White Electroluminescence by Supramolecular Control of Energy Transfer in Blends of Organic‐Soluble Encapsulated Polyfluorenes

Here, it is demonstrated that energy transfer in a blend of semiconducting polymers can be strongly reduced by non‐covalent encapsulation of one constituent, ensured by threading of the conjugated strands into functionalized cyclodextrins. Such macrocycles control the minimum intermolecular distance of chromophores with similar alignment, at the nanoscale, and therefore the relevant energy transfer rates, thus enabling fabrication of white‐light‐emitting diodes (CIE coordinates: x = 0.282, y = 0.336). In particular, white electroluminescence in a binary blend of a blue‐emitting, organic‐soluble rotaxane based on a polyfluorene derivative and the green‐emitting poly(9,9‐dioctylfluorene‐alt‐benzothiadiazole ( F8BT ) is achieved. Morphological and structural analyses by atomic force microscopy, fluorescence mapping, µ‐Raman, and fluorescence lifetime microscopy are used to complement optical and electroluminescence characterization, and to enable a deeper insight into the properties of the novel blend.     

Physical Simulation of the Interference Immunity of Electronic Equipment under the Electromagnetic Action of Industrial Macrosources

For the action of a pulse field generated by industrial macrosources under the short-circuit condition used as an example, mathematical models, the circuit of an experimental setup, and design parameters for physical simulation of electromagnetic interferences in the communication lines of the electronic equipment have been proposed. The presented software provides the basis for a practical procedure for estimating the interference immunity of the electronic equipment subjected to the electromagnetic action of industrial macrosources.     

Scheduling Combined Unicast and Multicast Traffic in Broadcast WDM Networks

This paper studies the performance of various strategies for scheduling a combined load of unicast and multicast traffic in a broadcast WDM network. The performance measure of interest is schedule length, which directly affects both aggregate network throughput and average packet delay. Three different scheduling strategies are presented, namely: separate scheduling of unicast and multicast traffic, treating multicast traffic as a number of unicast messages, and treating unicast traffic as multicasts of size one. A lower bound on the schedule length for each strategy is first obtained. Subsequently, the strategies are compared against each other using extensive simulation experiments in order to establish the regions of operation, in terms of a number of relevant system parameters, for which each strategy performs best. Our main conclusions are as follows. Multicast traffic can be treated as unicast traffic, by replicating all multicast packets, under very limited circumstances. On the other hand, treating unicast traffic as a special case of multicast traffic with a group of size 1, produces short schedules in most cases. Alternatively, scheduling and transmitting each traffic component separately is also a good choice.     

A Comparison of Allocation Policies in Wavelength Routing Networks*

We consider wavelength routing networks with and without wavelength converters, and several wavelength allocation policies. Through numerical and simulation results we obtain upper and lower bounds on the blocking probabilities for two wavelength allocation policies that are most likely to be used in practice, namely, most-used and first-fit allocation. These bounds are the blocking probabilities obtained by the random wavelength allocation policy with either no converters or with converters at all nodes of the network. Furthermore, we demonstrate that using the most-used or first-fit policies gives an improvement on call blocking probabilities that is equivalent to employing converters at a number of nodes in a network with the random allocation policy. These results have been obtained for a wide range of loads for both single-path and general mesh topology networks. The main conclusion of our work is that the gains obtained by employing specialized and expensive hardware (namely, wavelength converters) can be realized cost-effectively by making more intelligent choices in software (namely, the wavelength allocation policy).     

A study of the thermal behaviour of a specimen during fatigue

A steel specimen (XC 10), submitted to fatigue by alternating symmetrical torsion, gives rise to heat dissipation, which is a function of the amplitude of the applied forces.The relationship between the amplitude of the applied forces and the quantity of heat dissipated was measured while a specimen underwent fatigue testing (E_n curves).The results appear to show that this relation is not identical for similar specimens at the beginning of the tests, initial state which is assumed to correspond to something like a “virgin state”, but that there is a convergence of the E_n curves as rupture is approached.     

