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131.
Adsorption of arsenic from water using activated neutralized red mud 总被引:16,自引:0,他引:16
In this paper activated seawater-neutralized red mud, herein referred to as activated Bauxsol (AB), is used as a novel adsorbent for removing inorganic arsenic (As) from water. The adsorption of As onto AB is studied as a function of contact time, particle size, pH, initial As concentration, AB dosage, and temperature. Kinetic data indicate that the process pseudoequilibrates in 3 and 6 h for As(V) (arsenate) and As(III) (arsenite), respectively, and follows a pseudo-first-order rate expression. Within the range tested, the optimal pH for As(V) adsorption is 4.5, and close to 100% removal can be achieved irrespective of the initial As(V) concentration. Desorption of As(V) is greatest at pH 11.6 where a maximum of 40% can be achieved. In contrast, the optimum pH for As(III) removal is 8.5, and the removal efficiency changes with the initial As(III) concentration. The adsorption data fit the Langmuir isotherm and its linearized form well, with thermodynamic data indicating the spontaneous and endothermic nature of the process. The FITEQL (V.4) and PHREEQC (V.2) computer programs are used to predict As(V) adsorption at various pH values (based on diffuse double layer models). The modeling results fit the experimental results very well and indicate that surface complexation modeling is useful in describing the complex AB surface during the adsorption process. This study shows that As(III) needs to be oxidized to As(V) for a favorable removal using AB and that AB can be a very efficient unconventional adsorbent for removing As(V) from water. 相似文献
132.
介绍了托普索公司新开发的WSA-DC工艺,详述其流程、优点、性能、消耗和生产数据.WSA-DC工艺是一个两次冷凝工艺,它结合了WSA工艺与两转两吸工艺的优点,通过对中间冷凝器的设计改进和仔细控制气体中的H2O/SO2比率,可以用ψ(SO2)等于或高于13%的原料气生产w(H2SO4)为99%的硫酸.以1套540t/d硫磺制酸装置为例,对WSA-DC工艺和传统干法两转两吸工艺进行了技术经济比较. 相似文献
133.
The Falling Lake Victoria Water Level: GRACE,TRIMM and CHAMP Satellite Analysis of the Lake Basin 总被引:2,自引:0,他引:2
Joseph L. Awange Mohammad A. Sharifi Godfrey Ogonda Jens Wickert Erik W. Grafarend Monica A. Omulo 《Water Resources Management》2008,22(7):775-796
In the last 5 years, Lake Victoria water level has seen a dramatic fall that has caused alarm to water resource managers.
Since the lake basin contributes about 20% of the lakes water in form of discharge, with 80% coming from direct rainfall,
this study undertook a satellite analysis of the entire lake basin in an attempt to establish the cause of the decline. Gravity
Recovery And Climate Experiment (GRACE), Tropical Rainfall Measuring Mission (TRMM) and CHAllenging Minisatellite Payload
(CHAMP) satellites were employed in the analysis. Using 45 months of data spanning a period of 4 years (2002–2006), GRACE
satellite data are used to analyse the variation of the geoid (equipotential surface approximating the mean sea level) triggered
by variation in the stored waters within the lake basin. TRMM Level 3 monthly data for the same period of time are used to
compute mean rainfall for a spatial coverage of .25°×.25° (25×25 km) and the rainfall trend over the same period analyzed.
To assess the effect of evaporation, 59 CHAMP satellite’s occultation for the period 2001 to 2006 are analyzed for tropopause
warming. GRACE results indicate an annual fall in the geoid by 1.574 mm/year during the study period 2002–2006. This fall
clearly demonstrates the basin losing water over these period. TRMM results on the other hand indicate the rainfall over the
basin (and directly over the lake) to have been stable during this period. The CHAMP satellite results indicate the tropopause
temperature to have fallen in 2002 by about 3.9 K and increased by 2.2 K in 2003 and remained above the 189.5 K value of 2002.
The tropopause heights have shown a steady increase from a height of 16.72 m in 2001 and has remained above this value reaching
a maximum of 17.59 km in 2005, an increase in height by 0.87 m. Though the basin discharge contributes only 20%, its decline
has contributed to the fall in the lake waters. Since rainfall over the period remained stable, and temperatures did not increase
drastically to cause massive evaporation, the remaining major contributor is the discharge from the expanded Owen Falls dam. 相似文献
134.
丹麦Lynetten污水处理厂运行维护与管理 总被引:1,自引:0,他引:1
对丹麦第一大城市污水处理厂--Lynetten污水处理厂的运行、维护和日常管理进行了详细介绍.同时对该污水处理厂的能耗状况、污泥处理工艺以及污水和污泥处理费用进行了总结和分析. 相似文献
135.
