纳米TiO_2光催化降解次甲基蓝的影响因素研究

以TiCl4为原料,采用水解沉淀法,并在空气气氛下于不同温度煅烧2h,制备得到纳米TiO2。采用XRD、TEM及UV-Vis对样品进行表征。在卤钨灯照射下,研究了不同煅烧温度、不同pH值以及H2O2的加入等因素对TiO2光催化降解次甲基蓝的影响。结果表明:以水解沉淀法制备的纳米TiO2,随煅烧温度的提高,在600℃开始向金红石相转变,1000℃时全部转变为金红石相,并且TiO2粒子长大,吸收带边向长波方向移动。锐钛矿相与金红石相共存的纳米TiO2比纯锐钛矿相和金红石相有更优异的光催化活性,在卤钨灯下照射90min,对次甲基蓝的降解率达到97%。     

Organic Semiconducting Luminophores for Near-Infrared Afterglow,Chemiluminescence, and Bioluminescence Imaging

Optical imaging has played a pivotal role in deciphering in vivo bioinformatics but is limited by shallow penetration depth and poor imaging performance owing to interfering tissue autofluorescence induced by concurrent photoexcitation. The emergence of near-infrared (NIR) self-luminescence imaging independent of real-time irradiation has timely addressed these problems. There are two main kinds of self-luminescent agents, namely inorganic and organic luminophores. Inorganic luminophores usually suffer from long-term biotoxicity concerns resulting from potential heavy-metal ions leakage and nonbiodegradability, which hinders their further translational application. In contrast, organic luminophores, especially organic semiconducting luminophores (OSLs) with good biodegradable potential, tunable design, and outstanding optical properties, are preferred in biological applications. This review summarizes the recent progress of OSLs used in NIR afterglow, chemiluminescence, and bioluminescence imaging. Molecular manipulation and nanoengineering approaches of OSLs are discussed, with emphasis on strategies that can extend the emission wavelength from visible to NIR range and amplify luminescence signals. This review concludes with a discussion of current challenges and possible solutions of OSLs in the self-luminescence field.     

人瘢痕疙瘩成纤维细胞原代培养及生物学行为研究

目的:建立可靠的人瘢痕疙瘩成纤维细胞培养方法,为瘢痕疙瘩体外研究提供平台.方法:采用组织块贴壁法进行瘢痕疙瘩成纤维细胞的原代培养,使用含10%胎牛血清的RPMI-1640培养基,37℃,5%CO2,饱和湿度下培养;描述其生长曲线、分裂指数、形态及波形蛋白表达.结果:瘢痕疙瘩成纤维细胞培养成功率43%(6/14),48～65天可传第一代,以后每5～10天可传一代,细胞为长梭形,波形蛋白表达阳性.结论:培养出的瘢痕疙瘩成纤维细胞可用作体外实验研究.     

通信设备厂商并购产业重组潮流涌动

现象揭示着规律,面对已不算新闻的爱立信-马可尼、阿尔卡特-朗讯、诺基亚-西门子三起通信设备厂商并购案,什么样的思考方能正解通信产业的变迁？也许这数起并购是通信产业重组潮流中的过去时．是进行时,也是将来时。邀请阚凯力、陈金桥、曾剑秋、陈育平、张薇及邓志成先生等知名业内人士一道聚焦这几起并购,《世界电信》与您一起思考。     

Modifications of the Cubic Phase Function

By introducing a symmetric pair of time instants, a modification of the Cubic phase （CP） function, named as the Quartic phase （QP） function, is proposed to estimate the quadratic FM signal. The performance in terms of estimate bias and variance is presented via the first-order permutation principle. Two extensions are presented for multiple components and the cubic FM signals. Both theoretical analysis and numerical examples confirm that the QP function and its extensions provide a number of advantages, such as： （1） lower asymptotic Mean-square error （MSE） for the estimate of the third-order phase pa- rameter at high SNR; （2） a better capability of discriminating multicomponent signals; （3） a lower SNR threshold for the estimates of the cubic FM signal.     

百皮秒激光脉冲的全光纤放大及应用

为了得到高单脉冲能量的百皮秒激光脉冲,采用自制的被动锁模掺镱光纤激光器获得了100ps的激光脉冲输出,在此基础上采用两级全光纤结构主振荡功率放大器进行功率放大,其中预放大级采用7m纤芯的双包层掺镱光纤做增益介质,得到平均功率160mW的稳定脉冲输出;主放大级采用20m纤芯的双包层掺镱光纤做增益介质,在抽运功率逐步增加到35.37W时,输出功率达到了16.60W,相应的单脉冲能量为1.63J,峰值功率为16.61kW。此外,主放大级输出的激光通过自制的模场转换器与光子晶体光纤(纤芯4.6m)成功熔接,得到了2.85W的白光超连续光谱,光谱波长覆盖了600nm~1700nm的检测范围。结果表明,此激光可用于超连续谱光源的产生。     

基于SVM的语音情感识别研究

随着计算机技术的发展,人们对和谐人机交互的要求不断提高,这就要求计算机能理解说话人的情感信息,即能进行语音情感识别。本文提出了一种基于支持向量机（SVM）的语音情感识别方法,主要对人类的6种基本情感：高兴、惊奇、愤怒、悲伤、恐惧、平静进行研究。首先对自建语音情感数据库的情感语句提取特征,然后运用序列前向选择（SFS）算...     

Primary User Emulation Detection Algorithm Based on Distributed Sensor Networks

In this paper, we propose a novel primary user emulation (PUE) detection approach which employs a distributed sensor network, where each sensor node operates as an independent PUE detector. Distributed nodes collaborate in order to obtain the final detection results for the whole network. A voting algorithm is used to improve the performance of energy detection, while the classification is conducted by the nearest node in order to improve the efficiency of the detector. As a result of voting, if a potential primary user exists, then the features of the unknown user is compared with entries from the database in order to obtain a solid detection match. An artificial neural network (ANN) is used for the classification of an unknown user. To assess the accuracy of the detection result, we implement a reliability check at the output of ANN. The proposed algorithm is validated via computer simulations as well as by experimental hardware implementations using the Universal Software Radio Peripheral (USRP) software-defined radio (SDR) platform. The experiment results show that the distributed network detector detects the PUE 180–200%, depending on the number of primary users, faster than single node detector.     

面向图像复原的广义岭估计模式法波前重构

为了提高自适应光学图像的复原效果,提出了一种面向图像复原的广义岭估计Zernike模式波前重构算法。首先,按照用时间换精度的思路,把广义岭估计引入自适应光学波前重构算法中。改善最小二乘估计的奇异性,抑制波前测量误差的放大。然后,引入迭代计算提高方程的解算精度,进一步提高点扩散函数(PSF)重建质量。最后,利用广义岭估计重建的PSF对降质图像进行复原实验验证PSF的重建质量。实验结果证明,广义岭估计PSF的复原效果比最小二乘估计PSF高约15%,更接近成像系统的光学衍射极,同时复原计算迭代次数也减少了35%。新算法重构的PSF在图像复原中有更好的图像重建效果。     

CDMA2000覆盖公路隧道的工程实例分析

简要介绍了公路隧道的孔径尺寸、电信运营商所需的电源、站点、管沟资源及隧道覆盖工程费用构成;详细论述了无线覆盖建设方案中的共建共享、公路隧道无线传播特点及信号源、天馈系统、天线、站点选择等有关问题,并通过多个具体实例对典型覆盖工程分别进行了测试验证。