Stretching and deformation vibrations of CH2, C(CH3) and O(CH3) groups of poly(methyl methacrylate)

Infrared and Raman spectra of atactic PMMA and infrared spectra of stereoregular PMMA and of its four deuterated derivatives

, were measured. They were used to assign the bands of stretching and deformation vibrations of CH₂, CCH₃ and OCH₃ groups in the infrared and Raman spectra and to discuss the effect of stereoregularity on these bands in the infrared spectra.     

Flow modelling within non-homogeneous packings: The structural macro-correlations

The pressure drop and the fluid velocity profiles were investigated experimentally and numerically in the model packings of complex geometry. The numerical estimations were performed by means of the hybrid method involving the use of structural macro-correlations. In this paper it has been demonstrated on several examples that the structural macro-correlations allow to predict the macro-scale flow behaviour in non-homogeneous packings. Finally, the recent mechanistic approaches to flow modelling in packed tubes of low tube-to-particle diameter ratio have been discussed.     

Influence of anionic form on thermooxidation of TMAHP–cellulose

With the help of DTA, DTG elementary analysis of carbonized residues and ESR spectroscopy the influence of anionic form on thermooxidation of trimethylammoniumhydroxyprophyl (TMAHP)–cellulose was studied. At 300°C the percentage of carbon in carbonized residue thermolyzed in oxidative atmosphere is higher than for the sample degraded in inert atmosphere. The percentage of hydrogen decreases simultaneously. The concentration of free radicals in thermolyzed residue also increases due to the presence of oxygen. We propose that oxygen is abstracting the hydrogen atoms from polysaccharide and unpaired electrons on carbon atoms are produced. At 400°C the percentage of carbon in residues prepared at inert atmosphere is higher than for residue formed at oxidative atmosphere. Also the concentration of free radicals in thermolyzed residues obtained in inert atmosphere is greater than for those from oxidative ones. That is why suppose that at this temperature oxygen is bonded to polysaccharide residue and free radicals are terminated. From the semiquantitative DTA we can make the following sequence of samples according to their increasing thermooxidative effect: unmodified cellulose < A–HSO < A–Br^? < A–I^? < A–NO < A–H₂PO < A–CH₃COO^? < A–HCO < A–F^? < A–Cl^?1 < A–OH^p?.     

Boolean factors as a means of clustering of interestingness measures of association rules

Measures of interestingness play a crucial role in association rule mining. An important methodological problem, on which several papers appeared in the literature, is to provide a reasonable classification of the measures. In this paper, we explore Boolean factor analysis, which uses formal concepts corresponding to classes of measures as factors, for the purpose of clustering of the measures. Unlike the existing studies, our method reveals overlapping clusters of interestingness measures. We argue that the overlap between clusters is a desired feature of natural groupings of measures and that because formal concepts are used as factors in Boolean factor analysis, the resulting clusters have a clear meaning and are easy to interpret. We conduct three case studies on clustering of measures, provide interpretations of the resulting clusters and compare the results to those of the previous approaches reported in the literature.     

Invariant‐set‐based fault diagnosis in Lure systems

In this paper, we present an invariant‐set‐based method for actuator and sensor fault detection and isolation in Lure systems. The Lure plant is controlled by an observer‐based feedback tracking controller, designed for the nominal (fault‐free) system. Suitable residual signals are constructed from measurable system outputs and estimates associated with the nominal observer. Faults are diagnosed by online contrasting the residual signal trajectories against sets of values that the residuals are shown to attain under healthy or faulty operation. These values are obtained via set‐invariance analysis of the system closed‐loop trajectories. Copyright © 2013 John Wiley & Sons, Ltd.     

Differentiating seawater and groundwater sulfate attack in Portland cement mortars

The study reported in this article deals with understanding the physical, chemical and microstructural differences in sulfate attack from seawater and groundwater. Portland cement mortars were completely immersed in solutions of seawater and groundwater. Physical properties such as length, mass, and compressive strength were monitored periodically. Thermal analysis was used to study the relative amounts of phases such as ettringite, gypsum, and calcium hydroxide, and microstructural studies were conducted by scanning electron microscopy. Portland cement mortars performed better in seawater solution compared to groundwater solution. The difference in performance could be attributed to the reduction in the quantity of the expansive attack products (gypsum and ettringite). The high Cl concentration of seawater could have played an important role by binding the C₃A to form chloroaluminate compounds, such as Friedel's salt (detected in the microstructural studies), and also by lowering the expansive potential of ettringite. Furthermore, the thicker layer of brucite forming on the specimens in seawater could have afforded better protection against ingress of the solution than in groundwater.     

