Determination of instantaneous corrosion rates and runoff rates of copper from naturally patinated copper during continuous rain events

Instantaneous corrosion rates of naturally patinated copper of varying age (16 months, 138 and 145 years) have been determined during continuous rain events in the laboratory with electrochemical impedance spectroscopy using a two-electrode cell. The two-electrode cell was found to yield the same information in bulk rainwater as a conventional three-electrode cell.Relatively constant corrosion rates, between 0.2 and 0.6 μm/y, were determined for samples having a two-layer structure with an inner brownish layer of cuprous oxide and an outer greenish layer of basic copper salts (138, 145 years). Samples with cuprous oxide as the dominating phase of the patina (16 months) showed higher and somewhat increasing corrosion rates during a rain event (from 0.6 to 1.2 μm/y). During a continuous rain event, corrosion rates were found to be approximately 10 (brownish patina) and 25 times (greenish patina) lower than corresponding instantaneous runoff rates. The first flush phenomena of the runoff process, with an increased concentration during first flush and a relatively constant concentration during steady state, was indirectly seen as an increase in solution conductivity during the first rain volume followed by relative constant value. The contribution of the concentration in the first flush to the total annual runoff rate was significant for panels having a greenish layer (138, 145 years) whereas it was negligible for panels having a brownish layer (16 months).     

改进的第三代相干算法及应用

在讨论相干技术发展及三代相干算法优缺点的基础上，介绍了改进的第三代相干算法。应用自行开发的相干软件对多个油气勘探和开发区块的三维地震资料进行处理、分析，对相干时窗长度、相关道数等参数对算法效果的影响及相干体对断层、异常地质体的识别，以及解释方法进行了探讨。应用实例证明，改进的第三代相干算法抗干扰能力强，横向分辨率高，不仅适用于倾斜地层，而且对断层尤其对小断层、异常地质体具有较高的检测能力，是油气勘探和开发的一项有效和实用的技术。     

学校图书馆随书光盘的有效管理

本文介绍了随书光盘的类型和特点，总结了我校图书馆随书光盘管理的几种方法，并针对随书光盘在管理方面易出现的问题．提出了应对措施。     

个性飞扬 情境使然

相IT和数码领域对而言,打印机市场已经发展得比较成熟,一个成熟的市场在一定程度上辐射出其竞争的激烈,打印机市场便是如此.     

用于安全稳定控制的高压直流极闭锁判据

交直流并联运行电网中直流极闭锁后引起的安全稳定问题十分突出，如何正确判别直流极闭锁是安全稳定控制系统研究中的重要课题。采用数值仿真方法分析了直流极闭锁对电力系统稳定的影响，指出稳定控制装置必须正确、快速地判出不同形式的直流极闭锁。通过研究直流极闭锁的电气量特征以及直流控制保护系统的动作行为，提出了可靠的直流极闭锁综合判据，并进行了详细的阐述。通过介绍中国南方交直流混联电网安全稳定控制系统核心部分———高肇直流输电安全稳定控制系统，进一步论述了研究直流极闭锁判据及直流极闭锁后稳定控制的重要性。     

Mass transfer kinetics of neodymium(III) extraction by calix[4]arene carboxylic acid using a constant interfacial area cell with laminar flow

BACKGROUND: Thermodynamics and kinetics data are both important to explain the extraction property. In order to develop a novel separation technology superior to current extraction systems, many promising extractants have been developed including calixarene carboxylic acids. The extraction thermodynamics behavior of calix[4]arene carboxylic acids has been reported extensively. In this study, the mass transfer kinetics of neodymium(III) and the interfacial behavior of calix[4]arene carboxylic acid were investigated. RESULTS: The rate constant (K_ao) becomes constant when the stirring speed was controlled between 250 rpm and 400 rpm. The activation energy (E_a) was calculated to be 21·41 kJ mol^?1 or 88·17 kJ mol^?1 (dependent on temperature) from the slope of log K_ao against 1000/T. The linear relationship between the specific area and the extraction rate is the characteristic of an interfacial reaction control. The minimum bulk concentration of the extractant necessary to saturate the interface (C_min) is lower than 4·19 × 10^?4 mol L^?1. CONCLUSION: The effect of stirring speed, temperature, and species concentration on the extraction rate demonstrates that the extraction regime depends on the extraction conditions. The chemical reaction control governs the extraction regime at temperatures below 303 K and a mixed control regime occurs when the temperature is between 303 K and 318 K. The probable locale for the chemical reaction is at the liquid–liquid interface and the rate equation is deduced to be: ? d[Nd³⁺]_(a)/dt = k_f[Nd³⁺]_(a)[H₄A]_(o)^0·727[H⁺]_(a)^?0·978. The rate‐controlling step was suggested by the analysis of the experimental results. Copyright © 2008 Society of Chemical Industry     

Bandwidth‐guaranteed QoS routing of multiple parallel paths in CDMA/TDMA ad hoc wireless networks

This paper investigates the issues of QoS routing in CDMA/TDMA ad hoc networks. Since the available bandwidth is very limited in ad hoc networks, a QoS request between two nodes will be blocked if there does not exist a path that can meet the QoS requirements, even though there is enough free bandwidth in the whole system. In this paper, we propose a new scheme of using multiple paths between two nodes as the route for a QoS call. The aggregate bandwidth of the multiple paths can meet the bandwidth requirement of the call and the delays of these paths are within the required bound of the call. We also propose three strategies by which to choose a set of paths as the route, namely, shortest path first (SPF), largest bandwidth first (LBF), and largest hop‐bandwidth first (LHBF). Extensive simulations have been conducted to evaluate the performance of the three strategies in comparison with a traditional single path routing algorithm. The simulation results show that the proposed multiple paths routing scheme significantly reduces the system blocking rates in various network environments, especially when the network load is heavy. Copyright © 2005 John Wiley & Sons, Ltd.     

液体酚型抗氧剂的制备及性能评定

以2，6-二叔丁基苯酚和丙烯酸酯为主要原料制备出一种液体酚型抗氧剂新产品羟基苯基丙酸酯化合物(LA0)。对制备的LAO的结构、组成及理化性能特别是抗氧化性能进行了分析评定。结果表明：LAO具有油溶性好、使用方便、特别是高温抗氧化能力强等优点，质量达到国外同类优质产品水平，并具有良好的环保性。     

Novel one-step route for synthesizing sub-micrometer PSt hollow spheres via redox interfacial-initiated method in inversed emulsion

Interfacial-initiated polymerization of styrene (St) was carried out in inversed emulsion with cumene hydroperoxide (CHPO) and ferrous sulfate (FeSO₄)/disodium ethylenediaminetetraacetate (NaEDTA)/sodium formaldehyde sulfoxylate (SFS) as the redox initiation system. The water-soluble Fe²⁺-NaEDTA-SFS acted as the reducing component and the oil-soluble CHPO as the oxidant component of the redox initiation system. Therefore, the primary radicals were produced mainly at the oil/water interface to initiate the polymerization of St. Thus, sub-micrometer hollow polystyrene (PSt) spheres were obtained by one-stage polymerization, which was supported by the techniques of transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM).     

《钢结构工程施工质量验收规范》修订简介

简要介绍《钢结构工程施工质量验收规范》(GB 5 0 2 0 5 - 2 0 0 1)的修订原则、方法以及对原规范进行修订中新增加的内容及要求 ,并进行了详细解释 ,以便于对新规范的理解