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11.
Protection of Metals and Physical Chemistry of Surfaces - To improve the mechanical and biological properties and also to increase the lifetime and performance of Ti–6Al–4V dental...  相似文献   
12.
A series of new alternating aromatic poly(ester‐imide)s were prepared by the polycondensation of the preformed imide ring‐containing diacids, 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl (2a) and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl (2b) with various aromatic dihydroxy compounds in the presence of pyridine and lithium chloride. A model compound (3) was also prepared by the reaction of 2b with phenol, its synthesis permitting an optimization of polymerization conditions. Poly(ester‐imides) were fully characterized by FTIR, UV‐vis and NMR spectroscopy. Both biphenylene‐ and binaphthylene‐based poly(ester‐imide)s exhibited excellent solubility in common organic solvents such as tetrahydrofuran, m‐cresol, pyridine and dichloromethane. However, binaphthylene‐based poly(ester‐imide)s were more soluble than those of biphenylene‐based polymers in highly polar organic solvents, including N‐methyl‐2‐pyrrolidone, N,N‐dimethylacetamide, N,N‐dimethylformamide and dimethyl sulfoxide. From differential scanning calorimetry thermograms, the polymers showed glass‐transition temperatures between 261 and 315 °C. Thermal behaviour of the polymers obtained was characterized by thermogravimetric analysis, and the 10 % weight loss temperatures of the poly(ester‐imide)s was in the range 449–491 °C in nitrogen. Furthermore, crystallinity of the polymers was estimated by means of wide‐angle X‐ray diffraction. The resultant poly(ester‐imide)s exhibited nearly an amorphous nature, except poly(ester‐imide)s derived from hydroquinone and 4,4′‐dihydroxybiphenyl. In general, polymers containing binaphthyl units showed higher thermal stability but lower crystallinity than polymers containing biphenyl units. Copyright © 2005 Society of Chemical Industry  相似文献   
13.
A new method for prediction of Gurney velocity of explosives is introduced in which energy output is correlated with the heat of detonation, the number of moles of gaseous products of detonation per gram of explosive and the average molecular weight of gaseous products. It is assumed that the CHNO explosive reacts to form products composed of N2 , CO, H2O, CO2, H2,O2 and C(s) as determined by the oxygen balance of the unreacted compound. Good agreement is obtained between measured and calculated values of Gurney velocity as compared to previous correlations which assumed the reaction products to consist of N2 , H2O, CO2 and either C(s) or O2.  相似文献   
14.
The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008  相似文献   
15.
D. N. Riahi  T. L. Sayre 《Acta Mechanica》1996,118(1-4):109-119
Summary Nonlinear natural convection in a mushy layer during solidification of a binary alloy is investigated under a high gravity environment where the rotation axis is inclined to the high gravity vector. Asymptotic and scaling analyses are applied to convective flow within the mushy layer and in vertical chimneys. The main result is that, for some particular moderate rotation range, vertical velocity in the chimneys decreases rapidly with increasing rotation rate and appears to have opposite signs across some rotation dependent vertical level.  相似文献   
16.

The present work aimed to evaluate and optimize the design of an artificial neural network (ANN) combined with an optimization algorithm of genetic algorithm (GA) for the calculation of slope stability safety factors (SF) in a pure cohesive slope. To make datasets of training and testing for the developed predictive models, 630 finite element limit equilibrium (FELE) analyses were performed. Similar to many artificial intelligence-based solutions, the database was involved in 189 testing datasets (e.g., 30% of the entire database) and 441 training datasets; for example, a range of 70% of the total database. Moreover, variables of multilayer perceptron (MLP) algorithm (for example, number of nodes in any hidden layer) and the algorithm of GA like population size was optimized by utilizing a series of trial and error process. The parameters in input, which were used in the analysis, consist of slope angle (β), setback distance ratio (b/B), applied stresses on the slope (Fy) and undrained shear strength of the cohesive soil (Cu) where the output was taken SF. The obtained network outputs for both datasets from MLP and GA-MLP models are evaluated according to many statistical indices. A total of 72 MLP trial and error (e.g., parameter study) the optimal architecture of 4 × 8 × 1 were determined for the MLP structure. Both proposed techniques result in a proper performance; however, according to the statistical indices, the GA–MLP model can somewhat accomplish the least mean square error (MSE) when compared to MLP. In an optimized GA–MLP network, coefficient of determination (R2) and root mean square error (RMSE) values of (0.975, and 0.097) and (0.969, and 0.107) were found, respectively, to both of the normalized training and testing datasets.

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17.
Engineering with Computers - The advent of new data-mining techniques and, more recently, swarm-based optimization algorithms have antiquated traditional models in the field of energy performance...  相似文献   
18.
19.
The Journal of Supercomputing - During recent years, big data explosion and the increase in main memory capacity, on the one hand, and the need for faster data processing, on the other hand, have...  相似文献   
20.
The Journal of Supercomputing - In wireless sensor networks (WSNs), designing a stable, low-power routing protocol is a major challenge because successive changes in links or breakdowns destabilize...  相似文献   
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