Atomistic Origin of the Enhanced Crystallization Speed and n‐Type Conductivity in Bi‐doped Ge‐Sb‐Te Phase‐Change Materials

Phase‐change alloys are the functional materials at the heart of an emerging digital‐storage technology. The GeTe‐Sb₂Te₃ pseudo‐binary systems, in particular the composition Ge₂Sb₂Te₅ (GST), are one of a handful of materials which meet the unique requirements of a stable amorphous phase, rapid amorphous‐to‐crystalline phase transition, and significant contrasts in optical and electrical properties between material states. The properties of GST can be optimized by doping with p‐block elements, of which Bi has interesting effects on the crystallization kinetics and electrical properties. A comprehensive simulational study of Bi‐doped GST is carried out, looking at trends in behavior and properties as a function of dopant concentration. The results reveal how Bi integrates into the host matrix, and provide insight into its enhancement of the crystallization speed. A straightforward explanation is proposed for the reversal of the charge‐carrier sign beyond a critical doping threshold. The effect of Bi on the optical properties of GST is also investigated. The microscopic insight from this study may assist in the future selection of dopants to optimize the phase‐change properties of GST, and also of other PCMs, and the general methods employed in this work should be applicable to the study of related materials, for example, doped chalcogenide glasses.     

Insulator‐Conductor Type Transitions in Graphene‐Modified Silver Nanowire Networks: A Route to Inexpensive Transparent Conductors

Silver nanowire coatings are an attractive alternative to indium tin oxide for producing transparent conductors. To fabricate coatings with low sheet resistance required for touchscreen displays, a multi‐layer network of silver nanowires must be produced that may not be cost effective. This problem is counteracted here by modifying the electrical properties of an ultra‐low‐density nanowire network through local deposition of conducting graphene platelets. Unlike other solution‐processed materials, such as graphene oxide, our pristine graphene is free of oxygen functional groups, resulting in it being electrically conducting without the need for further chemical treatment. Graphene adsorption at inter‐wire junctions as well as graphene connecting adjacent wires contributes to a marked enhancement in electrical properties. Using our approach, the amount of nanowires needed to produce viable transparent electrodes could be more than 50 times less than the equivalent pristine high density nanowire networks, thus having major commercial implications. Using a laser ablation process, it is shown that the resulting films can be patterned into individual electrode structures, which is a pre‐requisite to touchscreen sensor fabrication.     

Characterization of Security Notions for Probabilistic Private-Key Encryption

The development of precise definitions of security for encryption, as well as a detailed understanding of their relationships, has been a major area of research in modern cryptography. Here, we focus on the case of private-key encryption. Extending security notions from the public-key setting, we define security in the sense of both indistinguishability and non-malleability against chosen-plaintext and chosen-ciphertext attacks, considering both non-adaptive (i.e., ``lunchtime') and adaptive oracle access (adaptive here refers to an adversary's ability to interact with a given oracle even after viewing the challenge ciphertext). We then characterize the 18 resulting security notions in two ways. First, we construct a complete hierarchy of security notions; that is, for every pair of definitions we show whether one definition is stronger than the other, whether the definitions are equivalent, or whether they are incomparable. Second, we partition these notions of security into two classes (computational or information-theoretic) depending on whether one-way functions are necessary in order for encryption schemes satisfying the definition to exist. Perhaps our most surprising result is that security against adaptive chosen-plaintext attack is (polynomially) equivalent to security against non-adaptive chosen-plaintext attack. On the other hand, the ability of an adversary to mount a (non-adaptive) chosen-plaintext attack is the key feature distinguishing computational and information-theoretic notions of security. These results hold for all security notions considered here.     

Delivery of iPS‐NPCs to the Stroke Cavity within a Hyaluronic Acid Matrix Promotes the Differentiation of Transplanted Cells

Stroke is the leading cause of adult disability with ≈80% being ischemic. Stem cell transplantation has been shown to improve functional recovery. However, the overall survival and differentiation of these cells is still low. The infarct cavity is an ideal location for transplantation as it is directly adjacent to the highly plastic peri‐infarct region. Direct transplantation of cells near the infarct cavity has resulted in low cell viability. Here, neural progenitor cells derived from induce pluripotent stem cells (iPS‐NPC) are delivered to the infarct cavity of stroked mice encapsulated in a hyaluronic acid hydrogel matrix to protect the cells. To improve the overall viability of transplanted cells, each step of the transplantation process is optimized. Hydrogel mechanics and cell injection parameters are investigated to determine their effects on the inflammatory response of the brain and cell viability, respectively. Using parameters that balanced the desire to keep surgery invasiveness minimal and cell viability high, iPS‐NPCs are transplanted to the stroke cavity of mice encapsulated in buffer or the hydrogel. While the hydrogel does not promote stem cell survival one week post‐transplantation, it does promote differentiation of the neural progenitor cells to neuroblasts.     

