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21.
Land surface temperature (LST) is a key parameter in numerous environmental studies. Surface heterogeneity induces uncertainty in pixel-wise LST. Spatial scaling may account for the uncertainty, however, different approaches lead to differences in scaled values. Satellite-retrieved LST may be representative of the pixel-wise LST and useful for scaling analysis, but the limited accuracy of retrieved values adds uncertainty into the scaled values. Based on the Stefan-Boltzmann (S-B) law, this study proposed scaling approaches for LST over flat and relief areas to explore the combined uncertainties in scaling using satellite-retrieved data. To take advantage of simultaneous, multi-resolution observations at coincident nadirs by the Advanced Spaceborne Thermal Emission Reflection Radiometer (ASTER) and the MODerate-resolution Imaging Spectroradiometer (MODIS), LST products from these two sensors were examined for part of the Loess Plateau in China. 90-m ASTER LST data were scaled up to 1 km using the proposed approaches, and variation in the LST was generally reduced after scaling. Amongst the sources of uncertainties, surface heterogeneity (emissivity) and different scaling approaches resulted in very minor differences, with a maximum difference of 0.2 K for the upscaled LST. Terrain features, taken as an areal weighting factor, had negligible effects on the upscaled value. Limited accuracy of the retrieved LST was the major uncertainty. The overall LST increased 0.6 K on average with correction for terrain-induced angular effect and 0.4 K for both angular and adjacency effects over the study area. Accounting for terrain correction in scaling is necessary for rugged areas. With terrain correction, the upscaled ASTER LST achieved an agreement of − 0.1 ± 1.87 K and a root mean square error (RMSE) of 1.87 K overall with the 1-km MODIS LST rectified by Wan et al.'s approach [Wan, Z., Zhang, Y., Zhang Q., Li, Z.-L. (2002b), Validation of the land-surface temperature products retrieved from Terra Moderate Resolution Imaging Spectroradiometer data. Remote Sensing of Environment, 83, 163-180]. Refining the rectification approach resulted in a better agreement of − 0.2 ± 1.57 K and a RMSE of 1.58 K.  相似文献   
22.
Metallurgical and Materials Transactions A - Microstructural changes were observed during the plastic deformation of ASTM F90 Co-20Cr-15W-10Ni (mass pct) alloy heat-treated at...  相似文献   
23.
Abstract

We present our ab initio molecular dynamics (MD) study of the effect of Si on the oxidation of α-Ti(0?0?0?1) surfaces. We varied the Si concentration in the first layer of the surface from 0 to 25 at.% and the oxygen coverage (θ) on the surface was varied up to 1 monolayer (ML). The MD was performed at 300, 600 and 973 K. For θ = 0.5 ML, oxygen penetration into the slab was not observed after 16 ps of MD at 973 K while for θ > 0.5 ML, oxygen penetration into the Ti slab was observed even at 300 K. From Bader charge analysis, we confirmed the formation of the oxide layer on the surface of the Ti slab. At higher temperatures, the Si atoms diffused from the first layer to the interior of the slab, while the Ti atoms moved from second layer to the first layer. The pair correlation function shows the formation of a disordered Ti-O network during the initial stage of oxidation. Si was found to have a strong influence on the penetration of oxygen in the Ti slab at high temperatures.  相似文献   
24.
Hydrogen is a clean alternative to conventional hydrocarbon fuels, but it is very important to reduce the nitrogen oxides (NOx) emissions generated by hydrogen combustion. The rich-lean combustion or staged combustion is known to reduce NOx emissions from continuous combustion burners such as gas turbines and boilers, and NOx reduction effects have been demonstrated for hydrocarbon fuels. The authors applied rich-lean combustion to a hydrogen gas turbine and showed its NOx reduction effect in previous research. The present study focused on experimental measurements of NO and NO2 emissions from a coaxial rich-lean burner fueled with hydrogen. The results were compared with diffusion combustion and methane rich-lean combustion. Significant reductions in NO and NO2 were achieved with rich-lean combustion. The NO and NO2 reduction effects by rich-lean combustion relative to conventional diffusion combustion were higher with hydrogen than with methane.  相似文献   
25.
The thermoelectric properties of ternary and Al-containing quaternary Ru1?xRexSiy chimney–ladder phases have been studied as a function of the Re concentration with the use of directionally solidified alloys. The Ru1?xRexSiy chimney–ladder phases exhibit n- and p-type semiconducting behaviors, respectively, at low and high Re concentrations, at which the X(=Si)/M(=Ru + Re) ratios are respectively, larger and smaller than those expected from the VEC (valence electron concentration) = 14 rule. The absolute values of both Seebeck coefficient and electrical resistivity increase as the extent of the deviation from the VEC = 14 rule increases, i.e. as the alloy composition deviates from that corresponding to the p–n transition (x  0.5), indicating that the carrier concentration can be controlled by changing the extent of compositional deviation from the ideal VEC = 14 composition. The highest values of the dimensionless figure of merit obtained are 0.47 for ternary (x = 0.60) and 0.56 for Al-containing quaternary alloys. The reasons for the systematic compositional deviation from the ideal VEC = 14 compositions observed for a series of chimney–ladder phases are discussed in terms of atomic packing.  相似文献   
26.
