High temperature melt viscosity and fragile to strong transition in Zr–Cu–Ni–Al–Nb(Ti) and Cu47Ti34Zr11Ni8 bulk metallic glasses

The molten viscous behavior of Vitreloy 106, 106a, 105 and 101 bulk metallic glass-forming alloys was investigated at temperatures above T_liq. Couette concentric cylinder viscometry was used to determine the isothermal and continuous cooling melt viscosities. Isothermal three point beam bending measurements of the viscosity in the vicinity of T_g revealed a kinetically stronger liquid at low temperatures than at high temperatures, near T_liq. This behavior is revealed to be the result of a fragile to strong transition in the undercooled liquid, possibly due to polyamorphism.     

Study of TATP: Influence of Reaction Conditions on Product Composition

The influence of reaction conditions (temperature, catalyst type, catalyst concentration – represented as molar ratio catalyst/acetone n_c/n_a) on the composition of the product formed from the reaction of acetone and hydrogen peroxide (30%) under acid catalysis was studied. 3,3,6,6,9,9‐Hexamethyl‐1,2,4,5,7,8‐hexoxonane (TATP) was found to be the major product when the content of the catalyst in the reaction mixture is low (n_c/n_a ≤ 0.5). A single side product (peak 10.2) in an amount ranging from 1.5 to 8% of the total peak area was present in all the prepared samples. Three other side products were found when catalyzing by hydrochloric and nitric acids. Temperature and catalyst type did not have a significant influence on the composition of the product at low catalyst concentration. Increasing the catalyst concentration led to the formation of 3,3,6,6‐tetramethyl‐1,2,4,5‐tetroxane (DADP) either as a co‐product of TATP or as an exclusive product depending on the concentration of the catalyst.     

Two-Dimensional Modeling of Self-Propagating High-Temperature Synthesis of Strontium-Doped Lanthanum Manganate

A two-dimensional finite element model is developed to study the reaction kinetics and heat transfer during the self-propagating high-temperature synthesis of La_0.6Sr_0.4MnO₃, a cathode and interconnect material used in solid oxide fuel cells. The activation energy of La_0.6Sr_0.4MnO₃ formation was calculated from experimental temperature history. The calculated spatial-temporal temperature profile, heat generation rate, reaction conversion, and flow pattern of surrounding gas during the reaction are reported in this work. Hot spots are found at the corner near the ignition point shortly after the ignition. The model provided a simple and reliable way to design a large-scale production of La_0.6Sr_0.4MnO₃.     

Colorimetric method for phase evaluation

Measurements of very small phase changes in optical measurement techniques are usually performed with interferometric methods that are based on evaluation of interference patterns, which correspond to a phase change of the investigated wave field. If values of the phase change are small, it is difficult to determine accurately the phase values, and one needs very expensive measurement systems. We present a simple method for evaluation of small phase variations that uses the interference of polychromatic light. The phase change affects the color of the interference pattern, and the color of the interference pattern corresponds to a specific phase change that can be evaluated using colorimetric analysis. We describe and analyze our colorimetric phase evaluation method. The proposed method offers accurate results, and it may be suitable for practical utilization in the optical industry.     

Contour superresolved imaging of static ground targets using satellite platform

We propose a method for increasing the contour resolution of static ground targets and to overcome the diffraction limit of an optical system installed on top of a satellite. The resolution improvement is obtained by using a sequence of low-resolution images taken from different angles realized by the movement of the satellite platform. The superresolving process is obtained by the generation of relative movement between the inspected object and the a priori known high-resolution background. The relative movement is caused because the images are taken from different angles. The captured set of low-resolution images are decoded by the a priori known high-resolution background obtained from a set of reference images taken only once by a high-resolution camera. The proposed concept is demonstrated via Matlab simulation and laboratory experiments.     

Dependence of Strehl ratio on f-number of optical system

Formulas for a minimum of wave aberration variance and a maximum of the Strehl ratio in the optimal image point are derived using the third- and fifth-order aberration theory. Moreover, relations for the calculation of the optimal value of f-number of the optical system were derived, which enabled us to theoretically analyze real optical systems and their image quality. The optimal f-number corresponds to such a value of f-number when the image quality of a real optical system is comparable to an aberration-free optical system. This value may also serve as an auxiliary criterion of the image quality of the optical system, for example, in photography.     

An 11-bit successive approximation analog-to-digital converter based on a combined capacitor-resistor network

Within this work an 11-bit integrated Successive Approximation Register (SAR) Analog-to-Digital Converter (ADC) based on a combined capacitor and resistor network is presented. Utilizing this approach, the chip area is reduced by the factor of 2⁴ compared to conventional solutions without any interpolation and it occupies only 0.3 mm². Furthermore, the equivalent capacitance is decreased by connecting two capacitors in series, whereby the matching and the power consumption are improved. The measured Differential Non-Linearity (DNL) and the Integral Non-Linearity (INL) are below 0.3 and 0.5 LSBs, respectively. The calculated Effective Number Of Bits (ENOB) accounts to 10.72 bits. The chip is produced in 0.6 μm CMOS technology.     

Investigation of Protein Composition of Barley by Gel Electrophoresis and MALDI Mass Spectrometry with Regard to the Malting and Brewing Process

The protein composition of barley partly determines its quality in terms of malting and brewing. For this reason, the water‐soluble proteins of two different barley cultivars were investigated by gel electrophoresis and matrix‐assisted laser desorption/ionization mass spectrometry. Mass spectra were obtained directly from barley extracts by using three matrices. According to the quality of the measured spectra, it was possible to establish which matrix was the most suitable for the analysis of water‐soluble proteins from barley. We found that the protein patterns did not differ significantly between Jersey and Tolar varieties. However, our results showed the influence of the malting process on the posttranslational modification of some water‐soluble barley proteins. These proteins also survive the brewing process and they are very important for the formation and stability of beer foam. Several barley proteins were also identified by proteomic analysis.     

制鞋工业中用于抑菌处理的甘油一酸酯(续)

3 RESULTS AND DISCUSSION 3.1 Testing the MAG antimycotic effectivity by micro titration method This method was used only for the yeasts Candida albicans and Candida parapsilosis.