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991.
We report microstructure and mechanical properties of bulk metallic glass (BMG)/metallic glass composites fabricated by mechanical alloying with subsequent consolidation process. The microstructural investigations of a bulk composite reveal that a submicron-scale layered structure with irregular interfaces consists of three amorphous phases in tornado-like morphology. Based on these results, poor plasticity of the metallic glass composite can be understood possibly due to the irregular interfacial morphology of the submicron-scale heterogeneous amorphous phases throughout the materials. 相似文献
992.
Juhyun Kang Kunho Lee Jae Young Yoo Joongmyeon Bae 《International Journal of Hydrogen Energy》2018,43(12):6400-6405
An electroless plating process of nickel is introduced to solve the drawbacks of impregnation for developing the multiscale anode of a solid oxide fuel cell (SOFC). Impregnation is the conventional fabrication method of the electrode. The process is not favorable for depositing nanoscale metal catalysts due to severe problems including agglomeration of the catalysts while reducing metal oxides. Thus, as an alternative, we propose electroless plating of nickel to fabricate a multiscale nickel-based SOFC anode. A Ni-LSGM (La0.8Sr0.2Ga0.8Mg0.2O3-σ) anode is selected. The low chemical compatibility of LSGM with nickel emphasizes the advantage of the electroless plating process. First, nanoscale nickel particles are successfully applied as the main catalyst of the SOFC anode by plating nickel to the surface of the LSGM scaffold substrate near the triple phase boundary region. Thin film X-ray diffraction and image analysis confirm that pure nanoscale nickel particles form on the entire substrate, even at a low temperature (60 °C) without secondary phase formation. Electrochemical impedance spectroscopy analysis is then performed to verify the possibility of implementing an efficient Ni-LSGM anode through nickel electroless plating. As a result, the new Ni-LSGM anode shows ~50 times higher electrochemical performance than that of an impregnated Ni-LSGM anode. 相似文献
993.
In this study, a Gd0.1Ce0.9O1.95 (GDC) buffer layer and a Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) cathode, fabricated without pre-sintering, are investigated (unsintered GDC and unsintered BSCF). The effect of the unsintered GDC buffer layer, including the thickness of the layer, on the performance of solid oxide fuel cells (SOFCs) using an unsintered BSCF cathode is studied. The maximum power density of the metal-supported SOFC using an unsintered BSCF cathode without a buffer layer is 0.81 W cm−2, which is measured after 2 h of operation (97% H2 and 3% H2O at the anode and ambient air at the cathode), and it significantly decreases to 0.63 W cm−2 after 50 h. At a relatively low temperature of 800 °C, SrZrO3 and BaZrO3, arising from interaction between BSCF and yttria-stabilized zirconia (YSZ), are detected after 50 h. Introducing a GDC interlayer between the cathode and electrolyte significantly increases the durability of the cell performance, supporting over 1000 h of cell usage with an unsintered GDC buffer layer. Comparable performance is obtained from the anode-supported cell when using an unsintered BSCF cathode with an unsintered GDC buffer layer (0.75 W cm−2) and sintered GDC buffer layer (0.82 W cm−2). When a sintered BSCF cathode is used, however, the performance increases to 1.23 W cm−2. The adhesion between the BSCF cathode and the cell can be enhanced by an unsintered GDC buffer layer, but an increase in the layer thickness (1-6 μm) increases the area specific resistance (ASR) of the cell, and the overly thick buffer layer causes delamination of the BSCF cathode. Finally, the maximum power densities of the metal-supported SOFC using an unsintered BSCF cathode and unsintered GDC buffer layer are 0.78, 0.64, 0.45 and 0.31 W cm−2 at 850, 800, 750 and 700 °C, respectively. 相似文献
994.
