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71.
72.
In-situ studies of electron field emission of single carbon nanotubes inside the TEM 总被引:1,自引:0,他引:1
Electron field emission characteristics of individual multi-walled carbon nanotubes (MWCNTs) were investigated in situ inside the transmission electron microscope (TEM). For a single MWCNT it was found that while field-emission can hardly occur from the side of the nanotube, a curved nanotube may result in finite side emission and the best emission geometry is the top emission geometry. Current-voltage (I-V) measurements made at different vacuum conditions and voltage sweeps emphasize the importance of the adsorbates on the electron field emission of MWCNTs. For a contaminated MWCNT, although the field emission current was reduced, the stability of its emission was improved. A current of up to several tens of μA was observed for a single MWCNT, but it was found that long time emission usually results in drastic structure damage that may lead to sudden emission failure. 相似文献
73.
Hyoung Jin Choi Yong Woo Inn Myung S. Jhon 《Korean Journal of Chemical Engineering》1994,11(3):145-152
Polymer migration is a generally well-known phenomenon in a flow field, and it has been verified that the sources of such
phenomena are nonhomogeneity of the flow, concentration effects and hydrodynamic interactions between the polymer molecules.
In addition, temperature effects were found to be another source of polymer migration. The Langevin equation for a polymer
molecule was first derived from single chain dynamics using a kinetic theory for the bead-spring elastic harmonic dumbbell
model, as described in part I (reference [1]). In this paper the diffusion equation and concentration profile of the polymer
molecules induced by a temperature gradient are obtained from the Fokker-Planck equation. A new differential operator is also
introduced to calculate the concentration profile. From the concentration equation obtained in the general flow geometry,
we find that in dilute polymer solution there are significant effects on the polymer migration not only due to the nonhomogeneity
of the flow field but also due to temperature gradients. 相似文献
74.
Mesoporous sulfated Al2O3–ZrO2 (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher
Al2O3 content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized
by X-ray diffraction (XRD), N2 adsorption, transmission electron microscopy (TEM), 27Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed
desorption of ammonia (NH3-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al2O3–ZrO2 samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that
on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed
reactions. 相似文献
75.
Summary An aromatic copolyester with the ordered sequence of terephthalic acid (TA)-p-hydroxybenzoic acid (HB)-2,7-naphthalenediol (ND)-p-hydroxybenzoic acid (HB) was prepared and its properties were compared with those of the corresponding random copolyester having the same overall monomer composition. Thermal and crystallizing properties of the two polymers are quite different. The former exhibits significantly higher glass transition and melting temperatures than the latter. The former's degree of crystallinity also is much higher than the latter's. Both polymers are thermotropic and form nematic melts. 相似文献
76.
模拟三相流化床中颗粒尺寸对单气泡传质系数的影响 总被引:1,自引:0,他引:1
本文在模拟三相流化床中,测量了单气泡的传质系数,实验结果表明颗粒直径对气-液传质系数影响显著。颗粒直径较大时,传质系数有明显提高。 相似文献
77.
锌基重防腐双涂层防护技术在高速公路护栏上的应用 总被引:1,自引:0,他引:1
介绍了双涂层防护技术的进展以及锌基重防腐双涂层防护技术在高速公路护栏上的应用。 相似文献
78.
功能性建筑涂料除了具备普通建筑涂料的装饰作用外,还能起到某种功能性作用。随着国民经济的快速发展,其应用也越来越普遍,可以预期,功能性建筑涂料的实用性,拓宽建筑涂料的应用范围。本文作者庚晋介绍了几种功能性建筑涂料的特点、主要用途、最新研究动态、施工方法、市场前景等。 相似文献
79.
Boron-based metal-free catalysts for oxidative dehydrogenation of propane (ODHP) have drawn great attention in both academia and industry due to their impressive activity and olefin selectivity. Herein, the SiO2 and B2O3 sequentially coated honeycomb cordierite catalyst is designed by a two-step wash-coat method with different B2O3 loadings (0.1%-10%) and calcination temperatures (600, 700, 800 ℃). SiO2 obtained by TEOS hydrolysis acts as a media layer to bridge the cordierite substrate and boron oxide via abundant Si-OH groups. The welldeveloped straight channels of honeycomb cordierite make it possible to carry out the reactor under high gas hourly space velocity (GHSV) and the thin wash-coated B2O3 layer can effectively facilitate the pore diffusion on the catalyst. The prepared B2O3/SiO2@HC monolithic catalyst exhibits good catalytic performance at low boron oxide loading and achieves excellent propylene selectivity (86.0%), olefin selectivity (97.6%, propylene and ethylene) and negligible CO2 (0.1%) at 16.9% propane conversion under high GHSV of 345,600 ml·(g B2O3)-1·h-1, leading to a high propylene space time yield of 15.7 g C3H6·(g B2O3)-1·h-1 by suppressing the overoxidation. The obtained results strongly indicate that the boron-based monolithic catalyst can be properly fabricated to warrant the high activity and high throughput with its high gas/surface ratio and straight channels. 相似文献
80.
Chlorinated isotactic polypropylenes (CPP) having various chlorine contents were blended with poly(ethylene-co-vinyl acetate)s (EVA) having various vinyl acetate (VA) contents. The blends were made by casting films from dilute THF solutions and miscibility of the blends was identified by single glass transition temperature, which was confirmed by DSC and dynamic mechanical measurements. Based on the miscibility data from a large number of CPP/EVA combinations, a miscibility map was depicted where CO equivalent weight (CO-EQW) of EVA was plotted against chlorine equivalent weight (Cl-EQW) of CPP. Though an attractive interaction between CPP and EVA could be detected in all the miscible and immiscible blend pairs, miscibility of the CPP/EVA blends could solely be observed in a relatively narrow range of Cl-EQW ca. 65–100 and CO-EQW ca. 170–230. 相似文献