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排序方式: 共有598条查询结果,搜索用时 15 毫秒
21.
Nirmal Kumar Karan Samiran Mitra Georgina Rosair David J. Jenkins K. M. Abdul Malik 《Inorganic chemistry communications》2001,4(12)
A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba2(phen)4(H2O)6Fe(CN)6]·Cl·2(phen)·3H2O}n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba2(phen)4(H2O)6] units are bridged through two trans CN groups of [Fe(CN)6]3− ion, which results in the formation of a zig-zag polymeric chain. In each [Ba2(phen)4(H2O)6] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together. 相似文献
22.
Effect of glucose oxidase and mixing time on soluble and insoluble wheat flour protein fractions: Changes on SH groups and H2O2 consumption 总被引:1,自引:0,他引:1
Juan C. Pescador-Piedra Reynold R. Farrera-Rebollo Georgina Calderón- Domínguez 《Food science and biotechnology》2010,19(6):1485-1491
Glucose oxidase (GOX) has been recognized as an alternative to substitute chemical oxidants in bread making, however the action
exerted on wheat flour proteins by the H2O2 produced is still unclear. Looking for a better understanding of the role of GOX and H2O2 in the bread making process, the effect of varying GOX levels and mixing time on soluble and insoluble wheat flour protein
fractions was studied. Results showed that GOX promoted a decrement in free SH groups in both proteins, being the most evident
effect on the soluble fraction at the beginning of the mixing process, remaining almost constant afterwards. H2O2 was continuously produced during mixing, showing its largest consumption during the first 6 min without significant SH changes
afterwards. Results suggest that H2O2 must be involved in other reactions as it remains in the sample; this also suggests that oxygen is not a limiting factor
in this reaction. 相似文献
23.
The single crystal X-ray structures of three structurally related azonaphtharylamide pigments are reported. Two azo pigments derived from 4-amino-3-nitrotoluene as diazo component (1a and b) crystallize in the centrosymmetric space group P21/c while the third (1c), an analogue of 1b but derived from 2,5-dichloroaniline as diazo component, crystallizes in the chiral space group P212121. The compounds adopt the ketohydrazone tautomeric forms with intramolecular, but no intermolecular, hydrogen bonding. The application performance of the products is discussed in relation to the molecular and crystal structures. X-ray powder diffraction, supported by FTIR spectroscopic and DSC analysis, demonstrate that pigment 1a shows polymorphism. The application performances of the two polymorphs of this pigment are compared. 相似文献
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26.
J Chmielowska RC Coghill JM Maisog RE Carson P Herscovitch M Honda R Chen M Hallett 《Canadian Metallurgical Quarterly》1998,18(4):433-443
Ethanol at concentration of 200 mM induces anesthesia in experimental animals and depresses neurotransmission in isolated spinal cords. To determine whether actions on primary afferent nerve terminals contribute to ethanol's depressant effects on spinal cord, a study was undertaken to test whether ethanol blocks sodium currents (I(Na)) in dorsal root ganglion neurons (DRGn). Whole-cell patch clamp was used to examine I(Na) in DRGn isolated from 1- to 15-day-old rats. At a holding potential of -80 mV ethanol (200 mM) decreased peak tetrodotoxin-resistant (TTX-R) and tetrodotoxin-sensitive (TTX-S) I(Na) by 19.0% +/- 2.7 (mean +/- SEM) and 8.5% +/- 2.2, respectively. Maximal available I(Na) was reduced to 82 +/- 4% (TTX-R) and 93 +/- 1% (TTX-S) of control. Steady-state inactivation curves were shifted in the hyperpolarizing direction by 2.1 +/- 0.2 mV (TTX-R) and 1.1 +/- 0.1 mV (TTX-S). At prepulse potentials of -30 mV (TTX-R) and -70 mV (TTX-S), these shifts contributed an additional 17 +/- 1% (TTX-R) and 7 +/- 1% (TTX-S) reduction in available I(Na). Ethanol thus selectively induced both voltage-independent and voltage-dependent block of TTX-R I(Na) in DRGn. Because DRGn TTX-R sodium channels are associated with small-diameter primary afferent fibers, these results are consistent with a role for ethanol actions on sodium channels in depression of nociceptive-related neurotransmission in spinal cord. 相似文献
27.
For ultrasonographic B-scan images collected by means of a handheld transducer moving in the elevational direction, frame spacings are computed with a speckle-decorrelation algorithm, without additional positioning hardware. Fully developed speckle volumes are automatically segmented and spacing computed from the decorrelation curves. Position accuracy is within 10% for phantoms and 15% for breast studies. The algorithm provides image-based registration, which allows accurate three-dimensional volume rendering. 相似文献
28.
Ticks and mites respond to a limited spectrum of stimuli in their search for hosts and mates. Airborne chemical signals include carbon dioxide, ammonia, organic acids, terpenoids, 2,6-dichlorophenol, and other phenolic compounds. These are detected primarily by sensilla in and adjacent to Haller's organ. Most ixodid species examined have one or more multiporose sensilla that detect such volatiles. These olfactoreceptors enable the ticks to respond to remote volatile chemicals from hosts and from the other ticks, e.g., sex pheromones. Other sensilla, probably mechanogustatory in function, also occur on the tarsi. Gustatory sensilla on the palps detect assembly pheromones that enable ticks and mites to respond to conspecific or heterospecific chemical stimuli in their environment. Responses to those stimuli in ticks result in clustering, i.e., arrestant behavior. Arrestant behavior also occurs in certain mites. Finally, cheliceral chemosensilla enable ticks to recognize specific phagostimulants in host blood, e.g., ATP and glutathione, that stimulate feeding. InDennacentor variabilis andD. andersoni, these same cheliceral chemosensilla recognize species-specific genital sex pheromones in the vulvae of conspecific mates, without which they do not copulate. 相似文献
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30.
Impedance properties of a longitudinal slot antenna in the broad face of a rectangular waveguide 总被引:2,自引:0,他引:2
The impedance properties of a waveguide longitudinal slot antenna of arbitrary length and offset in guide walls of finite thickness are investigated. These properties are obtained by treating the slot discontinuity as an electromagnetic boundary value problem and the resulting pair of coupled integral equations are solved by numerical techniques. Results are given for slots having lengths from0.35lambda to1.7lambda and are in good agreement with experimental results. 相似文献