Improvement in hydrolytic procedure for GLC determination of non-indolyl glucosinolates in rapeseed as isothiocyanates

Some methods determine the non-indolyl glucosinolates content in rapeseed as their hydrolysates: the isothiocyanates and the oxazolidinethiones. These methods in their present form underestimate the amount of the glucosinolates content. In this investigation, a modified method was developed to give a better quantitative estimate, indicating a glucosinolate level five times that obtained by a typical existing method.     

FATIGUE DAMAGE IN 1045 STEEL UNDER VARIABLE AMPLITUDE BIAXIAL LOADING

Abstract— During constant amplitude loading, two different types of crack systems have been reported In the high cycle fatigue (HCF) region, cracks nucleate on a small number of maxium shear strain amplitude planes One of these cracks becomes a dominant crack and leads to failure of the specimen In the low cycle fatigue (LCF) region, equally developed microcracks are observed over the entire gage section and grow during the majority of the life. The failure is due to a linking in which the microcracks join up during the last few cycles of the fatigue life.
To investigate the interaction of these two types of crack systems in biaxial fatigue, experiments were performed on thin-wall tubular specimens in tension, torsion and combined tension-torsion loading The test program included step loading and block loading in which two equivalent strain amplitudes were employed. One of the equivalent strain amplitudes is in the HCF region and the other was in the LCF region
Fatigue lives were predicted from constant amplitude damage curves when a single crack system dominated the fatigue process Two competitive crack systems were sometimes developed on the maximum shear strain amplitude planes in a single specimen under block loading This resulted in a conservative prediction of the fatigue life.     

Determination of the relative amounts of free and complexed manganese ions in aqueous solution by nuclear magnetic resonance.

The ratio of the transverse relaxation rate to the longitudinal relaxation rate of water protons (T1/T2) at 90 MHz can be used to determine the relative amounts of free Mn2+ ions (the hexaquo ion) and chelated manganese ions when both species are present in the same aqueous solution. This technique is demonstrated for simple aqueous solutions containing known concentrations of both the free Mn2+ ion and a manganese(III) porphyrin. The accuracy of the method is found to be +/- 7.3% for the solutions considered in this report. The determinations of the relative amounts of the free Mn2+ ion and the manganese(III) porphyrin by this T1/T2 method are shown to agree well with those determined by nuclear magnetic resonance dispersion profiles. The theoretical basis of this ratio method as well as the scope and limitations in its application to aqueous solutions containing both free Mn2+ ions and chelated manganese species other than manganese(III) porphyrins are also discussed. This work demonstrates a unique use of NMR as a means for the quantitative analysis of manganese in which the effects of the metal ion on the solvent, and not the metal itself, are observed.     

High-resolution electron microscopy of the twinning and intergrowth in Ca4Al6SO16 and Ca3SrAl6SO16

The microstructures of unhydrated calcium aluminosulphate Ca₄Al₆SO₁₆ and Ca₃SrAl₆SO₁₆ have been studied by high-resolution electron microscopy (HREM). The results showed that twinning and twinned slabs could be introduced taking the [1 1 2] direction as the twin axis so that it seems to be coincident with the law of twinning formed in body-centred cubic structures. A previously reported superlattice with a repeat period twice that of the fundamental structure along the 〈1 1 0〉 direction has also been found in both matrix and twin variants. The close intergrowth of Ca₃SrAl₆SO₁₆ and another phase, possibly Sr₃Al₂O₆ existing as an inclusion between these two twin variants, was determined and clearly revealed by electron diffraction and HREM images. The coherent interphase boundaries and orientation relationship between them can also be deduced.     

Mechanical properties of SiNxCx ceramic films prepared by plasma CVD

The mechanical properties of Si₃N₄-SiC, SiN_x and SiC_y films prepared at a low temperature of 400 °C by plasma chemical vapour deposition are reported. Microhardness, internal stress of the film and adhesive strength between the film and glass or stainless steel substrate were evaluated as principal mechanical properties. Microhardness was measured to be about 10 to 20 G Pa dependent on the film composition in each system. Internal stress of the films on borosilicate glass substrates extensively varied from tensile to compressive with the film composition change from Si₃N₄ to SiC. Adhesive strength, as ascertained by the scratch test, was about 580 to 800 MPa for crown glass substrates, and about 210 to 310 M Pa for 316 stainless steel substrates. It is pointed out that tensile stress in these films brought about more abrupt decreases of the adhesive strength than did compressive stress.     

Waveband-switchable SOA ring laser constructed with a phase modulator loop mirror filter

An electrically tunable multiwavelength source has been developed using a birefringence-based optical comb filter in a semiconductor optical amplifier ring laser. The filter is constructed with an electrooptic phase modulator placed inside a fiber loop mirror. By controlling the birefringence of the modulator through the applied bias, the radio-frequency power, or the modulation frequency, we achieve a continuous shift of the spectral comb to access different interleaved wavebands. Electrical waveband switching has been successfully demonstrated for 21 wavelengths at 100-GHz grid spacing with an optical signal-to-noise ratio over 40 dB.     

Widely tunable bottom-emitting vertical-cavity SOAs

We present bottom-emitting tunable vertical-cavity semiconductor optical amplifiers (VCSOAs) with an effective wavelength tuning range of >20 nm. These devices utilize a high reflectivity micromechanically tunable Bragg mirror as the back reflector. Compared with our first generation tunable VCSOAs, the bottom-emitting devices exhibit a two-fold increase in the effective tuning range as well as a five-fold reduction in the required tuning voltage.     

Dyadic-based factorizations for regular paraunitary filterbanks and M-band orthogonal wavelets with structural vanishing moments

Paraunitary filterbanks (PUFBs) can be designed and implemented using either degree-one or order-one dyadic-based factorization. This work discusses how regularity of a desired degree is structurally imposed on such factorizations for any number of channels M /spl ges/ 2, without necessarily constraining the phase responses. The regular linear-phase PUFBs become a special case under the proposed framework. We show that the regularity conditions are conveniently expressed in terms of recently reported M-channel lifting structures, which allow for fast, reversible, and possibly multiplierless implementations in addition to improved design efficiency, as suggested by numerical experience. M-band orthonormal wavelets with structural vanishing moments are obtained by iterating the resulting regular PUFBs on the lowpass channel. Design examples are presented and evaluated using a transform-based image coder, and they are found to outperform previously reported designs.     

Novel T-rail electrodes for substrate removed low-voltage high-speed GaAs/AlGaAs electrooptic modulators

A novel traveling-wave electrode utilizing capacitively loaded T-rail elements was developed for low-voltage high-speed substrate-removed GaAs/AlGaAs electrooptic modulators. Electrodes with varying dimensions were fabricated and characterized. Electrode phase velocity, characteristic impedance, loss coefficient, and capacitive loading were extracted from the measured s-parameters up to 40 GHz. Electrode was also simulated using a finite-element solver. The measured and calculated electrode capacitance values were found to be in excellent agreement, showing that the electrode can be precisely designed. Approaches were outlined to provide a group velocity-matched very high-speed modulator electrode suitable for a low drive-voltage substrate-removed GaAs/AlGaAs electro-optic modulator