Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica,fumed silica and aluminosilicate materials

The presented report focuses on the testing of heterogenized methyltrioxorhenium (MTO) in indene epoxidation. A range of mesoporous materials with different SiO₂/Al₂O₃ ratios, namely aluminosilicates type Siral and MCM-41 silica and fumed silica, were used as supports for immobilization of MTO. The tested support materials and prepared catalytic systems exhibited high surface area, well-defined regular structure and narrow pore size distribution of mesopores and therefore represent good quality catalysts for various reactions. The immobilized MTO on various supports was tested for the preparation of 1,2-epoxyindane using two forms of hydrogen peroxide as oxidation agents, namely aqueous solution of hydrogen peroxide and its anhydrous form, urea-hydrogen peroxide. The prepared catalysts were successfully used for the preparation of 1,2-epoxyindane with achieved 100 % selectivities to the desired product at high conversions of indene.     

3GPP LTE‐Assisted Wi‐Fi‐Direct: Trial Implementation of Live D2D Technology

This paper is a first‐hand summary on our comprehensive live trial of cellular‐assisted device‐to‐device (D2D) communications currently being ratified by the standards community for next‐generation mobile broadband networks. In our test implementation, we employ a full‐featured 3GPP LTE network deployment and augment it with all necessary support to provide real‐time D2D connectivity over emerging Wi‐Fi‐Direct (WFD) technology. As a result, our LTE‐assisted WFD D2D system enjoys the required flexibility while meeting the existing standards in every feasible detail. Further, this paper provides an account on the extensive measurement campaign conducted with our implementation. The resulting real‐world measurements from this campaign quantify the numerical effects of D2D functionality on the resultant system performance. Consequently, they shed light on the general applicability of LTE‐assisted WFD solutions and associated operational ranges.     

Direct three-phase single-stage flyback-type power factor corrector

Based on the work of Hui and Chung (see ibid., vol. 33, no. 15, p.1274-76, 1997) a three-phase converter system consisting of three single-phase flyback-type AC/DC converter modules in star-connection is proposed and investigated     

A novel multicell DC-AC converter for applications in renewable energy systems

This paper presents a novel DC-AC converter for applications in the area of distributed energy generation systems, e.g., solar power systems, fuel-cell power systems in combination with supercapacitor or battery energy storage. The proposed converter is realized using an isolated multicell topology where the total AC output of the system is formed by series connection of several full-bridge converter stages. The DC links of the full bridges are supplied by individual DC-DC isolation stages which are arranged in parallel concerning the dc input of the. total system. Therefore, all switching cells of the proposed converter can be equipped with modern low-voltage high-current power MOSFETs, which results in an improved efficiency as compared to conventional isolated DC-AC converters. Furthermore, the cells are operated in an interleaved pulsewidth-modulation mode which, in connection with the low voltage level of each cell, significantly reduces the filtering effort on the AC output of the overall system. The paper describes the operating principle, analyzes the fundamental relationships which are relevant for component selection, and presents a specific circuit design. Finally, measurements taken from a 2-kW laboratory model are presented.     

Bestimmung des Grenzumformgrades mit dem Torsionsversuch

Die Bestimmung des Grenzumformgrades eines Stahles, der während der plastischen Verformung nicht überschritten werden kann, ist von großer Bedeutung. Die vorliegende Arbeit berichtet über Ergebnisse von Warmtorsionsversuchen, aus denen der Grenzumformgrad als Funktion von Temperatur und Umformgeschwindigkeit ermittelt wurde. Die Versuche wurden an den Stählen X 10 CrNiTi 18 9, 10 CrMo 9 10, X 10 CrNiMoTi 18 12, X 20 CrMoV 12 1 und X 2 NiCrNb 25 18 durchgeführt.     

