Erhebung zum betrieblichen Datenschutz in Mecklenburg-Vorpommern

Ohne Zusammenfassung     

COMPLEX FORMATION AND LIQUID-LIQUID EXTRACTION OF SILVER WITH CYCLIC AND OPEN-CHAIN OXATHIA ALKANES

The complex forming and extraction properties of various open-chain and two cyclic oxathia alkanes towards silver have been studied. The investigations confirm the direct proportionality between extraction constants and related complex stability constants.The extraction of silver by open-chain oxethie alkenee is greeter than by structurally analogoue thicacrown compounds. This fact and the determined stability constants show an absence of a macrocyclic effect during complex formation. The differences of extraction power between the various open-chain compounds can be interpreted on the basic o f the coordinative saturation and stereochemiatry of the silver ion, on the size o f the poesible chelate rings, and on the complexing capability o f the ether oxygen atoms.     

On negative dispersion without absorption in bichromatically driven two-level systems

Abstract

The possibility of obtaining strong negative dispersion without absorption in the central resonance structure of the spectrum of a bichromatically driven two-level system is investigated. A nonlinear analysis is performed using the technique of continued fractions with respect to the dressedstate basis of a strong pumping laser. We discuss the transition between the two regimes of the monochromatic driving case with a weak probing laser and of nearly equally strong lasers in terms of the contributions from coherences and populations of these dressed states. In contrast with the strong dependence of the Rabi side bands on probe field intensity, we find a remarkable stability of the negative dispersion in the central resonance structure.     

VC Management for Heterogeneous QoS Multicast Transmissions

A crucial component of the interaction between ATM's and the Internet's Quality of Service (QoS) architectures is the efficient mapping of RSVP (Resource reSerVation Protocol) as the Internet's signalling protocol onto the according ATM mechanisms. In particular, this article focuses on one of the most contrary characteristics of RSVP and ATM signalling. This is the support for heterogeneous reservations by RSVP over the ATM subnetwork, taking into account that ATM only allows for a homogeneous QoS within a single Virtual Circuit (VC). We present previous approaches to the solution of this problem and argue for more sophisticated and efficient approaches to manage ATM VCs taking into consideration ATM tariffs and resource consumption.     

Multiphoton imaging with a novel compact diode‐pumped Ti:sapphire oscillator

Multiphoton laser scanning microscopy commonly relies on bulky and expensive femtosecond lasers. We integrated a novel minimal‐footprint Ti:sapphire oscillator, pumped by a frequency‐doubled distributed Bragg reflector tapered diode laser, into a clinical multiphoton tomograph and evaluated its imaging capability using different biological samples, i.e. cell monolayers, corneal tissue, and human skin. With the novel laser, the realization of very compact Ti:sapphire‐based systems for high‐quality multiphoton imaging at a significantly size and weight compared to current systems will become possible. Microsc. Res. Tech. 78:1154–1158, 2015. © 2015 Wiley Periodicals, Inc.     

Experimentelle und numerische Untersuchungen zum Tragverhalten von Stahlbetondecken mit kugelförmigen Hohlkörpern

Massive Flachdecken erweisen sich in Hoch‐ und Industriebau häufig als insgesamt überlegenes Deckensystem. Die hohe Eigenlast dieser Decken kann ihren Anwendungsbereich jedoch einschränken. Eine sinnvolle Abhilfe schafft dann die Integration von Hohlkörpern in der neutralen Zone, weil hierdurch eine spürbare Gewichtsreduktion eintritt. Neben der Eigenlast wird auch der Verbrauch der unter ökologischen Gesichtspunkten wesentlichen Ressourcen Betonstahl und Zement deutlich verringert. Die Hohlräume beeinflussen vor allem die Querkrafttragfähigkeit solcher Decken. Vier Versuchsserien, die mit kugelförmigen Hohlkörperdecken des Systems “cobiax” durchgeführt wurden, werden in diesem Beitrag beschrieben. Aus den Versuchen wird ein Abminderungsfaktor zur Beschreibung des Querkrafttragverhaltens abgeleitet, der auch in die kürzlich erteilte allgemeine bauaufsichtliche Zulassung des Deckensystems eingegangen ist. Die Nachrechnung der Versuche mit der Finite‐Elemente‐Methode zeigt eine gute Übereinstimmung von Numerik und Experiment, so dass in der Weiterentwicklung Parameterstudien auf dieser Grundlage zur Ergänzung von Versuchen hilfreich sein werden. Experimental and Numerical Investigation of the Bearing Behaviour of Hollow Core Slabs Massive flat slabs have proven to be the most appropriate ceiling system for structural and industrial engineering. However the high dead load of these slabs might reduce their field of application. This problem can be solved by void formers that are placed in the neutral zone. These block‐outs cause a noticeable reduction of weight. Furthermore, the masses of ecologically important resources like reinforcement steel and cement can be reduced as well. The shear bearing capacity is significantly influenced by these block‐outs. This article describes four test series with spherical void former floors of the system “cobiax”. A reduction factor for the shear bearing capacity is derived from these tests. That factor was also introduced in the technical approval for this slab system which has been issued recently. A comparison to a calculation with the finite element method shows that the numerical results and the results of the tests are quite similar. In future research, parameter studies based on the finite element method might be helpful additional to further tests.     