Kyoung-Soo Kang Chang-Hee Kim Ki-Kwang Bae Won-Chul Cho Sung-Hyun Kim Chu-Sik Park 《International Journal of Hydrogen Energy》2010
The three-reactor chemical-looping process (TRCL) for the production of hydrogen from natural gas is quite attractive for both CO2 capture and hydrogen production. The TRCL process consists of a fuel reactor, a steam reactor and an air reactor. In the fuel reactor, natural gas is oxidized to CO2 and H2O by the lattice oxygen of the oxygen carrier. In the steam reactor, the steam is reduced to hydrogen through oxidation of the reduced oxygen carrier. In the air reactor, the oxygen carrier is fully oxidized by air. In this process, the oxygen carrier is recirculated among the three reactors, which avoids direct contact between fuel, steam and air. In this study, various candidate materials were proposed for the oxygen carrier and support, and a thermal analysis of the process was performed. The oxygen carrier for the process must have the ability to split water into hydrogen in its reduced state, which is a different chemical property from that of the chemical-looping combustion medium. The selection of the oxygen carrier and support require careful consideration of their physical and chemical properties. Fe2O3, WO3 and CeO2 were selected as oxygen carriers. Thermal analysis indicated an expected hydrogen production of 2.64 mol H2 per mol CH4 under thermoneutral process conditions. The results indicated that hydrogen production was affected mainly by the steam-conversion rate. The solid-circulation rate and temperature drop in the fuel reactor were calculated for the selected oxygen carriers with different metal oxide contents and solid-conversion rates. 相似文献
995.
Alkali-earth metaniobate compounds, ANb2O6 (A = Ca, Sr, Ba), were prepared by the conventional solid-state reaction route and their electronic band structures and photocatalytic activities were investigated. The prepared powders were characterized using X-ray diffraction (XRD), field-emission electron microscopy (FE-SEM), UV–vis diffuse reflectance spectroscopy, and fluorescence spectroscopy. It was found that the particle sizes (∼1 μm) and BET surface areas (∼1 m2/g) of the metaniobate compounds were nearly identical. From the electronic band structure calculations, however, the band-gap energies of these metaniobate compounds were found to be in the order of CaNb2O6 > SrNb2O6 > BaNb2O6. These calculated band-gap energies were consistent with those estimated from the UV–vis diffuse reflectance spectra. Moreover, the conduction-band edge (reduction potential) of SrNb2O6 calculated from the electronegativity data was higher than those of CaNb2O6 and BaNb2O6. The photoluminescence spectra revealed that CaNb2O6 exhibited a strong blue luminescence emission (at 300K), while no obvious emissions were observed in either SrNb2O6 or BaNb2O6. The luminescence behaviors of these metaniobate compounds and their band structure variations originating from their crystal structures play an important role in their photocatalytic activity for the evolution of H2 from pure water. SrNb2O6, which has a higher conduction-band edge potential than the other compounds, exhibited higher photocatalytic activity. 相似文献
996.
This study aims to examine the effect of particle size on the microstructure and corresponding properties in kinetic sprayed coatings of commercially pure nickel (CP-Ni) in conjunction with finite element modeling (FEM). Prior to the experiments, the adhesion factors (interface temperature, contact time and contact area), rebound factor (relative recovery energy) and the resultant critical velocities of CP-Ni for different particle sizes and temperatures were estimated by FEM. Based on the simulations, three different sized CP-Ni powders were successfully deposited onto mild steel substrates using a powder preheating system. Here we suggest optimized windows of operation for particle sizes of CP-Ni based on the microstructure and properties of the coatings (i.e. deposition efficiency, bond strength and micro-hardness) which are in good correspondence with the simulation results. 相似文献
997.
In the area of heavy construction, welding processes are vital in the production and maintenance of pipelines and power plants.
The fusion welding process generates formidable welding residual stresses and metallurgical change, which increase the crack
driving force and reduce the resistance of brittle fracture as well as environmental fracture. This is a serious problem with
many alloys as well as A106 Gr B steel pipe. This pipe, used in petrochemical and heavy chemical plants, either degrades due
to corrosive environments, e.g., chlorides and sulfides, and/or becomes damaged during service due to the various corrosion
damage mechanisms. Thus, in this study, the sulfide corrosion fatigue strength of multi-pass welded A106 Gr B steel pipe was
evaluated in a 5.0 wt.% NaCl solution that was saturated with H2S gas at room temperature on the basis of NACE TM 0177-90.
