Synthesis of chiral polymers containing the acetoxybornyl group and their applications on the asymmetric induction

Optically active 2-endo-actoxy-5-endo-bornyl methacrylate (ABMA) was prepared from (+)-camphor. The homopolymerization of ABMA and copolymerization of ABMA with achiral methyl methacrylate (MMA) or styrene (St) were carried out with 2,2′-azobisisobutyronitrile (AIBN) in benzene. Effects of temperature, solvents, and reaction time on the copolymerization were discussed. The monomer reactivity ratios(r₁, r₂) for poly(ABMA-co-MMA) and poly(ABMA-co-St) and Q and e values for the chiral ABMA in the copolymerization systems were evaluated by the Fineman—Ross method. The absolute value of the specific rotation of poly(ABMA-co-MMA) increased with increasing ABMA unit content. A small deviation from linearity was observed, which suggests that asymmetry is not introduced into the copolymer main chain. Temperature and solvent effects on the specific rotation of the chiral homopolymer and copolymers were investigated. The results suggest that the chiral polymers synthesized in this investigation did not show a strong preference for a particular helical conformation. Applications of the chiral polymers on the asymmetric addition of n-butyllithium to aldehydes were also discussed.     

Modification of a carbon/carbon composite with a thermosetting resin precursor as a matrix by the addition of carbon black

Carbon/carbon composites were made through the pyrolysis of stabilized PAN felt and phenolic resin with the addition of 5 or 10 wt % carbon black to the matrix and then heat treatment at 600–2500°C. The effects of adding carbon black to the matrix precursor on the physical properties, microstructure, and mechanical properties of the resultant composites were investigated. Adding carbon black not only reduced the weight loss but also limited the shrinkage of the resultant composites. Adding carbon black also accelerated the formation of carbon basal planes in the matrix. At 2500°C, the crystalline stacking height in the composite with 10 wt % added carbon black was 200% greater than that with no additive. The flexural strength of the composite also increased from 15 to 42 MPa (almost 300%). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 333–337, 2006     

TREOR多晶X射线衍射图指标化程序的适用性

多晶Ｘ射线衍射图指标化的ＴＲＥＯＲ程序已被普遍采用，特别是在硅酸盐矿物等材料的晶体结构研究工作中应用很多。然而，实际上它存在着一定的缺陷，有可能得出错误的结果。本文对这一程序作了详细的检验，发现即使在理想条件下它都不适用于低对称晶系的指标化。在对程序作改进以后，该程序可适用于高对称晶系多晶衍射的指标化     

二氧化硫在钒催化剂上氧化动力学的研究——Ⅲ.几种工业钒催化剂的动力学方程式的比较

<正>作者等过去的工作已经证实,由于扩散过程的影响、温度范围的不同、或化学组成的差异,二氧化硫在钒催化剂上的氧化动力学方程式可能具有不同的形式。反应物及生成物与催化剂之间的相互作用,可能使催化剂具有不同的颜色与活性,因而即使温度相同,由于催化剂在层内所处的部位不同,其催化活性可能并不一致。这些复杂性给工业设计带来了很大的困难。因此,合理的简化是完全必要的。 作者等选取了几种不同的工业钒催化剂,用实验方法求得了适用于它们的动力学方程式,进行比较和讨论,提出了一个简便的、合理的、可以用作设计基础的动力学方程式。     

Soy protein combined with copper and boron compounds for providing effective wood preservation

