全文获取类型
收费全文 | 94604篇 |
免费 | 9582篇 |
国内免费 | 5566篇 |
专业分类
电工技术 | 7280篇 |
技术理论 | 5篇 |
综合类 | 7485篇 |
化学工业 | 14390篇 |
金属工艺 | 5706篇 |
机械仪表 | 6163篇 |
建筑科学 | 7454篇 |
矿业工程 | 2832篇 |
能源动力 | 2558篇 |
轻工业 | 9398篇 |
水利工程 | 2159篇 |
石油天然气 | 4440篇 |
武器工业 | 1045篇 |
无线电 | 10926篇 |
一般工业技术 | 10100篇 |
冶金工业 | 3655篇 |
原子能技术 | 1135篇 |
自动化技术 | 13021篇 |
出版年
2024年 | 394篇 |
2023年 | 1586篇 |
2022年 | 3246篇 |
2021年 | 4222篇 |
2020年 | 3238篇 |
2019年 | 2543篇 |
2018年 | 2913篇 |
2017年 | 3190篇 |
2016年 | 2833篇 |
2015年 | 4240篇 |
2014年 | 5229篇 |
2013年 | 6058篇 |
2012年 | 7116篇 |
2011年 | 7570篇 |
2010年 | 6758篇 |
2009年 | 6503篇 |
2008年 | 6564篇 |
2007年 | 5922篇 |
2006年 | 5498篇 |
2005年 | 4421篇 |
2004年 | 3114篇 |
2003年 | 2725篇 |
2002年 | 2594篇 |
2001年 | 2235篇 |
2000年 | 1797篇 |
1999年 | 1534篇 |
1998年 | 1099篇 |
1997年 | 939篇 |
1996年 | 767篇 |
1995年 | 684篇 |
1994年 | 494篇 |
1993年 | 382篇 |
1992年 | 312篇 |
1991年 | 243篇 |
1990年 | 199篇 |
1989年 | 152篇 |
1988年 | 102篇 |
1987年 | 65篇 |
1986年 | 48篇 |
1985年 | 39篇 |
1984年 | 26篇 |
1983年 | 20篇 |
1982年 | 26篇 |
1981年 | 16篇 |
1980年 | 29篇 |
1979年 | 11篇 |
1977年 | 9篇 |
1976年 | 7篇 |
1959年 | 9篇 |
1951年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
992.
MgF2基催化剂合成CH2F2的研究 总被引:1,自引:2,他引:1
用混合法制备了一系列含Cr3+和过渡金属助剂的MgF2基催化剂。考察了助剂对CrF3/ MgF2 催化剂氟化CH2Cl2的催化性能,结果表明,在Cr3+/ MgF2中添加一定的Co2+和Ni2+能提高催化剂稳定性,延长使用寿命;Zn2+能提高CH2F2的选择性;Fe3+和Cu2+对Cr3+/ MgF2的活性有抑制作用。讨论了配料比、空速和温度等反应条件对催化剂性能的影响。 相似文献
993.
994.
Summary The complex forming poly[(ethylene glycol-co-proplene glycol)-g-acrylamide]: polyacrylic acid interpenetrating polymer network hydrogel is able to bend under electric field stimuli. pH, ionic strength gradients and voltage can influence it's bending degree. So we may improve the sample' responsive speed through manipulating those factor in the further study in order to put it into the biomedical application. 相似文献
995.
为了研究抑制剂对银核和硫化银核的不同作用,本工作考察了1-苯基-5-巯基四氮唑(PMT)和苯并三氮唑(BTA)作为抑制剂在银核和硫化银核上物理显影的阳极抑制和解抑制效应。实验结果表明:1)PMT和BTA对Ag核和银离子过量时制得的硫化银核,Ag2S(Ag),的显影催化活性都有不同程度的抑制作用,而对硫离子过量时制得的硫化银核,Ag2S(S),无明显的抑制作用,这可能是由于过量硫离子在硫化银核上的吸附要强于这两种抑制剂;2)S2O3^2-或I^-离子的存在对BTA在Ag核上有解抑制作用,不仅可恢复甚至提高Ag核的显影催化活性,而对Ag2S核的抑制作用无明显影响;3)与BTA不同,S2O3^2-或I^-离子对PMT在Ag核上没有解抑制作用,对Ag2S(Ag)核的抑制作用还稍有增强,而对Ag2S(S)核稍有减弱;4)银溶胶中的表面增强拉曼谱(SERS)测量证实:BTA在Ag核上的吸附导致Ag核显影催化活性的下降,加入S2O3^2-或I^-离子后致使BTA的SERS信号消失则意味着BTA在银核表面的脱附。以上这些结果说明阳极抑制机理在抑制效应中有重要作用。 相似文献
996.