Size charge fractionation of metals in municipal solid waste landfill leachate

Municipal solid waste landfill leachates from 9 Norwegian sites were size charge fractionated in the field, to obtain three fractions: particulate and colloidal matter >0.45microm, free anions/non-labile complexes <0.45microm and free cations/labile complexes <0.45microm. The fractionation showed that Cd and Zn, and especially Cu and Pb, were present to a large degree (63-98%) as particulate and colloidal matter >0.45microm. Cr, Co and Ni were on the contrary present mostly as non-labile complexes (69-79%) <0.45microm. The major cations Ca, Mg, K, and Mn were present mainly as free cations/labile complexes <0.45microm, while As and Mo were present to a large degree (70-90%) as free anions/non-labile complexes <0.45microm. Aluminium was present mainly as particulate and colloidal matter >0.45microm. The particulate and colloidal matter >0.45microm was mainly inorganic; indicating that the metals present in this fraction were bound as inorganic compounds. The fractionation gives important information on the mobility and potential bioavailability of the metals investigated, in contrast to the total metal concentrations usually reported. To study possible changes in respective metal species in leachate in aerated sedimentation tanks, freshly sampled leachate was stored for 48h, and subsequently fractionated. This showed that the free heavy metals are partly immobilized during storage of leachate with oxygen available. The largest effects were found for Cd and Zn. The proportion of As and Cr present as particulate matter or colloids >0.45microm also increased.     

Prevalence of Yersinia enterocolitica in fattening pigs

The prevalence of pathogenic Yersinia enterocolitica in pig herds was monitored during six trials (at four different farrow-to-finisher farms). Samples were taken throughout the whole rearing period from birth of the piglets to the final fattening stage, and different samples were taken from these pigs during the slaughter process. Environmental samples also were evaluated to identify potential sources of on-farm infection. Y. enterocolitica was isolated using irgasan-ticarcillin-potassium chlorate broth enrichment and cefsulodin-irgasan-novobiocin agar culture. Colonies were identified using bio- and serotyping methods and by PCR assay. Pathogenic Y. enterocolitica were not isolated from fecal samples from piglets and weaners. The only fecal samples positive for Y. enterocolitica were obtained during the fattening stage. The prevalence of Y. enterocolitica in fattening pig herds ranged between 0 and 65.4%. Y. enterocolitica isolates were detected at the abattoir in 38.4% of the tonsils, in 3.8% of the ileocecal lymph nodes, on 0.3% of the carcass surfaces before chilling, and on 0% of the carcass surfaces after chilling. Almost all isolates belonged to bioserotype 4/O:3. Only one strain was identified as O:9. All isolates contained the ail gene. The yopT gene was found in 99.1% of the farm isolates but in only 76.6% of the isolates found at the abattoir from the corresponding carcasses. Although a direct link between porcine isolates and human infection has not been demonstrated, the similarity of the bioserotypes in infected pigs and humans and the presence of virulence factors in porcine isolates should encourage further studies to determine the risk of transmission of Y. enterocolitica to humans from pigs and pork products.     

LIQUID-LIQUID EXTRACTION STUDIES OF METAL IONS WITH DIAZACROWN AND STRUCTURE ANALOGOUS OPEN-CHAIN COMPOUNOS

1,10-diaze [8]crown-6, their N,N'-dibutyl- and dioctyl-substituted derivatives and the structure analogous open-chein tetreoxedieza slkanee have been synthesized in order to examine the extraction properties for Na⁺, K⁺, Sr²⁺ and Hg²⁺. It wes found, that the extraction of strontium, potassium and sodium picratee with azacrown compounds ie much higher than that with open-chein oxaaze alkanes. 1,10-diaze [18] erown-6 has a good selectivity for the extraction of Sr²⁺ over K⁺ and Na in alkaline solution. In the case of Sr²⁺ the diffarencea between tha various azacrown compounds are email, whereea in the caee of K⁺ and Na the substituted derivativee are better extractante. Theserssulte correspond qualitativsly with tha order of stebility conetantB in protic solvsnts. The extrectebility of N,N'-dioctyl-l, 10-dieze[18]crown-6 for HgCl₂ is very high. Contrerv to the order of stability conetants the uneubetituted conpound do not extract mercury under the choeen experimental condition*. The extraction power of open-chain conpounde ie aleo high and strong Influenced by the alkyl eubatltuente at the nitrogen donor stons,