X-ray crystal structure of the dye 2-cyano-4-bromo-4′-N,N-diethylaminoazobenzene

The crystal structure and molecular conformation of 2-cyano-4-bromo-4′-N,N-diethylaminoazobenzene (C₁₇H₁₇N₄Br, mol. wt. = 357·2 a.m.u) has been determined from X-ray diffraction data; triclinic, P$\text{1}$ (No. 2), a = 10·132(11) Å, b = 12·216(16) Å, c = 6·966(11) Å, α = 104·21(9)°, β = 92·67(12)°, γ = 97·22(7)°, V = 826·5(9) ų, Z = 2, D_c = 1·436 g cm^?3, F(000) = 378, λ(MoKα) = 0·71069 Å, μ(MoKα) = 26·0 cm^?1. The structure was solved by the multiple solution direct method and refined by full-matrix least-squares to R = 0·059 for 1538 independent observed reflections. The azobenzene skeleton is planar to within 0·06 Å. Most significant bonding data are: NN, 1·290(8) Å; BrC, 1·866(6) Å; mean CN (azo) 1·380(8) Å; NNC, 113·6(4) and 115·3(4)°; NCC (cis relative to NN) 125·9(4)° and 126·7(4)°; NCC (trans) 116·8°(5)° and 116·1(4)°.     

Efficacy of iron fortification compared to iron supplementation among Vietnamese schoolchildren

Background  

Parents of six children are facing a trial on charges of aggravated manslaughter in the care a 5 1/2 month old infant who died suddenly and neglect of their four older children for causing them to be malnourished by feeding them all an exclusively raw foods vegan diet. Both parents declined plea bargains and plan to defend themselves in court.     

The pheromone of the eastern tent caterpillar,Malacosoma americanum (F.) (lepidoptera,Lasiocampidae)

The pheromone system of the eastern tent caterpillar,M. americanum, has been identified as a mixture of (E,Z)-5,7-dodecadienal and the corresponding alcohol. Field data on the attractiveness of the aldehyde alone were not consistent, but mixtures of aldehyde and alcohol in varying proportions were attractive to males. Addition of small amounts ofE,Z acetate toE,Z aldehyde had no effect on male response, but larger amounts reduced trap catch. Traps baited withZ,E, E,E, orZ,Z aldehydes were not more attractive than blank traps. Pherocon IC traps fortified with extra adhesive and baited with lures consisting of 500 µg (E,Z)-5,7-dodecadienal with either 250 or 100 µg of the corresponding alcohol trapped as many as 100 males/trap/night with means of 15–20. Lures prepared from purified (94%E,Z) aldehyde and alcohol were more attractive than those prepared from unpurified (58%E,Z) materials.DeceasedMention of a company name or proprietary product does not constitute an endorsement by the U.S. Department of Agriculture.     

Theoretical assessment of the catalytic (Pt/TiO2) oxidation of formaldehyde at ambient temperature

A recent article [C. Zhang, H. He, K. Tanaka, Catal. Commun. 6 (2005) 211] investigates the use of a Pt/TiO₂ catalyst for the oxidation of formaldehyde. The findings demonstrate nearly complete oxidation at ambient temperature (25 °C) for values of the surface velocity in the range 5–10 × 10⁴ h⁻¹ and a 45% destruction when using a surface velocity of 20 × 10⁴ h⁻¹.In the present communication, this oxidation was assessed by theoretical considerations of the reaction kinetics. The destruction efficiency was predicted using a first-order reaction rate expression, combined with different theoretical or semi-empirical equations for the intrinsic reaction rate constant. Predicted and experimental data are in fair agreement, thus validating the theoretical approach and confirming the experimental results.