网络备用电源自动投入系统控制策略研究

以襄樊电网为工程实际基础,介绍了区域电网网络备用电源自动投入系统产生背景、工作原理。阐述了网络备用电源自动投入系统典型控制策略,最大限度利用现有电网资源提高用户供电可靠性。     

Synthesis and characterization of La2Ti2O7 employed for photocatalytic degradation of reactive red 22 dyestuff in aqueous solution

Perovskite structured La₂Ti₂O₇ catalyst prepared by polymerized complex method was characterized and examined the photocatalytic activity by decomposing an azo dyestuff, Reactive Red 22, in aqueous solutions under UV irradiation. La₂Ti₂O₇ powders prepared by polymerized complex method exhibit higher surface areas, better homogeneity and are more sensitive to solution than those prepared by solid-state method. The first derivatives of UV–vis DRS patterns confirmed the complete crystallization of La₂Ti₂O₇ sintered at temperatures higher than 900 °C. The effects of sintering temperature of catalyst and solution pH of photocatalytic reaction were studied. The photocatalytic decomposition of Reactive Red 22 per unit surface area was found to be higher for experiments using La₂Ti₂O₇ than using TiO₂. However, the electron–hole recombination was found to be more obvious for La₂Ti₂O₇ than for TiO₂ because the network of metal cations constructed within La₂Ti₂O₇ enhances the mobility of photogenerated electrons and holes.     

弧焊变压器焊接时触电的原因分析及防范措施

阐述了使用弧焊变压器施焊时产生触电的原因,并提出了安全使用弧焊变压器焊接时的措施。希望焊接人员摒弃错误的观念及麻痹思想,高度重视安全用电,确保人身安全。     

国产HW2000型高频红外碳硫仪分析精度探讨

对国产HW2000型高频红外碳硫仪的分析精度进行了测定,并与进口EMIA-620型高频红外碳硫仪进行了比较,结果表明,HW2000型红外仪的检出限低(0.000 03％).对3种标准样品的分析,HW2000型红外仪分析的碳的RSD为0.000 59％～ 1.630 25％,硫的RSD为0.012 67％ ～ 0.513 20％:而EMIA-620型分析的碳的RSD为0.206 64％～ 1.724 17％,硫的RSD为0.025 30％～0.939 15％.而且HW2000型红外仪有较好的分析线性.     

Efficiency enhancement of dye-sensitized solar cells with addition of additives (single/binary) to ionic liquid electrolyte

The effect of addition of single and binary additives on the performance of dye-sensitized TiO₂ solar cells based on electrolytes containing an ionic liquid (IL), 1,2-dimethyl-3-propylimidazolium iodide (DMPII) has been studied. Among the seven additives used, the addition of 2-(dimethylamino)-pyridine (DMAP) to IL resulted in best cell efficiency, which showed further enhancement with the addition of 5-chloro-1-ethyl-2-methylimidazole (CEMI) as second additive. The efficiency of the dye-sensitized solar cell (DSC) based on an electrolyte containing binary additives (DMAP and CEMI in equal molar ratios) has been found to increase by 62·5% from 4·35 to 7·07%. The dependence of different photovoltaic performance parameters (V _oc, J _sc, ff, η) of DSC upon temperature has been studied over a 30–120°C range and only a small decrease in conversion efficiency has been observed. The electrolyte containing binary additives (DMAP and CEMI) shows best cell performance up to 120°C.     

聚偏氟乙烯紫外光接枝改性及其膜的耐污染性能研究

膜污染是影响膜分离性能的重要因素,今采用非均相表面光接枝术在聚偏氟乙烯粉料表面引入亲水性物质丙烯酸甲酯,然后采用相转移的方法制备超滤膜。运用傅里叶转换红外光谱、X光电子能谱、接触角仪等对改性前后制备的聚偏氟乙烯膜表面性能和结构进行表征;结果表明丙烯酸甲酯成功接枝到聚偏氟乙烯粉料表面上,接枝改性后膜表面亲水性和抗污染性能均有明显改善。     

原位化学氧化接枝聚合法制备PANI/AMTES-ATP复合材料

首先用偶联剂苯胺甲基三乙氧基硅烷(AMTES)对凹凸棒土(ATP)进行表面修饰(AMTES-ATP),然后通过苯胺单体在AMTES-ATP表面的原位化学氧化接枝聚合,制备了基于共价键结合的聚苯胺(PANI)/AMTES-ATP复合材料.利用透射电镜(TEM),红外光谱(FTIR),X射线衍射(XRD),紫外-可见漫反射光谱(UV-vis-DRS)和热重-差热(TG-DTA)分析等技术对复合材料进行了表征.结果表明,复合材料中PANI高分子链是通过偶联剂AMTES以化学键的方式与ATP相结合的,AMTES的桥连作用增加了两相间的接触面积,使PANI在ATP表面形成均匀的包覆层.PANI与ATP之间存在较强的相互作用力,限制了PANI的生长和结晶.由于ATP表面的界电限域效应,使PANI以伸展分子链构象存在.ATP的加入和两相间作用力的存在使复合材料中PANI的热稳定性能有明显的提高.     

硫酸盐对萘系减水剂与水泥相容性的影响

通过改变水泥浆体中的硫酸盐含量,以及调整萘系减水剂的掺量,观察水泥浆体的流动性和流动性经时损失的变化,由此确定萘系减水剂的饱和点。同时测定水泥浆体的水化放热,确定水泥浆体中硫酸盐含量对水泥和萘系减水剂相容性的影响。结果表明:减水剂掺量和水泥中硫酸盐的含量共同影响水泥浆体的流动度。掺加适量的硫酸盐可降低水泥的水化热,延缓水泥的水化反应,提高萘系减水剂与水泥的相容性,减少流动性经时损失。当水泥浆体中有适量萘系减水剂存在时,硫酸盐的作用更明显。     

载银/铜NaA分子筛的制备及抗菌性能研究

探讨了液相离子交换法制备载银/铜NaA分子筛抗菌剂的实验条件,并对载银/铜NaA分子筛样品中载银、铜的含量,抗变色性能及对大肠杆菌、金黄葡萄球菌的抗菌性进行检测。结果表明,与单独载银的NaA分子筛相比,载银/铜NaA分子筛中银和铜含量分别达到5.5%和1.6%,色差更小,抗菌性显著提高。