The crack growth characteristics of the welded pipe were then assessed at the low limit of sulfide corrosion fatigue strength,
which was previously obtained from the sulfide corrosion fatigue (SCF) tests. From the results, in terms of the SCF, all the
specimens failed at the heat-affected zone, where a high welding residual stress distributes. It was found that the fatigue
crack grew at the low corrosion fatigue limit (σ
SCFun-notched), which was 32 % (160MPa) of the ultimate tensile strength (502MPa) of the welded specimens. 相似文献
998.
Chlorine dioxide is potentially a powerful oxidant with environmentally compatible application in several strategic areas relating to pollution control typically for water disinfection, and its sustained production is a key factor for its successful application. Although increased attention has been paid for on-line chlorine dioxide generation by several chemical and electrochemical methods, the details are mostly confined as patents. We studied in this work the electrochemical generation of chlorine dioxide from an un-buffered solution of sodium chlorite and sodium chloride mixture in an un-divided electrochemical cell under constant current mode, with a view to optimize various process parameters, which have a direct bearing on the chlorine dioxide formation efficiency under laboratory conditions. The effect of feed flow rate (10-150 ml min(-1)), feed solution pH (2.3-5.0), concentration of sodium chloride (0-169.4mM), concentration of sodium chlorite (0-7.7 mM), and the applied current (100-1200 mA) on the formation of dissolved ClO(2) gas in solution and the pH of the product-containing solution was investigated by performing single pass experiments, with no circulation, in a cell set-up with Ti/IrO(2) anode and Ti/Pt cathode. The current efficiency and the power consumption were calculated for the optimized conditions. 相似文献
999.
In this study, immobilized TiO(2) electrode is applied to reduce toxic Cr(VI) to non-toxic Cr(III) in aqueous solution under UV irradiation. To overcome the limitation of powder TiO(2), a novel technique of immobilization based on anodization was applied and investigated under various experimental conditions. The anodization was performed at 20V-5 degrees C for 45min with 0.5% hydrofluoric acid, and then the anodized samples were annealed under oxygen stream in the range 450-850 degrees C. Based on the results of the experiments, the photocatalytic Cr(VI) reduction was favorable in acidic conditions, with approximately 98% of the Cr(VI) being reduced within 2h at pH 3. Among the samples tested under same anodizing condition, the nanotubular TiO(2) annealed at 450 and 550 degrees C showed highest reduction efficiencies of Cr(VI). In addition, the surface characterizations (zeta potential, XRD, and SEM) of these samples proved that the Cr(VI) reduction efficiency was higher under acidic conditions and at a lower annealing temperature. From this research, it was concluded that the anodized TiO(2) has the potential to be a useful technology for environmental remediation as well as photocatalytic hydrogen production from water. 相似文献
1000.
Jin-Seok Oh Jun-Ho Kwak Soo-Young Bae Ji-Yeoung Lee Toshimitsu Komatsu 《Journal of Mechanical Science and Technology》2009,23(6):1571-1575
Floating devices, such as a cavity resonance device, take advantage of both the water motion and the wave induced motions
of the floating body itself. In the design of a wave energy converter (WEC), the most significant factor is that an optimum
length of the internal water column should exists, that is, a length in which maximum power is converted near the heaving
resonance. A theoretical analysis of this power generated by a pneumatic-type WEC is performed, and the results obtained from
the analysis are used for a real WEC for a buoy. The length of the internal water column corresponds to that of the water
mass in the water column. If designed properly, a WEC can take advantage not only of the cavity resonance but also of the
heaving motion of the buoy. This paper presents the test results of the generation characteristic of a WEC and the harmful
effect of fouling in the internal water column. The results are then applied to the design of a WEC for a buoy.
This paper was recommended for publication in revised form by Associate Editor Jae Young Lee
Jin-Seok Oh was born in Kyung-Nam, Korea. He received the B. E. degree in Marine Engineering from Korea Maritime University in 1983.
Since 1983, he has been with the Zodiac (England Company) including early 4 years of System Engineer. He received the M.E.
and Ph. D. degrees from Korea Maritime University, Busan, Korea in 1989 and 1996, respectively. He had been with the Agency
for Defense Development (ADD) as a researcher from 1989 to 1992. In 1996, he joined the Division of Mechatronics Engineering
at Korea Maritime University. His research interests include electrical drive systems, robot control and PC-based Control
applications. 相似文献