Efficient recovery of CO2 from flue gas by clathrate hydrate formation in porous silica gels

Thermodynamic measurements and NMR spectroscopic analysis were used to show that it is possible to recover CO2 from flue gas by forming a mixed hydrate that removes CO2 preferentially from CO2/N2 gas mixtures using water dispersed in the pores of silica gel. Kinetic studies with 1H NMR microimaging showed that the dispersed water in the silica gel pore system reacts readily with the gas, thus obviating the need for a stirred reactor and excess water. Hydrate phase equilibria for the ternary CO2-N2-water system in silica gel pores were measured, which show that the three-phase hydrate-water-rich liquid-vapor equilibrium curves were shifted to higher pressures at a specific temperature when the concentration of CO2 in the vapor phase decreased. 13C cross-polarization NMR spectral analysis and direct measurement of the CO2 content in the hydrate phase suggested that the mixed hydrate is structure I at gas compositions of more than 10 mol % CO2, and that the CO2 molecules occupy mainly the more abundant 5(12)6(2) cages. This makes it possible to achieve concentrations of more than 96 mol % CO2 gas in the product after three cycles of hydrate formation and dissociation. 1H NMR microimaging showed that hydrate yields of better than 85%, based on the amount of water, could be obtained in 1 h when a steady state was reached, although approximately 90% of this yield was achieved after approximately 20 min of reaction time.     

Computerized segmentation of whole-body bone scintigrams and its use in automated diagnostics

Bone scintigraphy or whole-body bone scan is one of the most common diagnostic procedures in nuclear medicine used in the last 25 years. Pathological conditions, technically poor image resolution and artefacts necessitate that algorithms use sufficient background knowledge of anatomy and spatial relations of bones in order to work satisfactorily. A robust knowledge based methodology for detecting reference points of the main skeletal regions that is simultaneously applied on anterior and posterior whole-body bone scintigrams is presented. Expert knowledge is represented as a set of parameterized rules which are used to support standard image-processing algorithms. Our study includes 467 consecutive, non-selected scintigrams, which is, to our knowledge the largest number of images ever used in such studies. Automatic analysis of whole-body bone scans using our segmentation algorithm gives more accurate and reliable results than previous studies. Obtained reference points are used for automatic segmentation of the skeleton, which is applied to automatic (machine learning) or manual (expert physicians) diagnostics. Preliminary experiments show that an expert system based on machine learning closely mimics the results of expert physicians.     

The role of ceramic and glass science research in meeting societal challenges: Report from an NSF‐sponsored workshop

Under the sponsorship of the U.S. National Science Foundation, a workshop on emerging research opportunities in ceramic and glass science was held in September 2016. Reported here are proceedings of the workshop. The report details eight challenges identified through workshop discussions: Ceramic processing: Programmable design and assembly; The defect genome: Understanding, characterizing, and predicting defects across time and length scales; Functionalizing defects for unprecedented properties; Ceramic flatlands: Defining structure‐property relations in free‐standing, supported, and confined two‐dimensional ceramics; Ceramics in the extreme: Discovery and design strategies; Ceramics in the extreme: Behavior of multimaterial systems; Understanding and exploiting glasses and melts under extreme conditions; and Rational design of functional glasses guided by predictive modeling. It is anticipated that these challenges, once met, will promote basic understanding and ultimately enable advancements within multiple sectors, including energy, environment, manufacturing, security, and health care.     

The IoT Architectural Framework,Design Issues and Application Domains

The challenge raised by the introduction of Internet of Things (IoT) concept will permanently shape the networking and communications landscape and will therefore have a significant social impact. The ongoing IoT research activities are directed towards the definition and design of open architectures and standards, but there are still many issues requiring a global consensus before the final deployment. The paper presents and discusses the IoT architectural frameworks proposed under the ongoing standardization efforts, design issues in terms of IoT hardware and software components, as well as the IoT application domain representatives, such as smart cities, healthcare, agriculture, and nano-scale applications (addressed within the concept of Internet of Nano-Things). In order to obtain the performances related to recently proposed protocols for emerging Industrial Internet of Things applications, the preliminary results for Message Queuing Telemetry Transport and Time-Slotted Channel Hopping protocols are provided. The testing was performed on OpenMote hardware platform and two IoT operating systems: Contiki and OpenWSN.     

Thermodynamic Aspects of Molluscan Shell Ultrastructural Morphogenesis

Over the years, molluscan shells have become an exemplar model system to study the process of mineral formation by living organisms, the process of biomineralization. Typically, the shells consist of a number of mineralized ultrastructural motifs, each exhibiting a specific mineral‐organic composite architecture. These are made of calcium carbonate building blocks having a well‐defined three‐dimensional morphology that is significantly different from the shape of inorganically formed counterparts. Shell ultrastructures are known to form via a biologically controlled extracellular mineralization pathway in which the organism has no direct control over mineral formation. The cellular tissue, responsible for shell biomineralization, forms an organic framework and sets‐up the physical conditions necessary for the deposition of a specific morphology, whereas the growth of the mineral part of the shell proceeds spontaneously via the process of self‐assembly. In this feature article, the ability to employ thermodynamic models from classical materials science to describe the process of self‐assembly and structural evolution of a variety of shell architectures is reviewed. Having the potential to offer an analytical framework to express ultrastructure formation in time and in space, these models not only provide a deeper insight into shell biomineralization, but also suggest tools for novel composite materials design.     

