首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2402篇
  免费   183篇
  国内免费   5篇
电工技术   22篇
综合类   2篇
化学工业   593篇
金属工艺   124篇
机械仪表   160篇
建筑科学   40篇
能源动力   139篇
轻工业   211篇
水利工程   21篇
石油天然气   5篇
武器工业   2篇
无线电   349篇
一般工业技术   482篇
冶金工业   112篇
原子能技术   54篇
自动化技术   274篇
  2024年   3篇
  2023年   29篇
  2022年   42篇
  2021年   97篇
  2020年   60篇
  2019年   62篇
  2018年   84篇
  2017年   81篇
  2016年   84篇
  2015年   80篇
  2014年   117篇
  2013年   163篇
  2012年   215篇
  2011年   248篇
  2010年   158篇
  2009年   180篇
  2008年   127篇
  2007年   88篇
  2006年   96篇
  2005年   85篇
  2004年   68篇
  2003年   58篇
  2002年   48篇
  2001年   52篇
  2000年   53篇
  1999年   42篇
  1998年   65篇
  1997年   25篇
  1996年   14篇
  1995年   12篇
  1994年   15篇
  1993年   11篇
  1992年   3篇
  1991年   6篇
  1990年   2篇
  1989年   4篇
  1988年   4篇
  1987年   2篇
  1986年   1篇
  1985年   3篇
  1984年   1篇
  1978年   1篇
  1976年   1篇
排序方式: 共有2590条查询结果,搜索用时 359 毫秒
151.
The notion of a BCK-valued function on a set is introduced, and related properties are investigated. Codes generated by BCK-valued functions are established.  相似文献   
152.
Cyclic voltammetry (CV), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) were employed to investigate the electrodeposition of Eu and Al in an LiCl-KCl eutectic melt containing Eu2+ and Al3+ at 450 °C. In order to deposit a pure Eu and Al alloy, the stoichiometrically lower concentration of Al3+ than that of Eu2+ and Al wires as a counter electrode was introduced into the bath of LiCl-KCl melt for the electrodeposition. The electrodeposition takes place at a potential more negative than −1.95 V vs. Ag|Ag+ while the deposit is oxidized at more positive potential than −1.92 V. Two new reduction peaks and an anodic peak on a W working electrode were observed at −2.39 V, −2.42 V, and −2.1 V, vs. Ag|Ag+, respectively, suggesting that the potential window of the Al system in LiCl-KCl melt can be extended to −2.43 V vs. Ag|Ag+. The EDS analysis indicated that AlEu can be deposited at the potential more negative than −2.37 V.  相似文献   
153.
A glucose sensor electrode was prepared by thermally treating a pitch-based carbon material. Oxyfluorination was used to modify the surface of the prepared carbon to induce the formation of hydrophilic functional groups. A glucose oxidase enzyme was effectively loaded onto the surface of the oxyfluorinated carbon and was more sensitive in glucose sensing because of the effects of the improved interfacial affinity between the electrode and the glucose oxidase. The introduced hydrophilic functional groups were examined using XPS analysis. In current–voltage measurements, a higher current was observed in the samples prepared with a higher oxygen content. In addition, a clear redox peak was observed in the surface modified samples. These results can be attributed to efficient electrical resistance measurement by easy electron transfer during glucose sensing. An efficient glucose sensor electrode was prepared using pitch-based carbon, which has beneficial electrical properties, and oxyfluorination, which improves the surface interface.  相似文献   
154.
The concept of “waste-to-wealth” is spreading awareness to prevent global warming and recycle the restrictive resources. To contribute towards sustainable development, hydrogen energy is obtained from syngas (CO and H2) generated from waste gasification, followed by CO oxidation and CO2 removal. In H2 generation, it is key to produce more purified H2 from syngas using heterogeneous catalysts. In this respect, we prepared Pt/Al2O3 catalyst with nanoporous structure using precipitation method, and compared its catalytic activity with commercial alumina (Degussa). Based on the results of XRD and TEM, it was found that metal particles did not aggregate on the alumina surface and showed high dispersion. Optimum condition for CO conversion was 1.5 wt% Pt loaded on Al2O3 support, and pure hydrogen was obtained after removal of CO2 gas.  相似文献   
155.