A shared-memory virtual channel queue for ATM broadband terminal adaptors

In order to take advantage of the low entry cost of the future public ATM (asynchronous transfer mode) network with shared facilities, it is highly desirable to interconnect different hosts and local area networks (LANs) to the ATM network. The interface between the computer hosts or LANs and the ATM network, commonly called a broadband terminal adaptor (BTA), provides the necessary format conversion for the data packets and the ATM cells. It is conceivable that multiple packets from different virtual channels are interleaved as they arrive at the receive-end BTA. The BTA must have a sufficiently large buffer, called a virtual channel queue (VCQ), to temporarily store the partially received packets. Once a complete packet has been received, it is forwarded to the host or LAN. Whenever the buffer fills with all incomplete packets, a packet must be discarded to make room for others. In this paper, we first study, through computer simulations, the buffer size requirement of a shared-memory VCQ for different numbers of virtual channels at various packet loss probabilities. We then present two different implementation architectures for the shared-memory VCQ, and compare their hardware complexity. The second architecture with linked-queue approach, adopted in our work, requires less buffer and has better scalability to accommodate a large number of virtual channels. Various possible error conditions, such as cell losses in the ATM network and the VCQ buffer overflow, are considered. Corresponding solutions are proposed and included in the VCQ designs.     

The Social News Gap: How News Reading and News Sharing Diverge

This article seeks to explain variation in news sharing patterns on social media. It finds that news editors have considerable power to shape the social media agenda through the use of “story importance cues” but also shows that there are some areas of news reporting (such as those related to crime and disasters) where this power does not apply. This highlights the existence of a social “news gap” where social media filters out certain types of news, producing a social media news agenda which has important differences from its traditional counterpart. The discussion suggests that this may be consequential for perceptions of crime and engagement with politics; it might even stimulate a partial reversal of the tabloidization of news outlets.     

Plasma Lipid Peroxidation and Vitamin E Supplementation during High Intakes of Fish-Oil Fatty Acids

High intakes of fish oil concentrates (15g/day MaxEPA) resulted in increased TBARS in plasma after 2 weeks irrespective of the vitamin E intake and plasma content. After 4 weeks TBARS values returned to normal despite continued MaxEPA supplementation and different vitamin E levels. Fish oil supplements resulted in increased whole-blood aggregation and higher plasma glucose concentrations which did not occur when extra vitamin E was given. No significant differences in plasma cholesterol levels were observed.     

FNS Control Schemes for the Upper Limb

This paper is concerned with the problems of control associated with the application of functional neuromuscular stimulation of the upper limb, concentrating on elbow flexion/extension and wrist pronation/supination. A closed-loop controller is needed in order to overcome the gain nonlinearities and plant dynamic parameter variations. Controllers were developed based on models and parameters previously established. Two controllers are discussed in detail, a thirdorder feedforward controller and a model reference adaptive controller. There were no striking differences in the performances of the thirdorder controllers. The conventional controllers, however, required a lengthy a priori identification procedure each time they were used. This was performed implicitly by the adaptive controller within a few seconds, making it a practical proposition for an FNS controller.     

Ammoxidation of toluene over Y-Ba-Cu-Co-O perovskites

Ammoxidation of toluene over the perovskites YBa₂Cu₃O_6.1, YBa₂Cu₂CoO_6.7 and YBaCuCoO_4.9 was investigated at 400 °C. At low partial pressures of O₂ benzonitrile was selectively formed, while CO₂ was the main product at high pressures of O₂. Systematic differences in activity were observed for the three phases and are related to the crystal contents of Cu and Co. At low O₂ pressures, Cu-sites are active for nitrile formation, while Co-sites give CO₂. At high O₂ pressures, the activity for CO₂ of Cu-sites increases more than that of Co-sites due to filling of near-surface oxygen vacancies.