Experimental Liquidus Surface Projection of the Ni-Ru-Zr System

SEM with EDX and XRD analyses were used to study 21 as-cast Ni-Ru-Zr alloys. Phases were distinguished by BSE image contrast, and the primary phases were determined by their dendritic morphology, with the solidification sequences derived from the microstructure. Identification of the phases was done by EDX analyses, and they were verified by XRD. From these analyses, the solidus and liquidus surface projections were drawn. Three ternary phases were found: τ₁ of composition ~Zr₂₄Ru₂₂Ni₄₄ (at.%), τ₂ at ~Zr₇₄Ru₄Ni₂₂ (at.%), and τ₃ at ~Zr₃₅Ru₃Ni₆₂ (at.%). Sixteen invariant reactions were identified, and the largest liquidus surface was for ~ZrRu.     

Differential finishing of freeform surfaces (knee joint) using R-MRAFF process and negative replica of workpiece as a fixture

It is difficult and challenging to achieve uniform nanoscale surface finish in the contact zone, particularly on freeform (or sculptured) surfaces having different curvatures at different locations. Femoral (or, Knee joint component) is one of such biomedical freeform component which has complex profile along its curvature. Surface conditions of a femoral decide the life of the implant and they play a crucial role in its functionality. The variation in surface roughness of the femoral should be minimum in the contact zone. For this purpose, a special tooling is being proposed for rotational magnetorheological abrasive flow finishing (R-MRAFF) process. A negative replica of the workpiece (knee joint) as a tool (or a fixture) is used so that the medium flow velocity in the fluid flow channel is almost constant (or minimum possible variations) along the medium flow direction. It is able to do differential finishing also along the curvature. In addition, pulsating magnetic field has been used to generate vibrations in the medium in the finishing zone so that the possibility of fresh abrasive particles interacting with the surface of femoral is high. The surface finish has been achieved ranging from 26 nm to 62 nm using the proposed finishing technique and negative replica of the workpiece (femoral) as a fixture.     

Crystallization of Stoichiometric SbSI Glass

Congruent crystallization of antimony sulphoiodide (SbSI) glass of stoichiometric composition, which is prepared successfully for the first time using rapid melt‐quenching, has been investigated using differential scanning calorimetry (DSC). The results for glass powder show a glass transition at 127°C and two separate exothermal peaks with maxima around 140°C and 190°C. The ratio of the intensities of the exothermal peak at ~190°C to the peak at ~140°C increases as the particle size and heating rate are increased, but their total enthalpy remains constant at 62 ± 2 J/g for all DSC runs. Surface heating of the glass induced by a 520 nm CW laser shows two contracted regions: needle‐like crystalline formations at low temperature and bulk crystallization at high temperature. The observed phenomena and DSC results suggest two different kinds of crystallization of the SbSI phase: one‐dimensional crystallization at low temperature which starts from the sample surface and three‐dimensional bulk crystallization that continues the transformation to crystalline state at higher temperatures. The origin of the two different crystallizations can be traced to the strong anisotropy of the SbSI crystal structure due to the weak van der Waals interaction between covalent‐ionic chains (Sb₂S₂I₂)_n.     

Dendrimer as nanocarrier for drug delivery

Dendrimers are novel three dimensional, hyperbranched globular nanopolymeric architectures. Attractive features like nanoscopic size, narrow polydispersity index, excellent control over molecular structure, availability of multiple functional groups at the periphery and cavities in the interior distinguish them amongst the available polymers. Applications of dendrimers in a large variety of fields have been explored. Drug delivery scientists are especially enthusiastic about possible utility of dendrimers as drug delivery tool. Terminal functionalities provide a platform for conjugation of the drug and targeting moieties. In addition, these peripheral functional groups can be employed to tailor-make the properties of dendrimers, enhancing their versatility. The present review highlights the contribution of dendrimers in the field of nanotechnology with intent to aid the researchers in exploring dendrimers in the field of drug delivery.     

Propellant Gas Phase Chemical Kinetics

An adiabatic constant pressure chemical kinetic study of the AP gas phase is conducted. The objective is to examine the importance of chemical kinetic studies for propellant deflagration modelling in general and for AP in particular. A reaction mechanism consisting of ninety five elementary reactions involving twenty one chemical species is developed to represent the AP gas phase. An important parameter that can be obtained from the kinetics is the time rate of change of temperature of the gas phase at the condensed phase-gas phase boundary (dT/dt at t = 0). This is directly related to the heat feedback from the gas phase to the condensed phase. Comparison with earlier work indicates that the use of a one-step overall reaction could lead to underestimates of heat feedback from the gas phase by a factor of about four. In addition it is found that the rate of decrease of dT/dt at t = 0, with pressure is much larger at lower pressures, suggesting a possible gas phase role in the low pressure deflagration limit. Further, the kinetic study does not support the conclusion of a constant fraction of AP reacting in the condensed phase in the pressure range 20–100 atmospheres. These results are at variance with what is obtained by use of a one-step overall reaction. Thus, the one-step overall reaction cannot represent even qualitatively several gas phase characteristics important for deflagration studies, and its use leads to erroneous results. It is concluded that a full reaction mechanism representation of gas phase chemical kinetics is essential to AP deflagration modelling. The same conclusion is probably valid for propellant deflagration modelling in general.     

Fabrication and optimization of polypyrrole/cerium oxide/glassy carbon sensing platform for the electrochemical detection of flupirtine

Journal of Applied Electrochemistry - In spite of single nanomaterials, nanocomposites have come to be the superior modifying materials for electrochemical sensing. Herein, the highly...     

Energetics of Propellants,Fuels and Explosives; a chemical valence approach

A simple approach involving the chemical valences of the fuel and the oxidizer elements present in a combustible mixture is described to evaluate the energetics related parameters of propellants, fuels and explosives. It simplifies the stoichiometric balancing of complex combustion equations, and provides an easy method of calculating the elemental stoichiometric coefficient. The method correctly predicts whether a mixture is fuel-lean, fuel-rich or stoichiometrically balanced. The calorimetric value of various stoichiometrically balanced combustible systems has been shown to be linearly dependent upon their total oxidizing (or reducing) valences. This relationship has been used successfully to evaluate the calorific value of fossil fuels. For fuel-rich explosives, a new valence dependent parameter has been derived which is found to be related with properties such as detonation velocity, heat of explosion and impact sensitivity.