球形吸附剂间歇吸附的新近似模型

引　言间歇吸附是一非稳态过程 ,用线性等温吸附扩散方程的解析解来描述单个吸附剂的非稳态吸附过程过于复杂[1～ 3] ,许多学者试图用多项式函数模拟吸附剂中随时间变化的吸附质浓度分布侧形 .Ｌｉａｗ等[4 ] 首次将球形吸附剂颗粒中吸附质浓度分布侧形用二次函数近似后 ,Ｄｏ和Ｒｉｃｅ[1,5] 用二次多项式函数和四次多项式函数的近似解与解析解做了对比 ,随后又提出了较为理想的ｎ次二项式近似模型[6 ] ,修国华等[7] 对ｎ次二项式近似又做了进一步的改进 .这些近似计算模型在Ｂｉｏｔ数不很大时 ,除在初始阶段有较大正误差以外 ,其余部分都…     

30t大轴重机车转向架轴箱体的设计

介绍了30t大轴重机车转向架轴箱体的设计,分析了轴箱体各部分结构功能特点。依据UIC615-4为载荷标准,确定了在计算分析时的载荷,并利用ANSYS Workbench计算了轴箱体静强度,用Goodman图校核了疲劳强度,计算分析结果表明,轴箱体的静强度及疲劳强度均满足要求。     

基于智能高分子材料的灵敏检测技术研究进展

近年来,将智能高分子材料识别响应的微小刺激信号转化并放大为方便人们读取的信号检测技术成为研究热点。本工作综述了近年来基于智能高分子材料的灵敏检测技术的研究进展,重点介绍了将智能高分子材料识别响应刺激信号转化为电信号、流量信号和光信号的检测技术。最后讨论了基于智能高分子材料的灵敏检测技术应用时需解决的关键问题,为基于智能高分子材料的灵敏检测技术的设计与应用提供了有价值的参考。     

Acceleration of kinetic monte carlo simulations of free radical copolymerization: A hybrid approach with scaling

Kinetic Monte Carlo (KMC) has been widely used in the simulation of polymeric reactions. The power of KMC is highlighted by its ability to keep track of the length and sequence of every radical or polymer chain, while it is computationally more expensive than deterministic kinetic models. This paper introduces an acceleration method that significantly reduces the computational cost of KMC simulations, while keeping the same features as the full kinetic Monte Carlo simulations. Case studies are used to demonstrate the general applicability of this method to free radical copolymerization. © 2017 American Institute of Chemical Engineers AIChE J, 63: 4013–4021, 2017     

纳米铝粉的固相化学还原法制备、表征及对ADN热分解性能的影响

以山梨糖醇酐三油酸酯(Span-85)作为过程控制剂,通过氢化铝锂还原无水氯化铝,采用高能机械球磨法制备了纳米铝粉(n-Al)。利用扫描电镜(SEM)、高分辨率透射电镜(TEM)、X射线衍射(XRD)仪、傅里叶变换红外光谱(FTIR)仪及X射线光电子能谱(XPS)仪对其形貌和结构进行了表征。用差示扫描量热仪(DSC)对ADN(二硝酰胺铵)、n-Al/ADN的热分解反应特性进行了研究。结果表明:纳米铝粉属立方晶系,表面包覆有无定型Al2O3氧化物及部分表面活性剂Span-85,同时制备的纳米铝粉试样中含少量Al Cl3·6H2O杂质;此方法制备的n-Al粒子对ADN液化温度几乎没有影响,但放热分解温度明显增大,且ADN分解由多重峰变为单一的尖峰。     

MODIFIED BOTTLENECK-BASED PROCEDURE FOR LARGE-SCALE FLOW-SHOP SCHEDULING PROBLEMS WITH BOTTLENECK

A new bottleneck-based heuristic for large-scale flow-shop scheduling problems with a bottleneck is proposed, which is simpler but more tailored than the shifting bottleneck (SB) procedure. In this algorithm, a schedule for the bottleneck machine is first constructed optimally and then the non-bottleneck machines are scheduled around the bottleneck schedule by some effective dispatching rules. Computational results show that the modified bottleneck-based procedure can achieve a tradeoff between solution quality and computational time comparing with SB procedure for medium-size problems. Furthermore it can obtain a good solution in quite short time for large-scale scheduling problems.     

滑动窗快速横向滤波的自适应判决反馈均衡器算法

本文提出了一种基于滑动窗广义多路快速横向滤波（ＳＷＦＴＦ）的自适应判决反馈均衡器（ＤＦＦ）算法，它具有快速跟踪性能，故可用于快速时变多径衰落的信道。文中推导了ＳＷＦＴＦ－ＤＦＥ算法。在数字移动通信信道模型上，利用计算机模拟，在均方误差和误码率特性方面与其它均衡器算法进行了比较。     

X频段高频谱纯度频率合成器设计

针对高灵敏度接收机对频率合成器的高技术指标要求,构建了一种融合了直接模拟、直接数字以及间接数字的频率合成技术方案,根据该方案,成功实现了频率合成器的工程研制。通过测试,频率合成器相位噪声达-112 dBc/Hz@5 kHz,杂散抑制优于-75 dBc,频率分辨率小于1 kHz,10 MHz跳频时间约为13 μs,满足了高灵敏度接收机对频率合成器的高技术指标要求,为高纯度频率合成器的实现提供了一条新途径。     

太赫兹脉冲大气传输衰减特性

太赫兹大气传输是太赫兹科学技术及其应用的重要组成部分,渗透于所有的太赫兹应用技术领域。研究基于辐射传输、色散理论和Van-Vleck Weisskopf线型,结合喷气推进实验室(JPL)数据库,建立了太赫兹脉冲大气传输衰减与色散模型,对0.1 THz~1 THz频段太赫兹辐射在水汽中的吸收衰减特性进行了数值模拟研究,与现有的文献数据进行了比对。通过计算太赫兹脉冲大气传输,分析不同水汽密度和传输距离对波形幅值、相位及频谱特性的影响,得到了3个比较稳定的太赫兹脉冲大气传输窗口0.14 THz~0.17 THz、0.19 THz~0.32 THz和0.32 THz~0.37 THz,为太赫兹通信和时域太赫兹空间传输提供了理论参考。     

Method for altering deformational characteristics of controlled-clearance piston-cylinders

A new controlled-clearance pressure balance has been developed to improve the hydraulic pressure standard for pressures up to 1 GPa. For several controlled-clearance (CC) piston-cylinders, characterization experiments based on the Heydemann-Welch (H-W) model were performed to estimate the pressure dependence of the effective area. The results of the experiments, specifically, the changes in the piston fall-rate and the generated pressure in response to the applied jacket pressure, are summarized for CC piston-cylinders of different pressure ranges. At pressures higher than a few hundred MPa, the characteristics of some piston-cylinders differed from those predicted by the H-W model. In this paper, a method for altering the deformational characteristics of CC piston-cylinders is examined. It was found that adjusting the area of the outer surface of the cylinder to which the jacket pressure is applied is an effective method for obtaining deformational characteristics that satisfy the conditions of the H-W model.