In this study, the performance improvement of the SOFC single cell and its underlying mechanism was investigated. Furthermore, an application of the identified electrochemical mechanism is proposed and tested experimentally. The deposition of Platinum (Pt) at electrochemically active sites for the oxygen reduction reaction is determined to be responsible for the improved performance. Pt migration from a current collector to the cathode active sites originates from the oxygen partial pressure difference between current collector and triple phase boundary, and the electrochemical reduction reaction. It is supported by the confirmation of Pt particles at the cathode active sites by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and calculations of the thermodynamic equilibrium partial pressure values. In addition, correlation of the initial performance change and the quantities of Pt deposition are investigated. This selective Pt deposition mechanism at the active sites is applied to the LSCF cathode, as well.  相似文献   
156.
The corrosion behaviour and change of the phase fraction in welded 24Cr Duplex stainless steel was investigated for different chemical composition ranges of Mo contents. Filler metal was produced by fixing the contents of Cr, Ni, N, and Mn while adjusting the Mo content to 0.5, 1.4, 2.5, 3.5 wt%. The δ-ferrite fraction was observed to increase as the content of Mo increased. A polarisation test conducted in a salt solution, indicated the pitting corrosion potential increased continuously to 3.5 wt% Mo, while the corrosion potential changed most between 0.5 and 1.41 wt% Mo. The location of the pitting corrosion in 0.5 wt% Mo steel was randomly distributed, but it occurred selectively at the grain boundary between the γ- and δ-ferrite phases in 1.4, 2.5 and 3.5 wt% Mo steel. Energy dispersive X-ray spectroscopy mapping analysis showed that areas deficient in Cr, Mo, and Ni occurred around the grain boundary of the γ- and δ-ferrite phases. Non-metallic inclusions are thought to act as initiation points for the pitting corrosion that occurs in the salt solution initially as a result of the potential difference between the matrix structure and the incoherent inclusions.  相似文献   
157.
158.
While the way we build software affects significantly its maintenance in terms of the effort and cost, the experience level of the maintainer in a software acquirers' organization is also one of concern. In this context, often the maintainer is the user of the system. Unfortunately, it is quite possible to lose the trustworthiness of the software due to the inexperience of the maintainer, especially when the maintainer is without the help of the original developers. One remedy for providing security against the effects of the maintainer's software modifications is to restrict the access to software parts (modules) relative to the experience level of the maintainers. For such a remedy to be successful, the software should be constructed in such a way that its parts under maintenance affect others as little as possible. We propose an approach to software construction aligning the dependencies among software parts in one direction so that they are allocated to maintainers based on their experience level. Our approach decomposes the software into parts based on functionality and orders the parts by essentiality, which indicates how difficult it is to change each part. Then, we align the dependencies in such a way that the less essential functionality is dependent on the more essential functionality. Consequently, any modification on less essential functionality does not affect the essential functionalities. To demonstrate the feasibility of our proposed approach, we applied it to a military application and found that the constructed software enables us to confine maintainers' activity within a limited working area, and thus the software is safer against maintainers' modification. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
159.
In this paper, we introduce a mathematical model to analyze pricing and service quality strategies for e-business companies providing information services to customers. The basic strategy considered in this paper is that a monopolistic e-business company provides free services to try to earn a profit by developing premium goods or services to market created by their free goods or services. It is a kind of versioning strategy where lower quality versions of information goods are provided free. And a direct network effect was also considered. And we tried to find the profit maximizing strategies for monopolistic e-business companies. As a result, the optimal quality and price for the premium goods or services can be obtained at the same level of the intensity of the direct network effect. And the exact term related with the network externality is derived and insights are demonstrated through numerical explorations.  相似文献   
160.
We have performed high-dose Fe ion implantation into Si and characterized ion-beam-induced microstructures as well as annealing-induced ones using transmission electron microscopy (TEM) and grazing-incidence X-ray diffraction (GIXRD). Single crystals of Si(1 0 0) substrate were irradiated at 623 K with 120 keV Fe+ ions to a fluence of 4 × 1017 cm−2. The irradiated samples were then annealed in a vacuum furnace at temperatures ranging from 773 K to 1073 K. Cross-sectional TEM observations and GIXRD measurements revealed that a layered structure is formed in the as-implanted specimen with ε-FeSi, β-FeSi2 and damaged Si, as component layers. A continuous β-FeSi2 layer was formed on the topmost layer of the Si substrate after thermal annealing.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号