Influence of Drying Techniques on the Characteristics of Chitosan and the Quality of Biopolymer Films

In this work, spouted bed and tray-drying techniques were employed at different drying air temperatures to produce dried chitosan, and the chitosan powder was used to produce biofilms. The products obtained from each drying technique were compared in relation to quality aspects (molecular weight, lightness, and hue angle). The results found for chitosan in spouted bed drying (90°C) showed lower alteration and best quality aspects in relation to the chitosan powder. However, in tray drying under the best condition (60°C) the chitosan molecular weight increased about 50% in relation to the initial value and browning was observed. The biofilms produced from chitosan dried in the spouted bed showed the best mechanical properties (tensile strength of 42 MPa and elongation of 29%) and lower water vapor permeability (3.95 g mm m^?2 kPa^?1 day^?1).     

Identification of new epidemiological molecular markers by comparative proteomics of serogroup A meningococcal isolates from three pandemic waves

We previously described the first reference map for the proteome of one strain of serogroup A Neisseria meningitidis (MenA), a major cause of epidemic meningitis in humans. As a preliminary finding, in that work we noted that 2‐DE protein maps of closely related MenA isolates from different epidemics spreads could be easily compared to detect minor differences and that 2‐DE phenotypes attributable to the well‐known epidemiological marker tbpB agreed with the genoclouds model of MenA epidemiological variation during pandemic waves. We explored here the possibility that an extended comparative study of 2‐DE maps of isolates representative of the nine genoclouds described by Achtman and collaborators could be used to discriminate between strains otherwise undistinguishable. We showed the example of 14 proteins with different 2‐DE spot patterns in different genoclouds that could be considered as putative tracers for alike‐strains discrimination. We introduce the novel concept that comparative proteomics can be useful in identifying new epidemiological markers for N. meningitidis.     

Analog circuits optimization based on evolutionary computation techniques

This paper presents a new design automation tool, based on a modified genetic algorithm kernel, in order to improve efficiency on the analog IC design cycle. The proposed approach combines a robust optimization with corner analysis, machine learning techniques and distributed processing capability able to deal with multi-objective and constrained optimization problems. The resulting optimization tool and the improvement in design productivity is demonstrated for the design of CMOS operational amplifiers.     

Recherche statistique paramétrique du rapport résistance-indice sclérométrique: essai de définition de la classe des bétons

Résumé Dans cette recherche on analyse les corrélations résistance-indice sclérométrique, par rapport aux paramètres les plus communs qui caractérisent l'agglomérat et qui sont faciles à identifier au cours des essais sur les structures finies. On a mis en évidence le type de granulat, le type de ciment, la durée de vieillissement. L'analyse a été effectuée sur 2583 cubes standard, examinés au Laboratoire Officiel de l'Université de Rome. La recherche statistique a permis de déterminer 10 fonctions de régression et les courbes relatives; à chacune de ces courbes ont été associés le coefficient de détermination et le coefficient de dispersion des données. L'analyse a montré qu'on ne peut se fier à une seule courbe de corrélation étant donné que les différents paramètres du béton ont une influence non négligeable sur la réponse sclérométrique. Les auteurs proposent même une évaluation de la résistance caractéristique de l'agglomérat au moyen des courbes déjà indiquées en tenant aussi compte des coefficients de dispersion des données, de l'écart-type de la série de mesures effectuées, et encore du coefficient d'équivalence entre la résistance conventionnelle et la résistancein situ.

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Summary In this research an analysis is made of the strength-sclerometric index correlations in respect to the most common parameters which characterize the concrete and which are easy to identify during test on the finished structure. It is shown that the type of aggregate, the type of cement and the curing time have an effect on the results. The analysis was undertaken on 2583 standard cubes examined at the official laboratory of the University of Rome. With the statistical study it is possible to determine ten regressive functions and the related curves, each of which is associated with the coefficients to determine the dispersion coefficient of the given data. The analysis indicates that reference to one curve alone is not reliable because the different parameters of the concrete exert non-negligible influence on the sclerometer impact response. The authors propose an evaluation of the characteristic strength of the concrete by using the curves mentioned, also considering the data scatter, standard deviation from the series of measurements taken and the equivalence coefficient between conventional and in-situ strength.

     

Channel acquisition and tracking for DS-CDMA uplink transmissions

This paper deals with channel acquisition and tracking for the uplink of direct-sequence code-division multiple-access systems. The transmission medium is characterized by multipath propagation, and the goal is to estimate the time-varying channel impulse response (CIR) for a new user entering the system. Channel acquisition is pursued through maximum-likelihood techniques. The resulting scheme may be too complex in some applications, as it requires the online inversion of a large matrix. Therefore, we also consider a simpler solution based on the least-squares (LS) criterion. Channel tracking is performed through weighted LS methods. At each signaling interval, the CIR estimate is updated using data decisions and exploiting the inverse of the interference covariance matrix to mitigate the near-far problem. Performance is assessed by simulation in a scenario inspired by the frequency-division duplexing component of the universal mobile telecommunications system. The acquisition/tracking algorithms are found to be resistant to multiuser interference and suitable for transmissions over fast-fading channels.     

