A protocol for the analysis of the positional distribution of fatty acids (FA) in solid triacylglycerols (TAG) was developed using sn-1(3) selective alcoholysis catalyzed by immobilized Candida antarctica lipase B (CALB). One part by weight of solid fat and ten parts by weight of ethanol (99.5 %) were warmed to liquefy the fat. After adding 0.44 parts by weight of CALB, the mixture was shaken at 50 °C for 10 min then at 30 °C for 2.8 h. The recovery of 2-MAG after the 3-h transesterification reaction was ca. 85 % of the maximum theoretical yield (33 mol%), with the loss of 15 % attributable to the acyl migration from sn-2 to sn-1(3). The recovery was similar to that of the solvent-free alcoholysis of structured lipids, 1,3-dipalmitoyl, 2-oleoyl glycerol and 1,3-dioleoyl, 2-palmitoyl glycerol, conducted at 30 °C for 3 h. In contrast, the acyl migration from sn-1(3) to sn-2 was hardly observed. Because the detected acyl migration was only in the direction of sn-2 to sn-1(3), and not vice versa, it is proposed to determine the FA composition of the sn-2 position of TAG by the gas chromatographic analysis of 2-MAG fraction recovered from the enzymatic reaction mixture, and the FA composition of sn-1(3) position by a mass balance using the FA composition of TAG and of the sn-2 position as inputs. The procedure was successfully applied to palm oil and shea butter, and docosahexaenoic acid (DHA)-rich single cell oil from Aurantiochytrium sp. KH105 for the first time. 相似文献
To improve the performance of embedded processors, an effective technique is collapsing critical computation subgraphs as
application-specific instruction set extensions and executing them on custom functional units. The problem with this approach
is the immense cost and the long times required to design a new processor for each application. As a solution to this issue,
we propose an adaptive extensible processor in which custom instructions (CIs) are generated and added after chip-fabrication.
To support this feature, custom functional units are replaced by a reconfigurable matrix of functional units (FUs). A systematic
quantitative approach is used for determining the appropriate structure of the reconfigurable functional unit (RFU). We also
introduce an integrated framework for generating mappable CIs on the RFU. Using this architecture, performance is improved
by up to 1.33, with an average improvement of 1.16, compared to a 4-issue in-order RISC processor. By partitioning the configuration
memory, detecting similar/subset CIs and merging small CIs, the size of the configuration memory is reduced by 40%. 相似文献
In the present study we attempt to induce a quadruped robot to walk dynamically on irregular terrain and run on flat terrain by using a nervous system model. For dynamic walking on irregular terrain, we employ a control system involving a neural oscillator network, a stretch reflex and a flexor reflex. Stable dynamic walking when obstructions to swinging legs are present is made possible by the flexor reflex and the crossed extension reflex. A modification of the single driving input to the neural oscillator network makes it possible for the robot to walk up a step. For running on flat terrain, we combine a spring mechanism and the neural oscillator network. It became clear in this study that the matching of two oscillations by the spring-mass system and the neural oscillator network is important in order to keep jumping in a pronk gait. The present study also shows that entrainment between neural oscillators causes the running gait to change from pronk to bound. This finding renders running fairly easy to attain in a bound gait. It must be noticed that the flexible and robust dynamic walking on irregular terrain and the transition of the running gait are realized by the modification of a few parameters in the neural oscillator network. 相似文献
This paper describes a new type of self-organizing map (SOM) with twin units as opposed to the single unit type conventional SOM proposed by Kohonen. The present self-organizing map with twin units (TW-SOM) can describe a nonlinear input-output relation with high accuracy. It is applied to voice conversion problem from bone conduction voice to air conduction voice (nonlinear code vector mapping), and its superiority over the conventional method using Linde-Buzo-Gray (LBG) algorithm is discussed. The tone quality of the converted voice is examined not only from the quantization distortion viewpoint, but also from the auditory sensation viewpoint through actual listening tests. The enhancement of the tone quality was experimentally confirmed. 相似文献
This paper describes external reference management and distributed unification in a distributed implementation of a concurrent logic programming language KL1. This implementation is based on the KLIC system. KLIC has a feature calledgeneric objects that enable easy modification and extension of the system without changes in the core implementation. This distributed implementation is built upon the same core and external references are represented using generic objects. Unification operations are defined as methods of generic objects. Since creation of interprocessor reference loops cannot be avoided, we studied a new unification scheme that can cope with interprocessor reference loops. We built several experimental distributed systems that all demonstrate reasonable efficiency. 相似文献
Recent research in CAD systems has been conducted to realize intelligent processing. Several CAD systems and product modelling systems have been developed using AI techniques. However, in order to develop more intelligent CAD systems, the design logic which connects the functional requirement to the geometric and the technological information of the designed product must be evaluated.
A product model used in such intelligent CAD systems has to include not only the geometric and the technological information of the product but also the designer's thought process which explains the design logic.
Design logic is generally divided into two parts. One is the generalized design logic which is commonly used in the conceptual design of mechanical products. The other is the product specified design logic which is used in the fundamental and detailed design phase. Different logic is applied to each product. This type of design logic is often used in modification design and compilation design, where the dimensions of parts have to be modified according to different functional requirements. When the dimensions and accuracies of the products are defined in connection with the functional requirements through design logic, the CAD system can automatically make decisions according to the given requirements. In this paper, suitable presentation formats and processing functions for these two types of design logic are discussed.
The importance of design logic in product modelling is proven through several case studies in this paper. As a conclusion, the intelligent product modelling system is developed, which should expedite the progress of design automation in the near future. In conceptual design, the design logic is processed in the modelling system and the product structure, with the technological information decided automatically from the functional requirement. Automation in the detailed design phase is also facilitated by the modelling system using the product specified design logic in the product model. 相似文献