Organic Materials and Thin‐Film Structures for Cross‐Point Memory Cells Based on Trapping in Metallic Nanoparticles

Non‐volatile solid‐state memory cells based on composites of metal nanoparticles and polymers are embedded in organic semiconducting host materials. This paper presents data from a wide range of materials and device structures and shows that the switching phenomenon is commonly observed.     

Single‐Source Precursors For Synthesizing Bifunctional Periodic Mesoporous Organosilicas

A new class of bifunctional periodic mesoporous organosilicas (PMOs) composed of organosilicate building blocks with two different silicon sites have been synthesized from the single‐source bifunctional organosilica precursors tris(triethoxysilylethyl)ethoxysilane and bis(triethoxysilylethyl)diethoxysilane, respectively denoted MT³‐PMO and DT²‐PMO. The synthesis of these PMOs is achieved by the co‐assembly of a triblock‐copolymer Pluronic P123 template with the bifunctional organosilica precursor under acid‐catalyzed and inorganic‐salt‐assisted conditions. After template removal through solvent extraction, the MT³‐PMO and DT²‐PMO so obtained show well‐ordered mesopores and display large pore diameters (6–7 nm) and pore volumes (0.6–0.8 cm³ g^–1) with a narrow pore‐size distribution and high surface areas (700–800 m³ g^–1).     

Nonparametric bootstrapping of the reliability function for multiple copies of a repairable item modeled by a birth process

Nonparametric bootstrap inference is developed for the reliability function estimated from censored, nonstationary failure time data for multiple copies of repairable items. We assume that each copy has a known, but not necessarily the same, observation period; and upon failure of one copy, design modifications are implemented for all copies operating at that time to prevent further failures arising from the same fault. This implies that, at any point in time, all operating copies will contain the same set of faults. Failures are modeled as a birth process because there is a reduction in the rate of occurrence at each failure. The data structure comprises a mix of deterministic & random censoring mechanisms corresponding to the known observation period of the copy, and the random censoring time of each fault. Hence, bootstrap confidence intervals & regions for the reliability function measure the length of time a fault can remain within the item until realization as failure in one of the copies. Explicit formulae derived for the re-sampling probabilities greatly reduce dependency on Monte-Carlo simulation. Investigations show a small bias arising in re-sampling that can be quantified & corrected. The variability generated by the re-sampling approach approximates the variability in the underlying birth process, and so supports appropriate inference. An illustrative example describes application to a problem, and discusses the validity of modeling assumptions within industrial practice.     

Interface characteristics and mechanical properties of carbon fibre reinforced copper composites

Interface characteristics of carbon fibre reinforced copper matrix composites materials with various interface states and their effect on the flexural strength of composites have been studied. Interfacial states are mechanical bonding, dissolution bonding and reaction bonding. To a certain extent, raising the interfacial strength enables an increase in the flexural strength due to prevention of carbon fibre being pulled out under low stress during fracture process of composites. Raising the interfacial bondage strength, causes the brittleness of composites to increase; the fracture surface of composites is converted from a fibre pull-out model to a fibre even model. While strengthening the interface bondage, the extent of chemical reaction and dissolution at the interface must be controlled to avoid degrading the carbon fibre.     

Process issues in treatment: Application to sexual offender programs.

How critical is the therapeutic alliance in the treatment of sexual offenders? To date such process issues have been neglected in the field of sex offender treatment. This article reviews the literature on the influence on behavior change of therapist features, clients' perceptions, and the therapeutic alliance. Among the many therapist features identified as helpful are empathy, warmth, and being directive and rewarding. Therapists who are aggressively confrontational appear not to foster beneficial changes in their clients. These issues are directly related to treatment issues faced by therapists who work with sexual offenders, such as dealing with cognitive distortions, lack of empathy, and lack of motivation to change. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Implementation of a self-timed segmented bus

We propose an asynchronous structure for implementation on a SoC. An intersegment topological arrangement preserves parallelization and, through a so-called central arbiter, efficiently organizes communication with high signaling speed in the proposed structure. Researchers proposed the concept of segmenting buses primarily for multicomputer architectures. More recent approaches address on-chip implementation of segmented buses. We present an asynchronous segmented-bus architecture targeted for the modular design of high-performance SoC applications. The structure not only enables faster operation than a conventional bus system but also offers lower power consumption per transferred data item. This is possible because segmentation is realized in such a way that the majority of data transfers in the system are intrasegment transactions on relatively short wires with low or moderate capacitive loads.