Chromated copper arsenate (CCA), an arsenicbased wood preservative, is toxic to human health and the environment. Although CCA is stable in seasoned wood, there are potential dangers during CCA manufacture, lumber treatment, and waste disposal. This research was conducted to study the effectiveness of soy products to replace toxic chromium and arsenic compounds in wood preservative formulations. Three soy product (Arpro 2100, HM 90, and Supro 760) were used as fixative agents in preservative solutions containing anhydrous CuSO₄ and Na₂B₄O₇·10H₂O. The decay resistance of treated wood blocks was measured by a soil-block culture method. Despite the large molecular sizes of copper-protein and copper-boron-protein complexes, southern pine sapwood was treatable with these preservative formulations. Wood samples treated with >6 kg°m⁻³ CuSO₄ and 7.5 kg·m⁻³ soy product, and subsequently leached for 3 d and exposed to the decay fungus Gloeophyllum trabeum (Fr.) Mur., sustained only 0.5% weight loss over 12 wk. Wood samples needed 40 kg·m⁻³ CuSO₄ and 50 kg·m⁻³ soy protein to resist the copper-tolerant decay fungus Postia placenta (Fr.) M. Lars. & Lomb. These results suggest that soy-based wood preservatives can prevent wood products from fungal attack and can replace CCA.     

An efficient mode decision algorithm for H.264/AVC intra prediction

Multimedia Tools and Applications - Rate distortion optimization technique is adopted by H.264/AVC to select the best intra and inter prediction modes. It achieves remarkable improvement in...     

Authorized workflow schemas: deciding realizability through \mathsf{LTL }(\mathsf{F }) model checking

Many business processes are modeled as workflows, which often need to comply with business rules, legal requirements, and authorization policies. Workflow satisfiability is the problem of determining whether there exists a workflow instance that realizes the workflow specification while simultaneously complying with such constraints. This problem has already been studied by the computer security community, with the development of algorithms and the study of their worst-case complexity. These solutions are often tailored to a particular workflow model and are, therefore, of little or no use in analyzing different models; their worst-case complexities are likely to be an unreliable judge of their feasibility; and they lack support for other forms of analysis such as the determination of the smallest number of users required to satisfy a workflow specification. We propose model checking of an NP-complete fragment $\mathsf{LTL }(\mathsf{F })$ of propositional linear-time temporal logic as an alternative solution. We report encodings in LTL(F) that can compute a set of solutions (thus deciding satisfiability), compute minimal user bases and a safe bound on the resiliency of satisfiability under the removal of users. These theoretical contributions are validated through detailed experiments whose results attest to the viability of our proposed approach.     

Synthesis and kinetic studies of UV‐curable urethane‐acrylates

The UV‐curable urethane‐acrylates based on 2‐hydroxyethyl methacrylate (HEMA)‐terminated polyurethane (PU) for lithographic and coating applications are investigated in this study. Series of PU prepolymers were made from 4,4‐diphenyl methane diisocyanate (MDI), poly(propylene oxide) glycol (PPG 400), poly(butylene adipate)glycol (PBA 500), or poly(tetramethylene oxide) glycol (PTMO 1000) and are terminated with HEMA. The 2,2‐azobisisobutyronitrile (AIBN) was used as a UV‐initiator under air atmosphere. The curing kinetics of HEMA‐terminated PU film were studied. The curing analysis, using FTIR and reaction kinetics, indicate the reaction rate equation correlates well with the film thickness [T], initiator concentration [I], unreacted double bond concentration [C?C], and exposed energy [E] of the reaction system. The kinetic rate equation for the UV‐curable reaction can be written as © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3162–3166, 2004     

Morphology and characterization of conductive films based on polyaniline‐coated polystyrene latexes

The polyaniline (PANI)‐coated polystyrene (PS) latexes were synthesized, and the electrically conductive films were prepared thereafter. The weight ratio of PANI was 5%. Thermal analysis of the latices was performed using DSC and TGA. In this study, the electrically conductive films were prepared above the PS glass transition temperature (T_g). During the film formation, the effects of the annealing temperature and atmosphere (air or N₂) on the film resistance were investigated. In addition, the film morphology was observed utilizing scanning electron microscopy. The film resistance decreased in the initial heating stage due to the increasing temperature and the compaction of film. Then the film resistance increased with further annealing due to the aging of PANI. Typically, the film resistance was about 6000 Ω/sq, and the conductivity was 0.3 S/cm. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5406–5413, 2006     

多媒体教学服务系统的设计

本文从实际使用出发,提出了多媒体教学系统的设计思路,主要介绍了多媒体教学系统的系统结构、主要系统功能等。