Cyclization dynamics of polymers: 10 Synthesis,fractionation, and fluorescent spectroscopy of pyrene end-capped polystyrenes

The rate constant for end-to-end cyclization (k₁) for polymer chains is predicted to decrease sensitively with increasing chain length. In this paper the techniques are examined critically for extracting values of k₁ from experiments involving intramolecular pyrene excimer formation in polymers of the form pyrene-polystyrene-pyrene. For significance, results require samples of appropriately narrow molecular weight distribution ($\text{M}\text{?}{}_{\mathrm{w}}\text{M}\text{?}{}_{\mathrm{n}}\text{</ 1.13}$), as well as corrections for polydispersity differences among the samples. Particular attention is focussed both on experimental techniques and on the models used to interpret the kinetics of intramolecular pyrene excimer formation.     

Study of the incorporation of protic ionic liquids into hydrophilic and hydrophobic rigid-rod elastomeric polymers

A series of polymers was synthesized that contain a rigid aromatic backbone connected through triazine linkages that are cross-linked by flexible diamine-terminated poly(ethylene oxide) oligomers. Polymers were made that contained both hydrophilic sulfonated aromatic and hydrophobic pyridinium triflate backbones. Thermal and mechanical properties of the resulting polymer films were studied, as well as uptake of water and protic ionic liquids. Ionic liquid uptake varied from 41 to 440%, depending upon the nature of the polymer. The ionic liquid-doped films were analyzed for proton conductivity at high temperatures (>150 °C) under non-humidified conditions. Conductivities as high as 5×10⁻² S/cm were observed at 150 °C.     

A comparison of the biological properties of of androst-5-en-3β-ol,a series of (20R)-n-alkylpregn-5-en-3β-ols and 21-isopentylcholesterol with those of cholesterol

The Δ⁵-sterol, androst-5-en-3β-ol, which has no side chain at C-17, did not permit molting of the insectHeliothis zea, growth of either the protozoanTetrahymena pyriformis, or the yeastSaccharomyces cerevisiae adapted to anaerobic conditions, nor was the sterol esterified by a mammalian microsomal ACAT preparation. However, the sterol did form a liposome with egg lecithin and, when fed to mice, did inhibit hepatic cholesterol synthesis. 21-Isopentylcholesterol also formed a liposome but neither supported the growth of the yeast nor was metabolized by the protozoan. When sterols, 20(R)-n-alkylpregn-5-en-3β-ols, with side chains of varying lengths were added to the medium of the protozoan, maximal esterification with fatty acids occurred with the 20(R)-n-pentyl derivative, and maximal inhibition of tetrahymanol formation occurred with then-butyl,n-pentyl andn-hexyl derivatives. In all of the assays, cholesterol showed a positive response, either permitting molting or growth, being metabolized, inhibiting sterol or tetrahymanol synthesis, or forming a liposome.     

Oxidation of 3D-printed SiC in air and steam environments

The high-temperature oxidation of additively manufactured and chemically vapor infiltrated (3D-printed SiC) has been compared to chemical vapor deposited (CVD) SiC. 100-h isothermal exposures were conducted at 1425° and 1300°C at 1 atm under both dry air and steam environments. A SiC reaction tube was utilized to reduce silica volatility. After steam oxidation at 1425° and 1300°C, on the 3D-printed SiC surface, which was intrinsically rougher than the CVD surface, scales were 70%–90% thicker at the convex regions compared to concave/flat regions. In the convex regions, large cracks perpendicular to the oxidizing interface were observed. After dry air oxidation, scale thicknesses were comparable between 3D-printed SiC and CVD SiC, regardless of geometry. Finite element modeling, conducted to elucidate the relationship between SiC geometry and ß- to α-cristobalite transformation stress, determined cristobalite transformation tensile stresses to be on the order of 10³ MPa during cool down, assuming a 6 vol% reduction. Compared to flat SiC substrates, tensile transformation stresses were elevated at concave regions and relaxed at convex regions. Combined with specimen mass gain (accounting for the rougher surface) of 3D-printed SiC being 15%–32% higher for 3D-printed SiC after 1300°C and 1425°C steam oxidation, the work presented concludes that the increased oxidation of 3D-printed SiC is primarily caused by tensile hoop stresses driven by oxidation volume expansion. Lastly, the efficacy of the 3D-printing method is demonstrated through the production of tristructural isotropic imbedded 3D-printed SiC fuel forms.     