Several Mg–Y binary ribbons with Y content up to 17.9 at.% were fabricated by melt-spinning. X-ray diffraction (XRD) revealed that the phase structure changes with increasing Y content from extended solid solution to partially amorphous, and then fully intermetallic Mg24Y5. Anodic potentiodynamic polarization performed in 0.01 M NaCl electrolyte (pH=12) revealed improved anodic passivity behavior compared to pure Mg for all the Mg–Y alloys. X-ray photoelectron spectroscopy (XPS) revealed that the improved passivity of Mg–Y was more related to the elemental oxidation state rather than the concentration of the surface components. To study the effect of Cl− ion on the passivity behavior, anodic potentiodynamic and potentiostatic polarization were performed on Mg–17.9 at.% Y in alkaline (pH=12) NaCl electrolytes containing Cl− ion in the concentration range from 0.00 to 0.50 M. The passive films formed in 0.01 M NaCl electrolyte were similar to the native film, which were composed of MgO and Y2O3. No CO32− and Cl− ions were incorporated into the passive film. The passivity was significantly degraded in the electrolytes containing higher Cl− concentration (0.1 and 0.5 M). Detailed XPS revealed that the surface films under these conditions were composed of much hydrated species Mg(OH)2 and YOOH and/or Y(OH)3 and CO32− was incorporated into the surface film. The incorporation of Y2O3 in the passive film was given as the reason for the enhanced passivity properties of Mg–Y ribbons. The mechanism of Cl− and CO32− ions to the degradation of the passivity was discussed. 相似文献
997.
聚丙烯/轻质碳酸钙/三单体固相接枝物复合体系结构与性能的研究 总被引:3,自引:0,他引:3
将聚丙烯与马来酸酐、甲基丙烯酸甲酯、丙烯酸丁酯三种单体的固相接枝物应用于聚丙烯侥质碳酸钙复合体系,研究接枝物对复合体系力学性能、微观形态和耐热性等的影响。结果表明,在PP中加入CaCO3进行填充改性,在一定用量的三单体固相接枝物作用下,PP的力学性能及耐热性得到明显的提高。 相似文献
998.
Donggang Yao Pratapkumar Nagarajan Lei Li Allen Y. Yi 《Polymer Engineering and Science》2007,47(4):530-539
An embossing strategy involving a hot station and a cold station for sequentially heating and cooling the embossing tool was investigated to reduce cycle times in hot embossing polymer microstructures. Experimental studies showed that aluminum stamps with a thickness of 1.4 mm can be rapidly heated from room temperature to 200°C in 3 s using contact heating against a hot station at 250°C. Microchannels and microlenses were successfully embossed onto high‐density polyethylene and acrylonitrile–butadiene–styrene substrates using a heating time less than 3 s and a total cycle time around 10 s. The two‐station embossing process for the microlens was also numerically studied. The simulated filling behavior agreed with the experimental observation and the predicted thermal and deformation history of the polymer offered a good explanation on the experimentally observed process characteristics. POLYM. ENG. SCI., 47:530–539, 2007. © 2007 Society of Plastics Engineers. 相似文献
999.
The transparent and flexible solid polymer electrolytes (SPEs) were fabricated from polyacrylonitrile‐polyethylene oxide (PAN‐PEO) copolymer which was synthesized by methacrylate‐headed PEO macromonomer and acrylonitrile. The formation of copolymer is confirmed by Fourier‐transform infrared spectroscopy (FTIR) measurements. The ionic conductivity was measured by alternating current (AC) impedance spectroscopy. Ionic conductivity of PAN‐PEO‐LiClO4 complexes was investigated with various salt concentration, temperatures and molecular weight of PEO (Mn). And the maximum ionic conductivity at room temperature was measured to be 3.54 × 10?4 S/cm with an [Li+]/[EO] mole ratio of about 0.1. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 461–464, 2006 相似文献
1000.
Photoinitiated crosslinking of EVA in the presence of benzophenone (BP) as photoinitiator and triallyl isocyanurate (TAIC) as crosslinker and characterization of the related properties have been studied by gel determination, heat extension, DSC, DMTA, TGA, and mechanical measurements. The photoinitiated crosslinking efficiency of the EVA‐BP‐TAIC system and various factors affecting the crosslinking process, such as photoinitiator and crosslinker and their concentrations, irradiation temperature, and irradiation atmosphere were studied in detail and optimized by comparison of gel contents. The results show that the EVA samples with a thickness of 1 mm are readily crosslinked to a gel content of above 80% with 5 s UV‐irradiation under optimum conditions. The data from the heat extension and DSC show that the crosslinking density of photocrosslinked EVA increase and their crystallinities decrease with increasing the UV‐irradiation time. At the same time, photocrosslinking of EVA leads to a lowering of the melt temperature and a decrease of heat of fusion. The DMTA results show that photocrosslinking increases the amorphous phase and storage modulus of the crosslinked EVA, but does not change the glass transition temperature. The data from TGA and mechanical tests give evidence that the thermal stability and mechanical properties of photocrosslinked EVA samples are much better than those of the uncrosslinked EVA. POLYM. ENG. SCI., 47:1761–1767, 2007. © 2007 Society of Plastics Engineers 相似文献