Synthesis and characterization of novel,temperature‐sensitive microgels based on N‐isopropylacrylamide and tert‐butyl acrylate

A series of temperature‐sensitive microgels based on N‐isopropylacrylamide as the main monomer, tert‐butyl acrylate (tBA) as the comonomer, and N,N′‐methylene‐bis(acrylamide) as the crosslinker were synthesized with a modified surfactant‐free emulsion polymerization method. The chemical structure and global shape with an excellent monodispersity of the microgels were confirmed by Fourier transform infrared spectroscopy and scanning electron microscopy, respectively. The temperature‐sensitive behavior of the microgels was investigated by dynamic light scattering and ultraviolet–visible spectrophotometric analysis. The results show that the volume phase‐transition temperature of the poly(N‐isopropylacrylamide‐co‐tert‐butyl acrylate) [poly(NIPAM‐co‐tBA)] microgels were tuned over a broad range by the incorporated amount of tBA comonomer and their temperature sensitivity decreased with increasing content of tBA units incorporated into the microgel network. Furthermore, the swelling ratios of the poly (NIPAM‐co‐tBA) microgels were lowered gradually with increasing tBA unit content within the microgel network. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2962–2967, 2007     

浸没循环撞击流反应器制备牙膏用磷酸氢钙

采用浸没循环撞击流反应器（SCISR），以焦磷酸钠和磷酸三镁为稳定剂，以磷钙液和石灰乳为原料，通过中和反应法制备出了平均粒度10μm的牙膏用微细磷酸氢钙；探讨了反应温度、熟化时间、反应器装填系数、反应终点pH、磷钙液质量浓度等对产品质量的影响。确定了最优操作条件：磷钙液质量浓度1．17～1．19kg／m^3，反应温度42℃，熟化时间2h，反应终点pH6．3，反应器装填系数0．75。得到产品符合HG3257—2001标准。     

俄罗斯减压渣油超临界萃取残渣的催化加氢反应研究

以高压反应釜为反应器、环己烷为溶剂,选用分子筛、金属及舍金3大类共6种催化剂,对俄罗斯减压渣油超临界萃取所得残渣的非催化及催化加氢反应进行研究。结果表明,采用NKF-β型和Y型分子筛作为催化剂,残渣加氢反应产物中芳烃的相对含量超过55％;采用金属Fe、Ni以及合金Co—Fe、Pd—C作为催化剂,残渣加氢反应产物中正构烷烃的相对含量超过70％;除采用Fe和Pd—C作为催化剂的残渣加氢反应产物之外,在其他各组产物中均检测到少量含氧化合物,而在以NKF-β型分子筛作为催化剂的加氢反应产物中还检测出含氮化合物。针对各组加氢反应产物中化合物相对含量的差异,推测了残渣在不同类型催化剂作用下可能存在的反应途径。     

Full-scaled deep metric learning for pedestrian re-identification

Multimedia Tools and Applications - The pedestrian re-identification problem (i.e., re-id) is essential and pre-requisite in multi-camera video surveillance studies, provided the fact that...     

一种抵制对等性攻击的(p,θ)k-匿名模型

针对当前p-sensitive k-匿名模型未考虑敏感属性的敏感程度,不能抵制对等性攻击的问题,提出一种可抵制对等性攻击的(p,θ)k-匿名模型.同时引入互信息量来度量属性间的关联度,为准标识属性的进一步泛化提供依据.实验结果表明,所提的(p,θ)k-匿名模型相对于p-sensitive k-匿名模型降低了敏感属性泄露的概率,更能有效地保护个体隐私.     

Characteristics of cationic Red X-GRL adsorption by diatomite tailings

As secondary mineral resources, diatomite tailings(DT) got from the Linjiang region of China were prepared and characterized by SEM, XRF and XRD. Mono-factor experiments were carried out to investigate the effects of the operation factor, including contact time, adsorbent concentration, initial p H value of the dye solutions, adsorption temperature and initial concentration of cationic Red X-GRL(X-GRL) on the adsorption of X-GRL. The adsorption kinetics, isotherms, thermodynamics and mechanisms for X-GRL were also studied. It was efficient for DT to adsorb X-GRL from aqueous solutions, and it was even discovered to have higher adsorptivity for X-GRL than diatomite concentrate(DC) in our previous test. The adsorption processes fit very well with the pseudo-second-order model and the Langmuir isotherm equation. In addition, various thermodynamic parameters, such as standard Gibbs free energy(ΔG°), standard enthalpy(ΔH°) and standard entropy(ΔS°) have been calculated. From thermodynamic studies, it was seen that the adsorption was spontaneous and endothermic. The main driving forces of the physical adsorption on DT are electrostatic attraction. The reason why DT showed higher adsorptivity for X-GRL than DC was that there were more clay mineral particles within, which has a remarkable ability of dye adsorption due to its high surface area. DT as a cheap absorbent for X-GRL removal would replace or partially replace the activated carbon.     

基于机器学习的用户窃电行为预测

新型智能电表普及后,为了准确检测出电网中的窃电用户,可以结合机器学习的方法.为此,选择了支持向量机、随机森林和迭代决策树3种机器学习中较常用的大数据算法进行分析,通过不断调整试验数据集的大小,对3种算法的效率和准确率进行测试.对比分析结果发现,随机森林算法运行的时间和数据量的大小基本呈线性关系,效率较高,且准确率稳定在86%以上,表现较好.     

SM-30磁化率仪的工作原理探讨

SM-30磁化率仪具有仪器轻巧、使用方便、测定快捷等多项优点,因此在磁法勘探中具有广泛的应用。从SM-30的原理框图流程入手,简述了SM-30磁化率仪内部的各元件组成及其工作流程,并介绍了推断模式的操作流程,最后从电气部分推导了SM-30磁化率仪内部振荡器的频率变化与外部待测物体磁化率间的线性关系,揭示了SM-30磁化率仪的工作原理,让广大地质工作者能够更好地掌握及使用SM-30磁化率仪。     

北京市停车场影响范围研究

为了解决北京市的停车位紧缺、停车拥堵问题,对停车场的影响范围进行了定量研究. 首先,基于驾驶员停车行为的调查,通过非参数检验,分析驾驶员性别、出行目的、停车引导类型、停车收费因素与步行距离的关系,确定停车场影响范围的影响因素及实际影响范围;然后,运用停车场分布密度和泰森多边形,确定了停车场的最小影响范围;最后,综合考虑实际影响范围和最小影响范围,结合北京市棋盘形路网的特性,进行影响范围的修正,得出停车场的合理影响范围.     

基于Legendre多项式展开的双基SAR二维频域成像算法

针对任意构型双基SAR基于传统Taylor级数展开斜距方法的边缘点散焦问题,提出了一种基于Legendre正交多项式逼近的双基SAR二维频域成像算法。该算法基于对斜距函数的Legendre多项式展开推导了点目标二维频谱,解除了回波信号距离—方位的耦合,使成像处理更高效。在二维频域对场景区域的点目标采用二维频域成像算法进行成像。该算法改善了场景边缘点的聚焦效果,增加了场景边缘点的聚焦深度。理论推导和仿真结果验证了该算法的有效性和可行性。