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991.
992.
时延作为无线网络的最基本的性能之一,对网络信息分发、路由协议设计、节点部署等都具有重要意义。与传统的无线网络不同,认知无线电网络的频谱资源具有动态变化性,该特性会对网络时延产生极大的影响。因此,如何对动态频谱环境下的大规模认知无线电网络进行时延分析,是一项很具挑战性的课题。为此,首先对动态频谱环境进行建模,将认知用户的频谱接入过程建模为一个连续时间的马尔可夫链,并建立认知用户的生存函数来量化授权用户活动以及信道数量对频谱环境的影响;其次,将上述模型与首次通过渗流理论结合起来,研究了大规模认知无线电网络时延的伸缩规律,并获取了更为精确的时延与距离比的上限值。理论分析及仿真结果表明,动态频谱环境与密度一样会对时延产生极大影响。研究结论对认知无线电网络的设计具有重要的指导意义。 相似文献
993.
994.
Wei-Gang Ji Ji-Ming Hu Liang Liu Jian-Qing Zhang Chu-Nan Cao 《Progress in Organic Coatings》2006,57(4):439-443
Epoxy resin was modified by a silane monomer, γ-aminopropyltrimethoxy silane (γ-APS), and was used as the protective coatings for LY12 aluminum alloys. The aim of the modification is to reduce the water uptake of polymeric coatings. The water absorption of coatings was measured by coating capacitance method in 3.5 wt.% NaCl aqueous solution. The result indicates that water uptake of epoxy coatings modified with 1.0 wt.% γ-APS decreases compared with pure epoxy coatings, whereas larger amounts of sliane result in the deterioration in performance against water permeation, due to the excessive consumption of epoxide group in epoxy resin by amino-group in silane agent, thus reduce the cross-linking of epxoy coating as a result of presence of excessive curing agent (polyamide). Tg of silane-modified coatings increases slightly after immersion, extremely contrasting with that of pure epoxy coating, which was observed to decrease significantly after water permeation. The formation of Si–O–Si structure resulting from the hydrolysis and condensation of silane components during the immersion in aqueous media may be a reasonable explanation for the abnormal change in Tg of silane-modified coatings. In addition, all silane-modified coatings display better protection performance, which is characterized by higher charge transfer resistances (Rct) and lower double layer capacitance (Cdl) at substrate/electrolyte interface. 相似文献
995.
A novel bisphenol(1,2-dihydro-2-(4-((4-hydroxy)phenyliminomethylidene)phenyl)-4-(4-((4-(4-hydroxy)phenyliminomethylidene)phenoxy)phenyl)(2H)phthalazin-1-one, DPP) and a diamine(1,2-dihydro-2-(4-aminophenyl)-4-(4-(4-aminophenoxy)phenyl)(2H)phthalazin-1-one, DAP) were synthesized and characterized. The novel epoxy polymers containing phthalazinone and/or azomethine moieties were prepared by binary polymerization of DAP (or DPP) with diglycidyl ether of biphenyl A (DGEBA) and ternary polymerization of hybrid curing agents, DAP/DPP (DAP and DPP under different molar ratios) with DGEBA. The cure behaviors of these new epoxy systems were studied by dynamic differential scanning calorimeter (DSC) and Infrared (IR) scans. Especially, the activation energy of DAP/DGEBA calculated by Kissinger and Ozawa methods were 73.8 and 77.4 kJ/mol, respectively. For ternary epoxy system, it was found that hybrid curing agents of DAP/DPP exhibited significant associated effect on their reactivity towards the oxirane group. Glass transition temperatures (Tg's) of these new epoxy polymers were all above 150 °C from the results of DSC, and the initial thermal decomposition temperatures (Td,5%'s) and integral procedure decomposition temperatures (IPDT's) of these new epoxy polymers are above 350 and 850 °C, respectively from results of thermogravimetric analyses (TGA). These results show that new epoxy polymers containing phthalazinone and/or azomethine moieties exhibited excellent thermal properties. Especially, thermal properties of the ternary epoxy polymers could be modified by changing the content of DAP and DPP. The linear relationships between char yield (Yc,wt%) and the structural compositions of these new polymers (weight percentage of phthalazinone, azomethine and nitrogen, C/H weight ratio) were built. 相似文献
996.
997.
Ji Hye Yoon Sang Beom Choi You Jin Oh Min Jeong Seo Young Ho Jhon Tae-Bum Lee Daejin Kim Seung Hoon Choi Jaheon Kim 《Catalysis Today》2007,120(3-4):324-329
A new mixed-valent iron MOF, formulated as Fe3O(F4BDC)3(H2O)3·(DMF)3.5 (1), has been synthesized by using a perfluorinated linear dicarboxylate to link trigonal prismatic Fe3(μ3-O)(O2C–)6 clusters. The structure refinement based on single crystal X-ray diffraction data collected from 1 reveals the material exhibits the acs topology with large channels along the crystallographic c-axis. Due to the presence of fluorine atoms the organic link, 2,3,5,6-tetrafluorobenzene-1,4-dicarboxylate (F4BDC), has a 63° torsion angle between the carboxylate and aromatic planes, resulting in larger channels compared to those in the isoreticular material MOF-235. While few iron-based MOFs have demonstrated porosity, nitrogen and hydrogen sorption experiments carried out at 77 K proved the porosity of outgassed 1, which has a Langmuir surface are of 635 m2/g and a gravimetric capacity of 0.9 wt% of hydrogen at 1 bar. 相似文献
998.
Hong Ma Jie Xu Chen Chen Qiaohong Zhang Jianbo Ning Hong Miao Lipeng Zhou Xiaoqiang Li 《Catalysis Letters》2007,113(3-4):104-108
Co(II)O was highly dispersed in the mesopores of SBA-15 by alcoholic impregnation method and characterized by XRD, TEM, UV–VIS
DRS, TPR, and XRF techniques. It was found that tetrahedral coordinated Co(II)O was stabilized by SBA-15 at low Co-loading.
Co/SBA-15 showed much higher activity than Co(OAc)2 or Co3O4 in the liquid-phase aerobic oxidation of ethylbenzene under solvent-free condition. 相似文献
999.
1000.
有机硅氧烷对硅丙微乳液的影响(英文) 总被引:2,自引:0,他引:2
采用种子乳液聚合法引入乙烯基三异丙氧基硅烷(C-1706)改性丙烯酸酯乳液来制备高性能硅丙微乳液。着重探讨了有机硅氧烷单体及其滴加方式对乳液性能的影响,发现引入1.5%的C-1706可将乳液涂膜的硬度提高到7.3,并将其吸水率降低到4.2;且当采用硅氧烷的后滴加方式时,可有效抑制乳液聚合过程中硅氧烷的水解和缩合反应。此外,借助扫描电镜和透射电镜分析聚合产物涂膜形态和共聚乳液的粒径及其分布,结果表明改性后的硅丙微乳液的粒径可控制在50~70 nm之间,C-1706的引入可有效提高微乳液的综合性能。 相似文献