Zhu and Marcotte ( 1988 ), (3) the double projection method of Khobotov ( 1987 ) and three of its recently developed variants (Nadezhkina and Takahashi, 2006 ; Wang et al., 2010 ; and He et al., 2012); (4) the method of Solodov and Svaiter ( 1999 ); and (5) the method of Solodov and Tseng ( 1996 ). These projection methods do not require evaluation of the Jacobians of the path cost functions. The source for asymmetries are link costs with interactions, as in the case of priority ruled junctions. The path‐based algorithm has been computationally tested using the previous projection methods on three medium to large networks under different levels of congestion and the computational results are presented and discussed. Comparisons are also made with the basic projection algorithm for the fixed demand asymmetric traffic assignment problem. Despite the lack of monotonicity properties of the test problems, the only method that failed to converge under heavy congestion levels was the basic projection algorithm. The fastest convergence was obtained in all cases solving the master problem step using the method of He et al. (2012), which is a variant of Khobotov's method.     

Concentrations and patterns of organochlorine pesticides and PCBs in Mediterranean monk seals (Monachus monachus) from Western Sahara and Greece

Blubber from Mediterranean monk seals (Monachus monachus) from the Western Sahara coast (Atlantic), sampled during 1996-1999, and from the Greek coast (Mediterranean), sampled during 1995-1999, was analyzed for organochlorine pollutants (OCs). In both populations, no significant difference was found between sexes. In the Atlantic population, mature females presented greater percentages of higher chlorinated PCB (polychlorinated biphenyl) congeners in relation to total PCBs (sum of 25 congeners) than pups, indicating a differential transfer of PCB congeners through lactation. In the Mediterranean, the reduced sample size of adult individuals precluded proper statistical investigation of age-related variation. Significant differences in concentrations and pollutant patterns were found between populations. Thus, Mediterranean individuals presented significantly higher levels of HCB (hexachlorobenzene), tPCB, and DDTs (dichlorodiphenyltrichloroethane) concentrations and DDE/tDDT and tDDT/tPCB ratios than their counterparts from the Atlantic. Moreover, the relative proportion of different congeners in relation to the total PCB load (congener/tPCB) was also different between the two areas. The 100*tDDT/tPCB ratio in Atlantic seals was 38.46, which indicates a predominance of industrial inputs over those associated with agriculture. Conversely, in the Mediterranean seal population, the 100*tDDT/tPCB ratio was 177.1, denoting a proportionally higher contribution of pollutants of agricultural origin.     

Assessment of the suitability of soil amendments to reduce 137Cs and 90Sr root uptake in meadows

In situ remediation strategies are an alternative approach in the management of radioactive contaminated areas, especially when based on modification of soil properties by the addition of amendments. Here, this strategy is applied to reduce 137Cs and 90Sr soil-plant transfer in meadows from areas of Russia, Belarus, and Ukraine affected by the Chernobyl fallout. Meadows were established on podzolic and peaty soils. Amendments covered a wide range of materials, such as loamy and sandy soils, polygorskite clay, phosphorite, turf, and sapropel. Field experiments showed the poor efficiency of most of the materials: only the polygorskite clay provoked a notable reduction (1.5-2-fold) in 137Cs root uptake. Subsequent laboratory characterization showed the lack of significant changes in the radiocesium interception potential and soil solution composition in the amended soils, a fact that helped to explain the lack of effect on the reduction of transfer. Moreover, a laboratory methodology based on the quantification of the adsorption potential of the amendments and the reversibility of the adsorption process was applied. This methodology was first proposed for the correct selection of the suitable materials to be used to decrease radionuclide root uptake in future remediation actions and then validated with data of the previous field experiments.     

Factors influencing the soil-air partitioning and the strength of soils as a secondary source of polychlorinated biphenyls to the atmosphere

