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101.
Kenta Aizawa Hiroki Takagi Eri Kokubo Masayasu Takada 《Journal of Applied Glycoscience》2021,68(3):53
Carbohydrate materials that produce lower postprandial blood glucose increase are required for diabetic patients. To develop slowly digestible carbohydrates, the effect of degree of polymerization (DP) of α-1,6 glucan on its digestibility was investigated in vitro and in vivo. We prepared four fractions of α-1,6 glucan composed primarily of DP 3–9, DP 10–30, DP 31–150, and DP 151+ by fractionating a dextran hydrolysate. An in vitro experiment using digestive enzymes showed that the glucose productions of DP 3–9, DP 10–30, DP 31–150, and DP 151+ were 70.3, 53.4, 28.2, and 19.2 % in 2 h, and 92.1, 83.9, 39.6, and 33.3 % in 24 h relative to dextrin, respectively. An in vivo glycemic response showed that the incremental area under the curve (iAUC) of blood glucose levels of α-1,6 glucan with DP 3–9, DP 10–30, DP 31–150, and DP 151+ were 99.5, 84.3, 65.4, and 40.1 % relative to dextrin, respectively. These results indicated that α-1,6 glucan with higher DP had stronger resistance to digestion and produced a smaller blood glucose response. DP 10–30 showed significantly lower maximum blood glucose levels than dextrin; however, no significant difference was observed in iAUC, indicating that DP 10–30 was slowly digestible. In addition, α-1,6 glucan was also produced using an enzymatic reaction with dextrin dextranase (DDase). This produced similar results to DP 10–30. The DDase product can be synthesized from dextrin at low cost. This glucan is expected to be useful as a slowly digestible carbohydrate source. 相似文献
102.
On the damping analysis of FRP laminated composite plates 总被引:2,自引:0,他引:2
This paper presents the damping analysis of fiber reinforced plastics laminated composite plates. For this purpose, the maximum strain and kinetic energies of a cross-ply laminated plate are evaluated analytically based on the three-dimensional theory of elasticity. The displacements of the simply supported rectangular plates are expanded into the polynomial forms with respect to a thickness coordinate, and then governing equations are formulated by using the Ritz's method. In the numerical calculations, natural frequencies and modal damping ratios are calculated for the plates with different stacking sequence and thickness ratios. The validity of the assumption of deformations and the applicability of the other plate theories (e.g. classical lamination theory (CLT), first-order shear deformation theory (FSDT) and higher-order shear deformation theory) to the laminated thick plates are discussed by comparing the numerical results obtained by the present method with the CLT and the FSDT solutions. 相似文献
103.
The use of dendrimer templates to make metal-based nanoparticles of controlled size has attracted much interest. These highly branched macromolecules have well-defined structures that enable them to bind metal ions to generate precursors that can be converted into nanoparticles. We describe the sub-nanometre size control of both anatase and rutile forms of TiO2 particles with phenylazomethine dendrimers, leading to samples with very narrow size distributions. Such fine tuning is possible because both the number and location of metal ions can be precisely controlled in these templates. Quantum size effects are observed in the particles, and the energy gap between the conduction and valence bands exhibits a blueshift with decreasing particle size and is dependent on the crystal form of the material. The dependency of the bandgap energy on these factors is explained using a semi-empirical effective mass approximation. 相似文献
104.
105.
At the calibration of standard leaks by a comparison method with reference standard leaks, important factors to evaluate the flow rates are the degrees of stability of a mass spectrometer leak detector (MSLD) and standard leaks. Stability of two leak element type standard leaks, a glass and a plastic, are tested. The test indicates that the warming up time is mainly influenced by the temperature of the mass spectrometer and 2 h is required to obtain a stabilized reading for the tested MSLD. In case of the glass type leak, 1 h pumping is required to obtain the stabilized flow rate after the exposure to the ambient air. In case of the plastic type leak, 1 min pumping is enough for the exposure time below 1 h but 6 h pumping is required after the 7 days exposure. After the valve closed duration within 3 h, the flow rates from both type of leaks recovered within a minute to 100% ± 0.5% of the averaged reading before the valve closed. 相似文献
106.
Kenta Kachi Hiroyuki Kato Aya Naiki-Ito Masayuki Komura Aya Nagano-Matsuo Itaru Naitoh Kazuki Hayashi Hiromi Kataoka Shingo Inaguma Satoru Takahashi 《International journal of molecular sciences》2021,22(14)
Pancreatic cancer is a fatal disease, and thus its chemoprevention is an important issue. Based on the recent report that patients with allergic diseases have a low risk for pancreatic cancer, we examined the potential chemopreventive effect of anti-allergic agents using a hamster pancreatic carcinogenesis model. Among the three anti-allergic drugs administered, montelukast showed a tendency to suppress the incidence of pancreatic cancer. Further animal study revealed a significantly decreased incidence of pancreatic cancer in the high-dose montelukast group compared with controls. The development of the pancreatic intraepithelial neoplasia lesions was also significantly suppressed. The Ki-67 labeling index was significantly lower in pancreatic carcinomas in the high-dose montelukast group than in controls. In vitro experiments revealed that montelukast suppressed proliferation of pancreatic cancer cells in a dose-dependent manner with decreased expression of phospho-ERK1/2. Montelukast induced G1 phase arrest. Conversely, leukotriene D4 (LTD4), an agonist of CYSLTR1, increased cellular proliferation of pancreatic cancer cells with an accumulation of phospho-ERK1/2. In our cohort, pancreatic ductal adenocarcinoma patients with high CYSLTR1 expression showed a significantly unfavorable clinical outcome compared with those with low expression. Our results indicate that montelukast exerts a chemopreventive effect on pancreatic cancer via the LTD4–CYSLTR1 axis and has potential for treatment of pancreatic carcinogenesis. 相似文献
107.
