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961.
白腐菌Panus conchatus降解稻草木素机理研究──(一)低分子木素降解产物各组分的分离及特征 总被引:3,自引:1,他引:3
经白腐菌Panusconchatuss发酵15天的稻草用乙酸乙酯进行抽提可有效分离出生物作用后的低分子量木煮降解产物。利用这些低分子降解产物在酸碱度不同的介质以及不同的有机溶剂中的溶解度不同进一步分离、分级和提纯,获得酚类(LP),芳香酸类(LA1—4)以及中性物质三个组份。我们发现LP与LA是降解产物中的主要组份,它们的得率分别为51.1%和34.4%。如此高的LP得率是白腐菌P.conchatus降解稻草木素的重要特征。本文还利用红外光谱和核磁共振技术对LP和LA中最多的一个组份LA—1的可能化学结构特征进行剖析。 相似文献
962.
963.
机压成型高效节能格子砖丘必云,黄渊鳞,林剑成(中国轻工总会玻璃搪瓷研究所200052)PressedHighEfficientCheckers¥QiuBiyun;HuangYuanlin;LinJiancheng(Glass&EnamelResear... 相似文献
964.
Novel organosoluble fluorescent polynorbornenes with multi-functional armed structure were designed and prepared by using highly stable block macroinitiators via a combination of living ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP). A bromo-containing functional norbornene (NBMBr) was prepared from the Diels-Alder reaction of cyclopentadiene and allyl bromide. The diblock copolymer of 5-(N-carbazolyl methyl)bicycle[2.2.1]hept-2-ene (CbzNB) and NBMBr was successfully prepared using living ROMP and used as a novel macroinitiator [poly(CbzNB-b-NBMBr)] for ATRP. Carbazoyl-containing multi-functional armed copolymer with poly(methyl methacrylate) (PMMA) was prepared by using poly(CbzNB-b-NBMBr) as a macroinitiator for ATRP. Strong fluorescence emissions (370-450 nm) were observed in the low excimer-forming multi-functional armed fluorescent polynorbornenes. The fact is that low excimer-forming carbazole-containing polymeric compound would apparently be favorable in photoconductive materials. The multi-functional armed structure make this compound an attractive candidate for applications as multi-modified hole transport materials in molecular electronic devices. Multi-modification could be further considered to be carried out by using such a functional bromo group at the end of multi-arms. 相似文献
965.
Jyh‐Ping Dong Jyh‐Gau Huang Fuh‐Huah Lee Jiunn‐Wei Roan Yan‐Jyi Huang 《应用聚合物科学杂志》2004,91(5):3388-3397
The effects of three series of self‐synthesized poly(methyl methacrylate) (PMMA)‐based low‐profile additives (LPAs), including PMMA, poly(methyl methacrylate‐co‐butyl acrylate), and poly(methyl methacrylate‐co‐butyl acrylate‐co‐maleic anhydride) with different chemical structures and MWs on the volume shrinkage characteristics and internal pigmentability for low‐shrink unsaturated polyester (UP) resins during curing were investigated by an integrated approach of static phase characteristics of the ternary styrene (ST)/UP/LPA system, reaction kinetics, cured‐sample morphology, microvoid formation, and property measurements. The relative volume fraction of microvoids generated during the cure was controlled by the stiffness of the UP resin used, the compatibility of the uncured ST/UP/LPA systems, and the glass‐transition temperature of the LPAs used. On the basis of the Takayanagi mechanical model, the LPA mechanism on volume shrinkage control, which accounted for phase separation and microvoid formation, and factors leading to both a good volume shrinkage control and acceptable internal pigmentability for the molded parts are discussed. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3388–3397, 2004 相似文献
966.
967.
A gel polymer electrolyte based on poly(acrylonitrile-co-styrene) as polymer matrix and N-methyl pyridine iodide salt as I− source was prepared. Controlling the concentration of polymer matrix of poly(acrylonitrile-co-styrene) at 17.5 wt.%, mixing the binary organic solvents mixture ethylene carbonate and propylene carbonate with 6:4 (w/w), and the concentration of N-methyl pyridine iodide and iodine with 0.5 and 0.05 M, respectively, the gel polymer electrolyte attains the maximum ionic conductivity (at 30 °C) of 4.63 mS cm−1. Based on the gel polymer electrolyte, a quasi-solid state dye-sensitized solar cell was fabricated and its overall energy conversion efficiency of light-to-electricity of 3.10% was achieved under irradiation of 100 mW cm−2. 相似文献
968.
Qin Kuang Shui-Chao Lin Xian-Hua Zhang Su-Yuan Xie Rong-Bin Huang Lan-Sun Zheng 《Carbon》2006,44(7):1166-1172
A simple and efficient approach for coating multiwalled carbon nanotubes (MWCNTs) with size-controllable SnO2 nanoparticles by chemical vapor deposition has been developed using tin hydride (SnH4) gas as the source of SnO2 at 550 °C. The size and coverage of SnO2 nanoparticles can be adjusted by simply controlling the deposition time and the flow rate of the SnH4/N2 mixture gas during the CVD procedure. In addition, by using the MWCNTs as a sacrificial template, a kind of one-dimensional chain-like SnO2 nanostructure has been synthesized by increasing the deposition temperature to 730 °C. This technique may provide a good way to produce tunable SnO2-MWCNT composites. 相似文献
969.
970.
The effects of comonomer composition of the curing kinetics of unsaturated polyester (UP) resins at 100–120°C were investigated by differential scanning calorimetry (DSC) and infrared spectroscopy (IR) over the entire conversion range. One commercial UP resin, UP2821, with 6.82 unsaturated C?C bonds per polyester molecule, was used. For styrene/UP2821 reactions, experimental results of the initial and maximum reaction rates by DSC at 100–120°C revealed that the styrene content, as well as the reaction temperature, would affect the formation of microgel structures. As the initial molar ratio of styrene to polyester C?C bonds increased, the styrene swelling effect could enhance the intramicrogel crosslinking reactions, while the styrene dilution effect could diminish the intermicrogel crosslinking reactions. The competition between the two reactions would depend on the reaction temperatures. Finally, a microgel-based reaction mechanism was proposed for the high temperature reactions. © 1993 John Wiley & Sons, Inc. 相似文献