A new method for the calculation of propagation constants and fieldprofiles of guided modes of nonlinear channel waveguides based on theeffective index method

In this paper, an extension of the effective index method (EIM) to waveguiding structures containing ideal or saturable third-order nonlinear materials is presented. By applying separation of variables to the dominant field component, the complete problem is subdivided into two scalar problems in the lateral and transverse direction, as in the case of the normal EIM. Making use of the strong transverse confinement, as observed in most real waveguide structures, the nonlinear index changes of the various transverse sections can be lumped into nonlinear effective indexes of the equivalent layered planar structures. By using these nonlinear effective indexes in self-consistent field calculations in the transverse direction, a complete approximate solution is obtained. In this way, the amount of computational effort required for the calculation of the effective indexes and field profiles of the waveguides can be reduced significantly     

Release of Bisphenol A from Polycarbonate—A Review

The release of Bisphenol A (BPA) from polycarbonate baby bottles into food and food simulants is reviewed in the perspective of the current intensive discussions on the risks of this substance. Potential factors that have been reported to influence the release of BPA are reviewed. Unlike most polymers polycarbonate is hydrolyzed under alkaline conditions by scale formation, residual alkaline detergents and boiled water. Data suggest that brushing of the bottle did not raise the release of BPA. Claims that used bottles release more BPA than new bottles and that mineral composition of the aqueous food simulant affect release could not be substantiated. There are indications that aminolysis of polycarbonate by milk and ethanolysis of polycarbonate by 50% ethanol might take place under relevant test conditions.

The relatively few migration data following the test conditions of European food contact material legislation, comply with the specific migration limit. Two test conditions were identified that reflect real use and exposure, and might cause higher release of BPA compared to the test conditions of European food contact material legislation. Further detailed studies are necessary to verify whether these two exposure scenarios are more severe.     

Effect of rotor–tower interaction,tilt angle,and yaw misalignment on the aeroelasticity of a large horizontal axis wind turbine with composite blades

This paper presents a detailed analysis of the rotor–tower interaction and the effects of the rotor's tilt angle and yaw misalignment on a large horizontal axis wind turbine. A high‐fidelity aeroelastic model is employed, coupling computational fluid dynamics (CFD) and structural mechanics (CSM). The wind velocity stratification induced by the atmospheric boundary layer (ABL) is modeled. On the CSM side, the complex composite structure of each blade is accurately modeled using shell elements. The rotor–tower interaction is analyzed by comparing results of a rotor‐only simulation and a full‐machine simulation, observing a sudden drop in loads, deformations, and power production of each blade, when passing in front of the tower. Subsequently, a tilt angle is introduced on the rotor, and its effect on blade displacements, loads, and performance is studied, representing a novelty with respect to the available literature. The tilt angle leads to a different contribution of gravity to the blade deformations, sensibly affecting the stresses in the composite material. Lastly, a yaw misalignment is introduced with respect to the incoming wind, and the resulting changes in the blade solicitations are analyzed. In particular, a reduction of the blade axial displacement amplitude during each revolution is observed.     

Effect of accelerated aging of MSWI bottom ash on the leaching mechanisms of copper and molybdenum

The effect of accelerated aging of Municipal Solid Waste Incinerator (MSWI) bottom ash on the leaching of Cu and Mo was studied using a "multisurface" modeling approach, based on surface complexation to iron/aluminum (hydr)oxides, mineral dissolution/precipitation, and metal complexation by humic substances. A novel experimental method allowed us to identify that the solid/liquid partitioning of fulvic acids (FA) quantitatively explains the observed beneficial effect of accelerated aging on the leaching of Cu. Our results suggestthat iron/aluminum (hydr)oxides are the major reactive surfaces that retain fulvic acid in the bottom ash matrix, of which the aluminum (hydr)oxides were found to increase after aging. A new modeling approach, based on the surface complexation of FA on iron/aluminum (hydr)oxides is developed to describe the pH-dependent leaching of FA from MSWI bottom ash. Accelerated aging results in enhanced adsorption of FA to (neoformed) iron/aluminum (hydr)oxides, leading to a significant decrease in the leaching of FA and associated Cu. Accelerated aging was also found to reduce the leaching of Mo, which is also attributed to enhanced adsorption to (neoformed) iron/aluminum (hydr)oxides. These findings provide important new insights that may help to improve accelerated aging technology.     

Deadlock detection in MPI programs

The Message‐Passing Interface (MPI) is commonly used to write parallel programs for distributed memory parallel computers. MPI‐CHECK is a tool developed to aid in the debugging of MPI programs that are written in free or fixed format Fortran 90 and Fortran 77. This paper presents the methods used in MPI‐CHECK 2.0 to detect many situations where actual and potential deadlocks occur when using blocking and non‐blocking point‐to‐point routines as well as when using collective routines. Copyright © 2002 John Wiley & Sons, Ltd.     

Stress-assisted crystallisation in anodic titania

The relationship between the microstructural and internal stress evolution during Ti anodising is discussed. Samples anodised galvanostatically to 12 V and 40 V, corresponding to different stages of the internal stress evolution, were examined by in-plane and cross-section transmission electron microscopy. Electron diffraction patterns have been complemented with stoichiometry data obtained from energy loss near edge structure spectra. The sample anodised to 40 V was observed to consist of two regions, with a crystallised inner region adjacent to the metal/oxide interface. Crystallisation of this region is associated with the presence of large compressive internal stresses which build up during anodising up to 12 V.     