Case Study: Refinement of Hydraulic Operation of a Complex CSO Storage/Treatment Facility by Numerical and Physical Modeling

The performance of a combined sewer overflow (CSO) storage/treatment facility in North Toronto, Ont., Canada, was investigated by conjunctive numerical and physical (hydraulic) modeling. The main objectives of the study were to (1) assess the feasibility of increasing the hydraulic loading of the CSO facility without bypassing; and (2) establish a verified numerical model of the facility for future work. The numerical model [a commercial computational fluid dynamics (CFD), PHOENICS] was validated and verified using results from a hydraulic scale model (1:11.6). The results obtained show that the CFD model can simulate hydraulic conditions in the facility well, as demonstrated by accurate reproduction of the filling rate, water levels at various locations, flow velocities in feed pipes, and overflows from the inflow channel. Numerical simulations identified excessive local head losses and helped select structural changes to reduce such losses. The analysis of the facility showed that with respect to hydraulic operation, the facility is a complex, highly nonlinear hydraulic system. Within the existing constraints, a few structural changes examined by numerical simulation could increase the maximum treatment flow rate in the CSO storage/treatment facility by up to 31%.     

Throughput bounds for closed queueing networks

Analytical lower and upper bounds for the throughput of closed queueing networks with single and delay (infinite) servers are studied in this paper. The numerical evaluation of these bounds requires a small number of significant operations which is independent of the population N. This is in contrast to the exact computation of the throughput which requires at least O(N) operations as N tends to infinity. The bounds are given by simple closed-form analytical expressions and may be more suitable for various performance studies than the algorithmical form of the exact solution.In this paper, the previously known balanced-job bounds are generalized to networks containing delay servers (terminals) and a hierarchy of bounds is obtained for single and multiple class networks. For the single class network, further new bounds are derived: lower and upper bounds that require the evaluation of one square root and an upper bound that requires a constant number of exponentiations. This upper bound does not employ the balancing of server loadings and is especially useful for asymptotic analysis in the case of a large number of customers N.     

Transmission parameters of a class of coupled distributed networks

It is shown how the equations of a class of coupled distributed networks can be decoupled, and their transmission parameters expressed in terms of those of an equivalent scalar system.     

Dietary sitostanol and campestanol: Accumulation in the blood of humans with sitosterolemia and xanthomatosis and in rat tissues

Dietary sitostanol has a hypocholesterolemic effect because it decreases the absorption of cholesterol. However, its effects on the sitostanol concentrations in the blood and tissues are relatively unknown, especially in patients with sitosterolemia and xanthomatosis. These patients hyperabsorb all sterols and fail to excrete ingested sitosterol and other plant sterols as normal people do. The goal of the present study was to examine the absorbability of dietary sitostanol in humans and animals and its potential long-term effect. Two patients with sitosterolemia were fed the margarine Benecol (McNeill Nutritionals, Ft. Washington, PA), which is enriched in sitostanol and campestanol, for 7–18 wk. Their plasma cholesterol levels decreased from 180 to 167 mg/dL and 153 to 113 mg/dL, respectively. Campesterol and sitosterol also decreased. However, their plasma sitostanol levels increased from 1.6 to 10.1 mg/dL and from 2.8 to 7.9 mg/dL, respectively. Plasma campestanol also increased. After Benecol withdrawal, the decline in plasma of both sitostanol and campestanol was very sluggish. In an animal study, two groups of rats were fed high-cholesterol diets with and without sitostanol for 4 wk. As expected, plasma and liver cholesterol levels decreased 18 and 53%, respectively. The sitostanol in plasma increased fourfold, and sitostanol increased threefold in skeletal muscle and twofold in heart muscle. Campestanol also increased significantly in both plasma and tissues. Our data indicate that dietary sitostanol and campestanol are absorbed by patients with sitosterolemia and xanthomatosis and also by rats. The absorbed plant stanols were deposited in rat tissues. Once absorbed by sitosterolemic patients, the prolonged retention of sitostanol and campestanol in plasma might increase their atherogenic potential.     

Optical Under-Sampling and Reconstruction of Several Bandwidth-Limited Signals

We demonstrate experimentally an optical system for under-sampling several bandwidth-limited signals with carrier frequencies that are not known apriori and can be located anywhere within a very broad frequency region between 0-18 GHz. The system is based on under-sampling asynchronously at three different sampling rates. The optical pulses required for the under-sampling are generated by a combination of an electrical comb generator and an electro-absorption optical modulator. To reduce loss and improve performance the implementation of the optical system is based on a wavelength division multiplexing technique. An accurate reconstruction of both the phase and the amplitude was obtained when two chirped signals each with a bandwidth of about 150 MHz were sampled.