Materials Nanoarchitecturing via Cation‐Mediated Protein Assembly: Making Limpet Teeth without Mineral

Teeth are designed to deliver high forces while withstanding the generated stresses. Aside from isolated mineral‐free exception (e.g., marine polychaetes and squids), minerals are thought to be indispensable for tooth‐hardening and durability. Here, the unmineralized teeth of the giant keyhole limpet (Megathura crenulata) are shown to attain a stiffness, which is twofold higher than any known organic biogenic structures. In these teeth, protein and chitin fibers establish a stiff compact outer shell enclosing a less compact core. The stiffness and its gradients emerge from a concerted interaction across multiple length‐scales: packing of hydrophobic proteins and folding into secondary structures mediated by Ca²⁺ and Mg²⁺ together with a strong spatial control in the local fiber orientation. These results integrating nanoindentation, acoustic microscopy, and finite‐element modeling for probing the tooth's mechanical properties, spatially resolved small‐ and wide‐angle X‐ray scattering for probing the material ordering on the micrometer scale, and energy‐dispersive X‐ray scattering combined with confocal Raman microscopy to study structural features on the molecular scale, reveal a nanocomposite structure hierarchically assembled to form a versatile damage‐tolerant protein‐based tooth, with a stiffness similar to mineralized mammalian bone, but without any mineral.     

Influence of ZnO/graphene nanolaminate periodicity on their structural and mechanical properties

Structural, electronic and mechanical properties of ZnO/Graphene (ZnO/G) nanolaminates fabricated by low temperature atomic layer deposition (ALD) and chemical vapor deposition (CVD) were investigated. We performed scanning and transmission electron microscopy (SEM/TEM), X-ray diffraction (XRD), electron energy loss spectroscopy (EELS), Raman spectroscopy, X-Ray photoelectron spectroscopy (XPS) and nanoindentation to characterize the ZnO/G nanolaminates. The main structural and mechanical parameters of ZnO/G nanolaminates were calculated. The obtained results were analyzed and interpreted taking into account mechanical interaction and charge effects occurring at the G-ZnO interface. The influence of graphene sublayers number on the mechanical behavior of the ZnO/G nanolaminates was studied. By reducing the bilayer thickness, the mechanical parameters of the films can be tuned (Young’s modulus 100–200 GPa, hardness 3–9 GPa). The softer response of the multilayers as compared to the single layers of ZnO and graphene was attributed to the structural changes in the ZnO layer and the interfaces. This study shows the mechanical behavior of ZnO/G nanolaminates and their influence on the development of novel electro-optical devices based on these structures.     

Testing superabsorbent polymer (SAP) sorption properties prior to implementation in concrete: results of a RILEM Round-Robin Test

This article presents the results of a round-robin test performed by 13 international research groups in the framework of the activities of the RILEM Technical Committee 260 RSC “Recommendations for use of superabsorbent polymers in concrete construction”. Two commercially available superabsorbent polymers (SAP) with different chemical compositions and gradings were tested in terms of their kinetics of absorption in different media; demineralized water, cement filtrate solution with a particular cement distributed to every participant and a local cement chosen by the participant. Two absorption test methods were considered; the tea-bag method and the filtration method. The absorption capacity was evaluated as a function of time. The results showed correspondence in behaviour of the SAPs among all participants, but also between the two test methods, even though high scatter was observed at early minutes of testing after immersion. The tea-bag method proved to be more practical in terms of time dependent study, whereby the filtration method showed less variation in the absorption capacity after 24 h. However, absorption followed by intrinsic, ion-mediated desorption of a specific SAP sample in the course of time was not detected by the filtration method. This SAP-specific characteristic was only displayed by the tea-bag method. This demonstrates the practical applicability of both test methods, each one having their own strengths and weaknesses at distinct testing times.     

Finite Element Analysis as a Method to Study Molluscan Shell Mechanics

The clade Mollusca is a highly diverse and disparate group of terrestrial and aquatic invertebrates, the taxon containing over 100 000 known species including some of the most intelligent invertebrate animals. Their shells are exemplar systems in the study of biomechanics, biomineralization, and biomimetics. Research into understanding the superior biomechanical properties of the shell and how these properties relate to the animals ecology have required a diverse range of methods at multiple length scales; one particularly powerful method is finite element analysis. Finite element analysis is a robust engineering method that has a long‐standing history in biomechanical research. This review summarizes the application of finite element analysis in the study of both the mechanical properties of different molluscan shell ultrastructures as well as macro‐scale modeling of the shell. From the calculation of elastic constants to the origins of the strength of nacre and the relationship between shell folding and ecology, this article provides a window into how finite element analysis can further our understanding of mechanics and functional morphology.

     

Design assessment of a multiple passenger vehicle component using load transfer index ($$ {\text{U}}^{*} $$) method

In recent years, the study of the load transfer in the structure has achieved a growing attention from mechanical engineers, specifically in the vehicle industry. To further develop this relatively new branch of structural analysis and in particular the \( {\text{U}}^{*} \) index theory for load transfer analysis, it seems necessary to apply this method to different vehicle components. Therefore, in this study, one of the main load carrying components of a multiple passengers carrying vehicle was chosen for load transfer analysis. This choice has significant importance due to the focus of previous \( {\text{U}}^{*} \) index studies on small passenger vehicles, which have completely different structure and load paths. Another important feature of this study is the application of a sophisticated and detailed approach for choosing the loading and boundary condition. To address an actual working condition, a full model of the vehicle was analyzed under different working loads and the most severe loading condition was selected for this study. Then, a detailed \( {\text{U}}^{*} \) index analysis was performed on the structure to evaluate the load transfer for both loading and reaction forces. Based on the results of this analysis, parts with questionable stiffness were located and a design modification was proposed to improve the structural behavior. In addition, to verify the computer model and conclusions of the \( {\text{U}}^{*} \) index analysis, the structure was tested physically under same loading condition. Finally, the proposed modified design of the structure was analyzed with \( {\text{U}}^{*} \) index theory, and using the design criteria suggested in the theory, it was shown that the new design has great potential for better performance and more efficient load transfer.