Soils are a major reservoir of persistent organic pollutants, and soil-air partitioning and exchange are key processes controlling the atmospheric concentrations and regional fate of pollutants. Here, we report and discuss the concentrations of polychlorinated biphenyls (PCBs) in soils, their measured fugacities in soil, the soil-air partition coefficients (K(SA)) and soil-air fugacity gradients in rural background areas of N-NE Spain and N-NW England. Four sampling campaigns were carried out to assess seasonal and daily variability and differences between sampling sites. K(SA) values were significantly dependent on soil temperature and soil organic matter quantity, and to a minor extent organic matter type. All the PCB congeners in the soil are close to equilibrium with the atmosphere at rural Ebro sites, but soil fugacities tend to be higher than ambient air fugacities in early and late summer, consistent with the influence of temperature on soil-air partitioning. Therefore, during warm periods, soils increment their strength as secondary sources to the atmosphere. The mixture of PCBs found in the atmosphere is clearly strongly influenced by the mixture of PCBs which escape from soil, with significant correlations between them (R(2) ranging between 0.35 and 0.74 and p-level <0.001 for the Ebro sampling sites). Conversely, the close-to-equilibrium to net sink status of rural UK sites, suggest a close coupling of air and soil concentrations, but it is not possible to elucidate the importance of these soils as secondary sources yet, and presumably there are still significant primary sources to the regional/global environment.     

International comparison of power measurements at 33 GHz(GT-RF/92-4)

A measurement comparison of effective efficiency has been carried out between eight national metrology laboratories at 33 GHz in rectangular waveguide IEC R320. Two waveguide thermistor mounts were measured. The following national laboratories participated: BNM-LCIE (France), NIST (U.S.), NRC (Canada), KRISS (Korea), CSIRO (Australia), PTB (Germany), NMi VSL (The Netherlands), and NPL (U.K.). The Bureau National de Metrologie-Laboratoire Central des Industries Electriques (France) acted as the pilot laboratory for the comparison. Excellent harmony is observed between results given by the participants, especially for the item LCIE-92021     

Antioxidant Activity of Added Phenolic Compounds in Freeze-Dried Microencapsulated Sunflower Oil

This study was aimed at evaluating the effectiveness of phenolic antioxidants with a similar structure but having a different polarity in dried microencapsulated sunflower oil. The antioxidants tested were, on one hand, α-tocopherol and its water soluble analogue, Trolox, and on the other, gallic acid and its ester derivatives, propyl gallate and dodecyl gallate. At a moderate temperature (40 °C), the samples were oxidized under accelerated conditions by using Cu(II) as an oxidation catalyst. The progress of oxidation was followed up over time in the free and encapsulated oil fractions. The peroxide value, the total content of polymers and, when appropriate, the content of α-tocopherol were determined. Quantitative analysis of the total fraction of the non-volatile oxidation products and their distribution in oligomers, dimers and monomers was applied to samples to obtain a complete evaluation of oxidation. Finally, as a complementary measure, the antioxidants were also assessed by direct application of the Rancimat test at 100 °C on the dried microencapsulated oil samples. Results showed that the antioxidants of lower polarity in each series, i.e. tocopherol and dodecyl gallate, were to a great extent the most protective antioxidants. The results obtained by the Rancimat test were consistent with those found during oxidation at moderate temperature. Furthermore, the addition of Cu(II) reduced proportionally the oxidative stability index of the dried microencapsulated samples.     

The product of the cph oncogene is a truncated, nucleotide-binding protein that enhances cellular survival to stress

Cph was isolated from neoplastic Syrian hamster embryo fibroblasts initiated by 3-methylcholanthrene (MCA), and was shown to be a single copy gene in the hamster genome, conserved from yeast to human cells, expressed in fetal cells and most adult tissues, and acting synergistically with H-ras in the transformation of murine NIH3T3 fibroblasts. We have now isolated Syrian hamster full-length cDNAs for the cph oncogene and proto-oncogene. Nucleotide sequence analysis revealed that cph was activated in MCA-treated cells by a point-mutational deletion at codon 214, which caused a shift in the normal open reading frame (ORF) and brought a translation termination codon 33 amino acids downstream. While proto-cph encodes a protein (pcph) of 469 amino acids, cph encodes a truncated protein (cph) of 246 amino acids with a new, hydrophobic C-terminus. Similar mechanisms activated cph in other MCA-treated Syrian hamster cells. The cph and proto-cph proteins have partial sequence homology with two protein families: GDP/GTP exchange factors and nucleotide phosphohydrolases. In vitro translated, gel-purified cph proteins did not catalyze nucleotide exchange for H-ras, but were able to bind nucleotide phosphates, in particular ribonucleotide diphosphates such as UDP and GDP. Steady-state levels of cph mRNA increased 6.7-fold in hamster neoplastic cells, relative to a 2.2-fold increase in normal cells, when they were subjected to a nutritional stress such as serum deprivation. Moreover, cph-transformed NIH3T3 cells showed increased survival to various forms of stress (serum starvation, hyperthermia, ionizing radiation), strongly suggesting that cph participates in cellular mechanisms of response to stress.