Data-aided frequency estimation for burst digital transmission

Burst transmission of digital data is employed in several applications such as satellite time-division multiple access (TDMA) systems and terrestrial mobile cellular radio. We propose a new algorithm for carrier frequency estimation in burst-mode phase shift keying (PSK) transmissions. The algorithm is data-aided and clock-aided and has a feedforward structure that is easy to implement in digital form. Its estimation range is large, about ±20% of the symbol rate and its accuracy is close to the Cramer-Rao bound (CRB) for a signal-to-noise ratio (SNR) as low as 0 dB. Comparisons with earlier methods are discussed     

Development of composites based on recycled polyethylene/sugarcane bagasse fibers

In this work, sugarcane bagasse fibers were used as filler in composites having recycled high‐density polyethylene (PEr) as matrix. Because of the poor interaction between fibers surface and the PEr, the surface of bagasse was chemically modified. This modification consists of washing with water at 80°C, a mercerization process using sodium hydroxide and acetylation reaction with acetic anhydride. The chemical modification was characterized by Fourier transform infrared–horizontal attenuated total reflectance (FTIR‐HATR) and ¹³C nuclear magnetic resonance spectroscopies (NMR), thermogravimetric analysis (TGA), and scanning electronic microscopy (SEM). The composites were prepared from modified and unmodified fibers into PEr matrix, containing 5, 10, and 20% (w/w) of fiber. The samples were processed by extrusion and molds were prepared by injection process in order to perform mechanical tests. These materials were analyzed by SEM, TGA, and the water uptake was evaluated. Also, their mechanical properties were analyzed. Morphological analysis indicated that the chemical modification of sugarcane bagasse increased the compatibility between matrix and reinforcement. Tensile, flexural, and impact tests showed that the mechanical properties of the composite were improved compared to PEr due to the presence of the fibers. POLYM. COMPOS., 35:768–774, 2014. © 2013 Society of Plastics Engineers     

Chemometric Analysis of <Superscript>1</Superscript>H NMR Fingerprints of <Emphasis Type="Italic">Coffea arabica</Emphasis> Green Bean Extracts Cultivated under Different Planting Densities

High planting density has been used to increase coffee production but there are few studies related to the variations it provokes in metabolite compositions. The use of ¹H NMR data associated with chemometric techniques allows the determination of metabolic fingerprints and verification of metabolic changes when coffee is subjected to high planting densities. The aim of this work is to investigate ¹H NMR spectral data of green bean extracts of Coffea arabica cv. IAPAR 59 grown in a square pattern at two planting densities, 6000 and 10,000 plants ha^?1. Thirty extracts were obtained using a simplex centroid design with four solvents (ethanol, acetone, dichloromethane, and hexane). The lyophilized extracts were dissolved in DMSO-d₆ to obtain the ¹H NMR spectra. The spectral data were analyzed with principal component (PCA) and cluster analyses (CA). Significant differences between ethanolic and non-ethanolic extracts were found by PCA. Only the ethanolic mean spectrum showed characteristic chemical shifts of sugars and trigonelline. Acetone extracts were separated by cluster analysis.     

Electrical,rheological and electromagnetic interference shielding properties of thermoplastic polyurethane/carbon nanotube composites

Electrically conducting rubbery composites based on thermoplastic polyurethane (TPU) and carbon nanotubes (CNTs) were prepared through melt blending using a torque rheometer equipped with a mixing chamber. The electrical conductivity, morphology, rheological properties and electromagnetic interference shielding effectiveness (EMI SE) of the TPU/CNT composites were evaluated and also compared with those of carbon black (CB)‐filled TPU composites prepared under the same processing conditions. For both polymer systems, the insulator–conductor transition was very sharp and the electrical percolation threshold at room temperature was at CNT and CB contents of about 1.0 and 1.7 wt%, respectively. The EMI SE over the X‐band frequency range (8–12 GHz) for TPU/CNT and TPU/CB composites was investigated as a function of filler content. EMI SE and electrical conductivity increased with increasing amount of conductive filler, due to the formation of conductive pathways in the TPU matrix. TPU/CNT composites displayed higher electrical conductivity and EMI SE than TPU/CB composites with similar conductive filler content. EMI SE values found for TPU/CNT and TPU/CB composites containing 10 and 15 wt% conductive fillers, respectively, were in the range ?22 to ?20 dB, indicating that these composites are promising candidates for shielding applications. © 2013 Society of Chemical Industry