The integration of three-dimensional spatial distributions into building simulations is of significant interest, and computational fluid dynamics (CFD) analysis is widely employed in building design processes. For example, based on the experience of architects and engineers, CFD analyses are often conducted under steady boundary conditions to determine the degree of attainment of indoor environments. However, CFD analyses have large calculation costs and cannot be often used for simulations with unsteady boundary conditions such as energy simulations in the building design processes. Thus, we developed a method that calculates sensitivities from heat sources to an arbitrary point in an indoor environment and integrates them into simulations with unsteady boundary conditions. In the proposed method, CFD analysis is employed under steady boundary conditions to calculate the response factors, and the resulting sensitivities are integrated into simulations under unsteady boundary conditions. In the present study, the proposed method was applied to optimize the variables of an air conditioning control system. With our method, temperature changes at a sensor over time are calculated from the time series of air supply temperature. In total, 800 calculations were conducted, and the optimal variables that allow the temperature at the sensor to reach the target value quickly were obtained. Except for the time required to calculate the response factors, the optimization in the present study took only a few seconds. If only CFD analysis was used for the optimization, the calculations would take a year. Thus, calculating the sensitivities via CFD analysis and utilizing the results in simulations is a useful approach for solving optimization problems. Moreover, the proposed method is applicable to simulations that require three-dimensional spatial distributions to enhance the accuracy of the calculation such as energy simulations.  相似文献   
27.
To investigate the possibility of further lowering the clearance in head?Cdisk interface systems, slider dynamic behavior during a touchdown sequence with a thermal flying-height control (TFC) function was investigated by using a spinstand-level evaluation utilizing an acoustic emission (AE) sensor and a laser Doppler vibrometer (LDV). Experimental results demonstrated that off-track vibration was easier to excite by head?Cdisk contact at the beginning of head?Cdisk contact. We then confirmed that the amplitude of pitch-mode vibration in the flying-height direction increased and sway-mode vibration in the off-track direction decreased when increasing heater power during the touchdown sequence. Moreover, we found that the peak frequency of pitch-mode vibration shifted to a higher frequency under over-push conditions. Time?Cfrequency domain analysis results showed that the peak shift occurred at several locations during a disk rotation. The mechanism of the peak shift is attributed to the increase in stiffness at the head?Cdisk interface (HDI) due to solid?Csolid contact or mode change occurred in such regions. During the touchdown sequence, the friction force at the HDI continues to increase, even though slider vibration and AE signal decrease when heater power is increased. The friction force at the HDI needs to be decreased to achieve further low-clearance HDI.  相似文献   
28.
A new method was proposed to measure the thermal conductivity of liquids with infinitesimal samples, which are much smaller than those required in conventional methods. The method utilizes a micro-beam-type MEMS sensor fabricated across a trench on a silicon substrate. Numerical analysis of heat conduction within and around a uniformly heated sensor showed that the temperature of a 10 μm long sensor reached a steady state within approximately 0.1ms, after the start of heating. It was also revealed that the average temperature of the sensor at the steady state was higher in liquids with lower thermal conductivity. These results demonstrate a new idea of measuring the thermal conductivity of liquids within an extremely short time at a steady state before the onset of natural convection.  相似文献   
29.
30.
Octanoyl, dodecanoyl and hexadecanoyl ascorbates were synthesized by the condensation of ascorbic acid and the corresponding fatty acids in acetone using an immobilized lipase from Candida antarctica. The oxidation process of methyl linoleate (ML) as an oil droplet in the ML/W emulsion with ascorbic acid or acyl ascorbate was measured at 40 °C, and their antioxidative properties were examined. Hydrophilic proxidant, AAPH, or lipophilic proxidant, AMVN, was added to the water or oil phase to investigate the properties, and the kinetic parameters for the oxidation expressed by the Weibull equation were evaluated. It was suggested that most of the ascorbic acid molecules in the emulsion would be present in the water phase due to its high hydrophilicity and suppress the AAPH-induced oxidation on the interface between the water and oil phases. Dodecanoyl and hexadecanoyl ascorbates would be dissolved in the oil phase and contribute to the suppression of the oxidation in the oil phase rather than on the interface. Octanoyl ascorbate with a HLB number of 11.8 would be in both phases. Regardless of the presence and type of the ascorbate, the rate constant, k, of the Weibull equation decreased as the pH of the water phase increased.  相似文献   
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