Hiroaki Matsumoto Daiki Naito Kento Miyoshi Kenta Yamanaka Akihiko Chiba Yoko Yamabe-Mitarai 《Science and Technology of Advanced Materials》2013,14(1):893-904
AbstractThis work identifies microstructural conversion mechanisms during hot deformation (at temperatures ranging from 750 °C to 1050 °C and strain rates ranging from 10?3 s?1 to 1 s?1) of a Ti-5Al-2Sn-2Zr-4Mo-4Cr (Ti-17) alloy with a lamellar starting microstructure and establishes constitutive formulae for predicting the microstructural evolution using finite-element analysis. In the α phase, lamellae kinking is the dominant mode in the higher strain rate region and dynamic globularization frequently occurs at higher temperatures. In the β phase, continuous dynamic recrystallization is the dominant mode below the transition temperature, Tβ (880~890 °C). Dynamic recovery tends to be more active at conditions of lower strain rates and higher temperatures. At temperatures above Tβ, continuous dynamic recrystallization of the β phase frequently occurs, especially in the lower strain rate region. A set of constitutive equations modeling the microstructural evolution and processing map characteristic are established by optimizing the experimental data and were later implemented in the DEFORM-3D software package. There is a satisfactory agreement between the experimental and simulated results, indicating that the established series of constitutive models can be used to reliably predict the properties of a Ti-17 alloy after forging in the (α+β) region. 相似文献
108.
Satoshi Wada Kenta Yamashita Ichiro Fujii Kouichi Nakashima Nobuhiro Kumada Chikako Moriyoshi Yoshihiro Kuroiwa 《Ceramics International》2013
Barium titanate (BaTiO3, BT)–potassium niobate (KNbO3, KN) (BT–KN) nanocomplex ceramics with various KN/BT molar ratios were prepared by the solvothermal method. From a transmittance electron microscopy (TEM) observation, it was confirmed that KN layer thickness of the BT–KN nanocomplex ceramics was controlled from 0 to 44 nm by controlling KN/BT molar ratios. Their dielectric constants were measured at room temperature and 1 MHz, and a maximum dielectric constant of around 400 was measured for the BT–KN nanocomplex ceramics with a KN thickness of 22 nm. TEM observation revealed that below KN thickness of 22 nm, BT/KN heteroepitaxial interface was assigned to the strained interface while over 22 nm, the interface was assigned to the relaxed one. These results suggested that the strained heteroepitaxial interface could be responsible for the enhanced dielectric constants. 相似文献
109.
Structures of acetylated residual lignin obtained from unbleached beech kraft pulp were investigated by 2D NMR in combination with selective cleavage of non-phenolic α-alkyl ether bonds with pivaloyl iodide generated in situ from pivaloyl chloride / sodium iodide. β-O-4 and resinol structures still remained in this polymer lignin. Furthermore, carbohydrates were proved to be linked glycosidically to benzyl carbons of lignin. Possibly this inhibits complete delignification during kraft pulping. 相似文献
110.
Sensitization by chromium depletion due to chromium carbide precipitation at grain boundaries in austenitic stainless steels can not be prevented perfectly only by previous conventional techniques, such as reduction of carbon content, stabilization-treatment, local solution-heat-treatment, etc. Recent studies on grain boundary structure have revealed that the sensitization depends strongly on grain boundary character and atomic structure, and that low energy grain boundaries such a~ coincidence-site-lattice (CSL) boundaries have strong resistance to intergranular corrosion. The concept of grain boundary design and control has been developed as grain boundary engineering (GBE). GBEed materials are characterized by high frequencies of CSL boundaries which are resistant to intergranular deterioration of materials, such as intergranular corrosion. A thermomechanical treatment was tried to improve the resistance to the sensitization by GBE. A type 304 austenitic stainless steel was cold-rolled and solution-heat-treated, and then sensitization-heat-treated. The grain boundary character distribution was examined by orientation imaging microscopy (OIM). The intergranular corrosion resistance was evaluated by electrochemical potentiokinetic reactivation (EPR) and ferric sulfate-sulfuric acid tests. The sensitivity to intergranular corrosion was reduced by the thermomechanical treatment and indicated a minimum at a small roll-reduction The frequency of CSL boundaries indicated a maximum at the small reduction. The ferric sulfate-sulfuric acid test showed much smaller corrosion rate in the thermomechanical-treated specimen than in the base material. A high density of annealing twins were observed in the thermomechanical-treated specimen. The results suggdst that the therrmomechanical treatment can introduce low energy segments in the grain boundary network by annealing twins and can arrest the percolation of intergranular corrosion from the surface. The effects of carbon content and other minor elements on optimization in grain boundary character distribution (GBCD) and thermomechanical parameters were also examined during GBE. 相似文献