The effect of silicon, aluminium and phosphor on the dynamic behavior and phenomenological modelling of multiphase TRIP steels

Multiphase TRansformation Induced Plasticity (TRIP) steels combine excellent ductility and high strength, making them ideally suited for shock absorbing parts in the automotive industry. When designing structures for impact, an understanding of the mechanical properties of materials under high strain rate conditions is essential. An extensive experimental program using a split Hopkinson tensile bar set-up was established in an effort to investigate the dynamic properties of various TRIP steel grades. Four different TRIP steels are described with varying contents of the alloying elements silicon, aluminium and phosphor. Moreover, several phenomenological models describing the strain rate and temperature-dependent mechanical behaviour are validated. TRIP steel grades in which aluminium is the main alloying element show high elongation values, whereas a high silicon content results in an increase in strength. The widely used Johnson-Cook model can describe the behaviour of TRIP steels and provides the opportunity to study its material and structural response.     

Concentrations of selected essential and non-essential elements in arctic fox (Alopex lagopus) and wolverines (Gulo gulo) from the Canadian Arctic

Arctic fox (Alopex lagopus) and wolverine (Gulo gulo) tissues were collected in the Canadian Arctic from 1998 to 2001 and analyzed for various essential and non-essential elements. Several elements (Ag, Al, As, B, Ba, Be, Co, Cr, Mo, Ni, Sb, Sn, Sr, Tl, U and V) were near or below the detection limits in >95% arctic fox and wolverine samples. Concentrations of Cd, Cu, Fe, total Hg (THg), Mn, Pb, Se and Zn were quantifiable in >50% of the samples analyzed and reported herein. Hepatic elemental concentrations were not significantly different among arctic foxes collected at Ulukhaqtuuq (Holman), NT (n=13) and Arviat, NU (n=50), but were significantly greater than concentrations found in wolverine liver from Kugluktuk (Coppermine), NU (n=12). The mean (+/-1 S.E.) concentrations of Cd in kidney were also significantly greater in arctic fox (1.08+/-0.19 microg g(-1) wet wt.) than wolverine (0.67+/-0.18 microg g(-1) wet wt.). However, mean hepatic Cu concentrations (Ulukhaqtuuq: 5.5+/-0.64; Arviat: 7.1+/-0.49 microg g(-1) wet wt.) in arctic foxes were significantly lower than in wolverines (32+/-3.3 microg g(-1) wet wt.). Hepatic total Hg (THg) concentrations in arctic fox from this study were not significantly different from specimens collected in 1973, suggesting that THg concentrations have not changed dramatically over the past 30 years. The mono-methylmercury (MeHg) concentrations in selected (n=10) arctic fox liver samples from Arviat (0.14+/-0.07 microg g(-1) wet wt.) comprised 14% of THg. While the molar concentrations of THg were correlated with Se in arctic foxes and wolverines, the hepatic Hg/Se molar ratios were consistently lower than unity; suggesting that Se-mediated detoxification pathways of Hg are not overwhelmed at current exposure.     

Epidural anesthesia impairs both central and peripheral thermoregulatory control during general anesthesia

BACKGROUND: The authors tested the hypotheses that: (1) the vasoconstriction threshold during combined epidural/general anesthesia is less than that during general anesthesia alone; and (2) after vasoconstriction, core cooling rates during combined epidural/general anesthesia are greater than those during general anesthesia alone. Vasoconstriction thresholds and heat balance were evaluated under controlled circumstances in volunteers, whereas the clinical importance of intraoperative thermoregulatory vasoconstriction was evaluated in patients. METHODS: Five volunteers were each evaluated twice. On one of the randomly ordered days, epidural anesthesia (approximately T9 dermatomal level) was induced and maintained with 2-chloroprocaine. On both study days, general anesthesia was induced and maintained with isoflurane (0.7% end-tidal concentration), and core hypothermia was induced by surface cooling and continued for at least 1 h after fingertip vasoconstriction was observed. Patients undergoing colorectal surgery were randomly assigned to combined epidural/enflurane anesthesia (n = 13) or enflurane alone (n = 13). In appropriate patients, epidural anesthesia was maintained by an infusion of bupivacaine. The core temperature that triggered fingertip vasoconstriction identified the threshold. RESULTS: In the volunteers, the vasoconstriction threshold was 36.0 +/- 0.2 degrees C during isoflurane anesthesia alone, but significantly less, 35.1 +/- 0.7 degrees C, during combined epidural/isoflurane anesthesia. Cutaneous heat loss and the rates of core cooling were similar 30 min before vasoconstriction with and without epidural anesthesia. In the 30 min after vasoconstriction, heat loss decreased 33 +/- 13 W when the volunteers were given isoflurane alone, but only 8 +/- 16 W during combined epidural/isoflurane anesthesia. Similarly, the core cooling rates in the 30 min after vasoconstriction were significantly greater during combined epidural/isoflurane anesthesia (0.8 +/- 0.2 degrees C/h) than during isoflurane alone (0.2 +/- 0.1 degrees C/h). In the patients, end-tidal enflurane concentrations were slightly, but significantly, less in the patients given combined epidural/enflurane anesthesia (0.6 +/- 0.2% vs. 0.8 +/- 0.2%). Nonetheless, the vasoconstriction threshold was 34.5 +/- 0.6 degrees C in the epidural/enflurane group, which was significantly less than that in the other patients, 35.6 +/- 0.8 degrees C. When the study ended after 3 h of anesthesia, patients given combined epidural/enflurane anesthesia were 1.2 degrees C more hypothermic than those given general anesthesia alone. The rate of core cooling during the last hour of the study was 0.4 +/- 0.2 degrees C/h during combined epidural/enflurane anesthesia, but only 0.1 +/- 0.3 degrees C/h during enflurane alone. CONCLUSIONS: These data indicate that epidural anesthesia reduces the vasoconstriction threshold during general anesthesia. Furthermore, the markedly reduced rate of core cooling during general anesthesia alone illustrates the importance of leg vasoconstriction in maintaining core temperature.