Should mobile Internet be an extension to the fixed web? Fixed-mobile reinforcement as mediator between context of use and future use

As the fixed and mobile Internet are converging, the question emerges whether consumers expect mobile Internet services to replicate services they know from the fixed Internet. Literature on reinforcement and displacement suggests that the use of new media depends on whether users are inclined to replace or reinforce their existing media use on a new device. This paper analyzes whether the importance that users attribute to using similar services on their mobile phone as on the fixed Internet can explain the intention to adopt mobile services. Specifically, we investigate if such fixed-mobile reinforcement could mediate the impact of personal innovativeness and several dimensions of context. We compare basic Internet services, entertainment services and transaction services. We find that especially the intention to adopt basic Internet services largely depends on the importance of using similar services in the mobile domain as on the fixed Internet. Several context-of-use predictors are partially or even fully mediated by fixed-mobile reinforcement. The results convey a positive message to operators that are betting on converged multimedia services that can be accessed from any device and from any fixed or mobile network.     

跟踪正负峰值的整流器

从音乐到复杂的控制系统等各种信号波形也许包含不相等的正负峰值幅度“。包络线跟随”电路能跟踪不相等的峰值,而选择预期峰值的能力能增强该电路的性能(参考文献1)。图1中的电路向经典的绝对值电路施加了一项新方法。向R(1全波)施加一个输入信号,就会产生一个等于输入绝对值的输出。向R(6正)或R7(负)施加一个输入信号,就会分别产生正或负半周期输出。图2描绘了所有三种工作模式。如果你考虑到运算放大器IC1力求把自己的反相输入保持在虚拟地,那么对该电路的理解就简单了。例如,向负输入R7施加-1V,就会把D1的阳极驱动到-333mV。IC1A的…     

传统中药现代化--中药健康食品的开发

传统中药是现代生活健康的宝库,其功效在保健及慢性疾病的治疗方面尤其显著,并已备受世界重视.要成功将中药引进世界市场,最基本要求是要从科学方法去证明其效用及安全性;更重要是依从传统中医学对复方应用的要求去作研究.本文陈述了我们对传统中药古方"生脉散"研究及开发抗氧化健康食品的经验.透过现代生化及药理技术,我们发现"生脉散"中的五味子含丰富的抗氧化活性成分,为传统中医学利用"生脉散"治疗心脏病提供了理论依据.     

An algorithm used for ventricular fibrillation detection without interrupting chest compression

Ventricular fibrillation (VF) is the primary arrhythmic event in the majority of patients suffering from sudden cardiac arrest. Attention has been focused on this particular rhythm since it is recognized that prompt therapy, especially electrical defibrillation, may lead to a successful outcome. However, current versions of automated external defibrillators (AEDs) mandate repetitive interruptions of chest compression for rhythm analyses since artifacts produced by chest compression during cardiopulmonary resuscitation (CPR) preclude reliable electrocardiographic (ECG) rhythm analysis. Yet, repetitive interruptions in chest compression are detrimental to the success of defibrillation. The capability for rhythm analysis without requiring "hands-off" intervals will allow for more effective resuscitation. In this paper, a novel continuous-wavelet-transformation-based morphology consistency evaluation algorithm was developed for the detection of disorganized VF from organized sinus rhythm (SR) without interrupting the ongoing chest compression. The performance of this method was evaluated on both uncorrupted and corrupted ECG signals recorded from AEDs obtained from out-of-hospital victims of cardiac arrest. A total of 232 patients and 31,092 episodes of either VF or SR were accessed, in which 8195 episodes were corrupted by artifacts produced by chest compressions. We also compared the performance of this method with three other established algorithms, including VF filter, spectrum analysis, and complexity measurement. Even though there was a modest decrease in specificity and accuracy when chest compression artifact was present, the performance of this method was still superior to other reported methods for VF detection during uninterrupted CPR.