A. Mohammed Hussain Jens V.T. HøghTorben Jacobsen Nikolaos Bonanos 《International Journal of Hydrogen Energy》2012
This report concentrates on high performance anodes appropriate for SOFCs operating at low temperatures (400–600 °C). Symmetrical cells were made by screen printing of Nb-doped SrTiO3 (STN) on both sides of a dense ScYSZ electrolyte. Backbones I (36% porosity) and II (47% porosity) were obtained by sintering STN in air and reducing atmosphere, respectively. The porous microstructures were then infiltrated with Ni and Gd-doped CeO2 (CGO) precursors to incorporate the electrocatalytically active sites. The electrochemical performance of the anode was improved with the increment of Ni-CGO loadings. The gas diffusion impedance was investigated with He and N2 in H2/H2O gas mixtures and by varying the H2O content at 655 °C. This study indicated that the gas diffusion in these electrodes are influenced by Knudsen and bulk diffusion. 相似文献
136.
The genomic distance problem in the Hannenhalli–Pevzner (HP) theory is the following: Given two genomes whose chromosomes are linear, calculate the minimum number of translocations, fusions, fissions and inversions that transform one genome into the other. This paper presents a new distance formula based on a simple tree structure that captures all the delicate features of this problem in a unifying way, and a linear time algorithm for computing this distance. 相似文献
137.
Kirsten Bobzin Nazlim Bagcivan Arnold Gillner Claudia Hartmann Jens Holtkamp Walter Michaeli Fritz Klaiber Maximilian Sch?ngart Sebastian Thei? 《Production Engineering》2011,5(4):415-422
Molding of micro structures by injection molding leads to special requirements for the molds e.g. regarding wear resistance
and low release forces of the molded components. At the same time it is not allowed to affect the replication precision. Physical
vapor deposition (PVD) is one of the promising technologies for applying coatings with adapted properties like high hardness,
low roughness, low Young’s modulus and less adhesion to the melt of polymers. Physical vapor deposition technology allows
the deposition of thin films on micro structures. Therefore, the influence of these PVD layers on the contour accuracy of
the replicated micro structures has to be investigated. For this purpose injection mold inserts were laser structured with
micro structures of different sizes and afterwards coated with two different coatings, which were deposited by a magnetron
sputter ion plating PVD technology. After deposition, the coatings were analyzed by techniques regarding hardness, Young’s
modulus and morphology. The geometries of the micro structures were analyzed by scanning electron microscopy before and after
coating. Afterwards, the coated mold inserts were used for injection molding experiments. During the injection molding process,
a conventional and a variothermal temperature control of the molds were used. The molded parts were analyzed regarding roughness,
structure height and structure width by means of laser microscopy. 相似文献
138.
Karsten Haslbeck Katharina Schwarz Jens M. Hohlfeld Jörg R. Seume Wolfgang Koch 《Journal of aerosol science》2010,41(5):429-438
The exhaled breath of humans contains droplets originating from the lung lining fluid. An analysis of these droplets for non-volatile proteinaceous biomarkers holds potential as a non-invasive diagnosis of lung diseases. To ease the interpretation of the diagnostic results, the source strength of the particles should be known und therefore an understanding of the particle generation process is required. It is assumed that during reopening of a collapsed terminal airway a liquid bridge of the lung lining fluid ruptures and droplets are generated. The objective of our experimental and theoretical study was to clarify the mechanisms of droplet generation for quiet breathing patterns by investigating in detail the number flux and the particle size distribution in the exhaled breath. The process of liquid film rupture is modelled by computational fluid dynamics analysis from which the droplet size distribution is calculated. In addition the number emission flux and the droplet size distribution are systematically measured in the exhaled breath of healthy volunteers. The strong increase of the particle emission flux with tidal volume and the good agreement between measured and calculated droplet number distribution both showing droplets primarily in the submicron range confirm the present hypothesis that reopening of collapsed airway structures associated with the rupture of a surfactant film is the physical mechanism of droplet generation. This was hypothesized previously in the literature. 相似文献
139.
Agnès Rortais Jenya Belyaeva Monica Gemo Erik van der Goot Jens P. Linge 《Food research international (Ottawa, Ont.)》2010,43(5):1553-1556
We evaluated the Medical Information System (MedISys) as an early-warning system for the detection of food- and feed-borne hazards. Nine hazards were selected in the period from January 2007 to March 2009 from the Rapid Alert System for Food and Feed (RASFF) and traced back on MedISys and ProMED-mail. In addition, from January to March 2009, food- and feed-borne (re-)emerging hazards were monitored on MedISys and traced back on ProMED-mail and RASFF. MedISys has demonstrated to be an effective early-warning system for food- and feed-borne hazards. However, further customization is required to improve its sensitivity, in particular by increasing the number of multi-lingual categories related to food and feed items. MedISys tended to detect food- and feed-borne hazards earlier and more frequently than ProMED-mail, but the information from both systems was often complementary. 相似文献