Surface modification of macroporous glycidyl methacrylate based copolymers for selective sorption of heavy metals

Two samples of macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), poly(GMA-co-EGDMA), were synthesized by suspension copolymerization and modified with amines. Initial poly(GMA-co-EGDMA), and the samples modified with ethylene diamine [poly(GMA-co-EGDMA)-en], diethylene triamine [poly(GMA-co-EGDMA)-deta] and triethylene tetramine [poly(GMA-co-EGDMA)-teta], were characterized by mercury porosimetry, FTIR spectroscopy and elemental analysis. The most pronounced increase of specific surface area (75%) was observed for poly(GMA-co-EGDMA)-teta sample with smaller particles (D < 150 μm). The Cu(II) sorption was rapid, depending on porosity of amino-functionalized samples and ligand type. For poly(GMA-co-EGDMA)-deta and poly(GMA-co-EGDMA)-teta sorption half time required to reach 50% of total sorption capacity, t _1/2, were around 3 min. Sorption capacities for Cu(II), Co(II), Cd(II) and Ni(II) as well as for Cr(VI), Co(II), Cd(II) and Ni(II) ions were determined under competitive conditions as a function of pH, ligand type and porosity at room temperature. The results indicate selectivity of poly(GMA-co-EGDMA)-deta for Cu(II) over Cd(II) of 3:1 and for Cu(II) over Ni(II) and Co(II) of 6:1. The decrease in particle size of poly(GMA-co-EGDMA)-teta caused the increase of sorption capacities for all metal ions. At pH 1.8 the selectivity of poly(GMA-co-EGDMA)-teta with smaller particles for Cr(VI) over Ni(II), Co(II) and Cd(II) ions was 8.5:1.     

Perspectives of sustainable development in countries of Southeastern Europe

Countries of SE Europe are at very beginning of planning of their development in accordance with theoretical concept of sustainable development. Sustainable development is defined as the basic imperative and the only model of development in a longer period of time. The basic indicators of sustainable development represent a very useful and quality way for measuring and monitoring the state of sustainable development, as in every country individually so as in the regions and globally as a whole. Values of the indicators of all four subsystems in observed countries are within expectation. Also the current level of development of every country separately is taken into account and in accordance to that it is defined the current position of any country in respect to its international requests. The special value is given by the comparison of obtained results of the state in the developed EU countries, according to which there is an impression of equal degree of sustainable development in France and Germany, whereas the data regarding the state of sustainable development in Greece and at Slovenia has been improved between two analysis. Taking into account the results of the previous and current research there is a clear need for regular observation of the state of every indicator individually but also the need to observe the relationship among them as a whole. The special attention needs to be given to the intensive monitoring of indicators of economic and ecological subsystem. The research showed, among other things, to the fragile relationship of values of indicators of economic and ecological subsystem, by which any change in values of one indicator consequently leads to the changes in the final result. Both conducted researches point to the fact that the value of the mentioned indicators changes at the fastest pace.     

The p-hub Model with Hub-catchment Areas,Existing Hubs,and Simulation: A Case Study of Serbian Intermodal Terminals

This paper addresses the problem of optimally locating intermodal freight terminals in Serbia. To solve this problem and determine the effects of the resulting scenarios, two modeling approaches were combined. The first approach is based on multiple-assignment hub-network design, and the second is based on simulation. The multiple-assignment p-hub network location model was used to determine the optimal location of intermodal terminals. Simulation was used as a tool to estimate intermodal transport flow volumes, due to the unreliability and unavailability of specific statistical data, and as a method for quantitatively analyzing the economic, time, and environmental effects of different scenarios of intermodal terminal development. The results presented here represent a summary, with some extension, of the research realized in the IMOD-X project (Intermodal Solutions for Competitive Transport in Serbia).     

An overview of biomass energy utilization in Vojvodina

The Autonomous Province of Vojvodina is an autonomous province in Serbia. It is located in the northern part of the country, in the Pannonia plain. Vojvodina is an energy-deficient province. Energy plays a pivotal role in socio-economic development by raising the standard of living. Biomass has been used by mankind as an energy source for thousands of years. Traditional fuels like firewood, dung and crop residues currently contribute a major share in meeting the everyday energy requirements of rural and low-income urban households in Vojvodina. Contribution of the renewable energy sources in the total consumption of energy in Vojvidina is less than 1%, i.e. it amounts to 280 KWh/year. Production of biodiesel in the year 2008 was 0.07 million tons, what is for 133% higher with respect to the production in the year 2007 (0.03 million tons). In Vojvodina, as the raw materials for bioethanol production are seen primarily sugar beet, corn, wheat surpluses, potato surpluses and waste potato, as well as the raw materials intended for these purposes grown on the uncultivated soils, such as hybrid broomcorn, Jerusalem artichoke and triticale. With introduction of new technologies for cultivation and collecting of biomass production of the electrical energy could be raised to 6.4 GWh/m² year, what, with retention of the contemporary consumption, would represent the significant 9% of the total consumption in the province. According to programme of realisation of energy strategy of Vojvodina/Serbia in the field of the renewable energy sources for to period till the year 2010 and its completion, till the year 2015, in Vojvodina could be created conditions for the employment of about 24,000 workers, i.e. 4000 employed for maintenance of the newly constructed plants, 17,000 employed on designing and manufacturing of plants and 3000 employed in auxiliary activities.