Cognitive Radio Engine Design for IoT Using Real-Coded Biogeography-Based Optimization and Fuzzy Decision Making

The Internet of Things (IoT) paradigm expands the current Internet and enables communication through machine to machine, while posing new challenges. Cognitive radio (CR) Systems have received much attention over the last decade, because of their ability to flexibly adapt their transmission parameters to their changing environment. Current technology trends are shifting to the adaptability of cognitive radio networks into IoT. The determination of the appropriate transmission parameters for a given wireless channel environment is the main feature of a cognitive radio engine. For wireless multicarrier transceivers, the problem becomes high dimensional due to the large number of decision variables required. Evolutionary algorithms are suitable techniques to solve the above-mentioned problem. In this paper, we design a CR engine for wireless multicarrier transceivers using real-coded biogeography-based optimization (RCBBO). The CR engine also uses a fuzzy decision maker for obtaining the best compromised solution. RCBBO uses a mutation operator in order to improve the diversity of the population and enhance the exploration ability of the original BBO algorithm. The simulation results show that the RCBBO driven CR engine can obtain better results than the original BBO and outperform results from the literature. Moreover, RCBBO is more efficient when applied to high-dimensional problems in cases of multicarrier system.     

The importance of gravity in droplet evaporation: A comparison of pendant and sessile drop evaporation with particles

As a droplet with particles evaporates, the particles deposit on the substrate surface. In this work, we show the extent of gravitational effects on the particle deposition profile and propose a new model for particle tracing in an evaporating droplet which accounts for gravitational effects. Experimentally, we compare pendant and sessile water droplets with 1 and 3 μm polystyrene particles. Numerically, the finite element method was used to create a transport model of the evaporating droplet system and particle deposition. The numerical and experimental results have excellent agreement and show that a pendant water droplet with 1 and 3 μm polystyrene spheres has significant separation of the two particle sizes. Finally, a phase diagaram was created to map different deposition profiles for various gravitational Péclet numbers (Pe_G) and ratios of Péclet number to Damköhler number (Pe/Da). © 2015 American Institute of Chemical Engineers AIChE J, 62: 947–955, 2016     

Walking the Tightrope: The Balancing Acts of a Large e-Research Project

Although e-Research has received much attention and acclaim in recent years, the realities of distributed collaboration still challenge even the most well-planned endeavors. This case study of an e-Research project examines the ‚balancing acts’ associated with multidisciplinary, geographically distributed, large-scale research and development work. After briefly describing the history and organizational design of this information technology and atmospheric science research project, I identify five paradoxical challenges that cannot be resolved: research versus development, harmony versus conflict, consensus versus top-down decision making, frequency and modes of communication, and fast versus slow pacing. Although collaboration and communication technologies supported the project’s management and organization, most of the complexities faced by the team were not technological in nature. From the five paradoxical challenges associated with the project, I distill three cross-cutting issues that could be relevant to other e-Research projects of this magnitude: satisfying the multiple needs of a multidisciplinary project, managing information, and engaging all participants. I identify the practical implications of these challenges and issues, specifically that organizational and low-tech solutions – not the introduction of more sophisticated technology tools – are needed to solve these challenges and to better streamline coordination.     

Statistical calibration of computer simulations

This paper surveys issues associated with the statistical calibration of physics-based computer simulators. Even in solidly physics-based models there are usually a number of parameters that are suitable targets for calibration. Statistical calibration means refining the prior distributions of such uncertain parameters based on matching some simulation outputs with data, as opposed to the practice of “tuning” or point estimation that is commonly called calibration in non-statistical contexts. Older methods for statistical calibration are reviewed before turning to recent work in which the calibration problem is embedded in a Gaussian process model. In procedures of this type, parameter estimation is carried out simultaneously with the estimation of the relationship between the calibrated simulator and truth.     

D-LTAG System: Discourse Parsing with a Lexicalized Tree-Adjoining Grammar

We present an implementation of a discourse parsing system for alexicalized Tree-Adjoining Grammar for discourse, specifying the integrationof sentence and discourse level processing. Our system is based on theassumption that the compositional aspects of semantics at thediscourse level parallel those at the sentence level. This coupling isachieved by factoring away inferential semantics and anaphoric features ofdiscourse connectives. Computationally, this parallelism is achievedbecause both the sentence and discourse grammar are LTAG-based and the sameparser works at both levels. The approach to an LTAG for discourse has beendeveloped by Webber and colleagues in some recent papers. Our system takes a discourseas input, parses the sentences individually, extracts the basic discourseconstituent units from the sentence derivations, and reparses the discoursewith reference to the discourse grammar while using the same parser usedat the sentence level.     

Progress towards ultrasound applications of new single crystal materials

In recent years, single crystal materials with better piezoelectric properties than the existing ceramics have become available. These new materials will potentially provide improved performance in ultrasonic applications such as NDT, sonar and biomedical diagnosis. In order to select the best material and optimize transducer design, comparison must be carried out. However, due to material and transducer fabrication costs, initial comparisons can be based on simulation. In this paper, a comparison is reported between transducers based on the single crystal lead magnesium niobate-lead titanate (PMN-32% PT) and the ceramic lead zirconate titanate (PZT-5H). Material performance is assessed both for single materials and piezoelectric-polymer composite configurations by defining the relevant piezoelectric parameters. Furthermore, the effect of such parameters on the performance of different ultrasonic transducers is illustrated. Practical limitations are also discussed. We conclude that the new single crystal material will be capable of outperforming the present widely used ceramic for almost all practical applications.