Synthesis and characterization of novel blue azo‐dye derivatives containing acrylate group for dye‐based color filters

Abstract— Even though dyes have a fine resolution and good chromaticities, they are not widely used as coloring materials for color filters (CFs) due to their low thermal stability and chemical resistance. A series of azo‐dye derivatives, which consist of two cross‐linkable acrylate or methacrylate groups to improve thermal and chemical properties, have been synthesized and used to fabricate color filters. The spectral properties and chemical/thermal stabilities of the fabricated CFs were investigated by comparing dye‐based CFs, without a complicated dispersion process, but with pigment‐based CFs using dispersed pigment. Also, more properties including the development test and surface morphologies lithographic properties were studied. The synthesized azo dyes were characterized by elemental analysis, UV‐visible spectra, IR, mass, and ¹H‐NMR spectra.     

Analysis of pressure-driven electrokinetic flows in hydrophobic microchannels with slip-dependent zeta potential

The present study is an analysis of pressure-driven electrokinetic flows in hydrophobic microchannels with emphasis on the slip effects under coupling of interfacial electric and fluid slippage phenomena. Commonly used linear model with slip-independent zeta potential and the nonlinear model at limiting (high-K) condition with slip-dependent zeta potential are solved analytically. Then, numerical solutions of the electrokinetic flow model with zeta potential varying with slip length are analyzed. Different from the general notion of “the more hydrophobic the channel wall, the higher the flowrate,” the results with slip-independent and slip-dependent zeta potentials both disclose that flowrate becomes insensitive to the wall hydrophobicity or fluid slippage at sufficiently large slip lengths. Boundary slip not only assists fluid motion but also enhances counter-ions transport in EDL and, thus, results in strong streaming potential as well as electrokinetic retardation. With slip-dependent zeta potential considered, flowrate varies non-monotonically with increasing slip length due to competition of the favorable and adverse effects with more complicated interactions. The influence of the slip on the electrokinetic flow is eventually nullified at large slip lengths for balance of the counter effects, and the flowrate becomes insensitive to further hydrophobicity of the microchannel. The occurrence of maximum, minimum, and insensitivity on the flowrate-slip curves can be premature at a higher zeta potential and/or larger electrokinetic separation distance.     

The role of goal awareness and information technology self-efficacy on job satisfaction of healthcare system users

This paper investigates the influence of goal awareness and IT self-efficacy on job satisfaction based on the motivation sequence model, goal-setting theory, and social cognitive theory. Using a large-scale field survey of healthcare enterprise resource planning (ERP) system users (n?=?352), this study investigates these relationships and provides important insight to healthcare ERP system researchers and managers. Both goal awareness and IT self-efficacy influence positive job satisfaction of healthcare ERP system users, as expected. Furthermore, the influence of goal awareness is stronger when the role of ERP systems is highly perceived for decision-making of the job. There was no interaction effect between goal awareness and IT self-efficacy in the post hoc analysis. The model is significantly supported by the empirical test with the large number of field data from healthcare ERP system users in the healthcare company. Practical and academic implications are discussed in the paper.     

Internet-Based Smart-Space Navigation of a Car-Like Wheeled Robot Using Fuzzy-Neural Adaptive Control

In this paper, a navigation system is developed. The system includes path tracking and obstacle avoidance apparatus for a car-like wheeled robot (CLWR) within an Internet-based smart-space (IBSS) using fuzzy-neural adaptive control (FNAC). Two distributed charge-coupled device (CCD) cameras are installed to capture both the dynamic pose of the CLWR and the obstacle. Based on the control authority of these two CCD cameras, a suitable reference command that contains the desired steering angle and angular velocity for the FNAC built into the client computer is planned. Because of the delay encountered by the transmission through the Internet network (IN) and the wireless local area network (WLAN) and the nonlinear coupling features of the CLWR, a weighted combination of $N$ linear subsystems that are described by a state-space model with average-delay is implemented to approximate the dynamics of an IBSS-CLWR. The proposed FNAC contains a neural network consisting of a radial basis function (RBFNN) to learn the uncertainties due to the fuzzy-model error (e.g., the random time-varying delays and the slippage of the CLWR) and the interactions caused by other subsystems. The stability of the overall system is then investigated by adopting the Lyapunov stability theory. Finally, a sequence of experiments including the control of the off-ground CLWR (i.e., the CLWR does not make contact with the ground) and the navigation of the IBSS-CLWR as compared with the conventional proportional-integral-derivative (PID) control is performed to demonstrate the advantage of the proposed control system.      

Dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing

The dynamic deformation behavior of ultrafine-grained low-carbon steels fabricated by equal-channel angular pressing (ECAP) was investigated in this study. Dynamic torsional tests, using a torsional Kolsky bar, were conducted on four steel specimens, two of which were annealed at 480 °C after ECAP, and then the test data were compared in terms of microstructures, tensile properties, and adiabatic shear-band formation. The equal-channel angular pressed specimen consisted of very fine, equiaxed grains of 0.2 to 0.3 μm in size, which were slightly coarsened after annealing. The dynamic torsional test results indicated that maximum shear stress decreased with increasing annealing time, whereas fracture shear strain increased. Some adiabatic shear bands were observed at the gage center of the dynamically deformed torsional specimen. Their width was smaller in the equal-channel angular pressed specimen than in the 1-hour-annealed specimen, but they were not found in the 24-hour-annealed specimen. Ultrafine, equiaxed grains of 0.05 to 0.2 μm in size were formed inside the adiabatic shear band, and their boundaries had characteristics of high-angle grain boundaries. These phenomena were explained by dynamic recrystallization due to a highly localized plastic strain and temperature rise during dynamic deformation.     

Effect of Hot Band Annealing on Magnetic Properties in 3% Si Grain‐oriented Electrical Steels

Hot band annealing is known to be a prerequisite for good magnetic properties irrespective of manufacturing methods in grain‐oriented Fe‐3 wt.% Si electrical steels. In this study, the effects of hot band annealing on magnetic properties were investigated in 3% grain‐oriented electrical steels of low soluble AI contents and one‐stage cold rolling. Microstructure and precipitate distribution were compared with hot band annealing conditions. Secondary recrystallization behaviour with hot band annealing condition was also discussed.     

Context Switching in a Run-Time Reconfigurable System

A distinguishing feature of reconfigurable computing over rapid prototyping is its ability to configure the computational fabric on-line while an application is running. Conventional reconfigurable computing platforms utilize commodity FPGAs, which typically have relatively long configuration times. Shrinking the configuration time down to the nanosecond region opens possibilities for rapid context switching and virtualizing the computational resources. An experimental context-switching FPGA, called the CSRC, has been created by BAE Systems, and gives researchers the opportunity to explore context-switching applications. This paper presents results obtained from constructing both control-driven and data-driven context switching applications on the CSRC device, along with unique properties of the run-time and compile-time environment.     

Shear horizontal wave transduction in plates by magnetostrictive gratings

Shear horizontal waves are very useful in nondestructive evaluation applications because of their non-dispersive property. The objective of this research is to investigate frequency-tuned shear horizontal wave transduction in plates by using magnetostrictive nickel gratings. Since wireless energy conversion between magnetic energy and acoustic energy in magnetostrictive material can take place, the generation and measurement of waves by the magnetostrictive principle have recently received much attention. In this work, a grating-type magnetostrictive transducer was considered for SH wave transduction; waves can be effectively tuned at desired frequencies by changing grating size and distance. The present experiments showed that the bias field strength and grating width should be selected appropriately to avoid generating unwanted wave modes such as the S0-Lamb wave modes. It is also confirmed from experiments that the grating distance controls the center (or tuning) frequency of the grating transducer.