TiO2悬浮液光电流响应的影响因素

利用电化学分析仪对TiO2悬浮液在紫外光照射下产生的光电流进行了收集测试.具体研究了悬浮液浓度、辅助添加剂加入与否等测试条件对TiO2悬浮液光电流的影响.试验表明,随着TiO2悬浮液浓度的增加光电流达到一定的峰值,而分散剂的加入是提高光电流响应值的关键因素.光电流测试是用来表征TiO2悬浮液分散性能及光催化反应能力的有效手段之一.     

2—甲基—1，4—萘醌对DNA光敏损伤的诱导作用

选择波长337nm的激光作为激励光源，借助凝胶电泳研究了2－甲基－1，4－萘醌诱导的DNA光敏损伤。结果表明：在氧气饱和、脱氧条件下光敏损伤显著，DNA损伤主要与光子剂量、核酸与萘醌浓度比及DNA存在形式有关。     

适应不同温度的几种钛熔块的研究

用TiO2作乳浊剂通过调节各种熔剂的用量制得了适用于各种不同温度的钛熔块釉。     

新颖除草剂研究进展

综述了新型除草剂研制的方向、重点和特点。涉及磺酰脲类除草剂 ,环状亚胺类除草剂 ,苯氧羧酸类除草剂 ,有机磷类除草剂。主要介绍了具有除草活性好的丙酮酸脱氢酶抑制剂研究新进展。     

Parallel matrix factorization for recommender systems

Matrix factorization, when the matrix has missing values, has become one of the leading techniques for recommender systems. To handle web-scale datasets with millions of users and billions of ratings, scalability becomes an important issue. Alternating least squares (ALS) and stochastic gradient descent (SGD) are two popular approaches to compute matrix factorization, and there has been a recent flurry of activity to parallelize these algorithms. However, due to the cubic time complexity in the target rank, ALS is not scalable to large-scale datasets. On the other hand, SGD conducts efficient updates but usually suffers from slow convergence that is sensitive to the parameters. Coordinate descent, a classical optimization approach, has been used for many other large-scale problems, but its application to matrix factorization for recommender systems has not been thoroughly explored. In this paper, we show that coordinate descent-based methods have a more efficient update rule compared to ALS and have faster and more stable convergence than SGD. We study different update sequences and propose the CCD++ algorithm, which updates rank-one factors one by one. In addition, CCD++ can be easily parallelized on both multi-core and distributed systems. We empirically show that CCD++ is much faster than ALS and SGD in both settings. As an example, with a synthetic dataset containing 14.6 billion ratings, on a distributed memory cluster with 64 processors, to deliver the desired test RMSE, CCD++ is 49 times faster than SGD and 20 times faster than ALS. When the number of processors is increased to 256, CCD++ takes only 16 s and is still 40 times faster than SGD and 20 times faster than ALS.     

液体消毒洗涤剂的研制

研制了具有消毒杀菌、洗涤去污双重功效的液体消毒洗涤剂 ,测定了其对金黄色葡萄球菌的杀灭效果。结果表明 ,消毒洗涤剂的杀菌效果随其浓度的增加 ,作用时间的延长而提高 ;戊二醛浓度为 2 0 0× 10 -6时 ,与金黄色葡萄球菌作用 5min ,杀灭率可达 99.99%。将消毒洗涤剂在室温下放置半年 ,戊二醛分解率为 17.3 1%     

感光化学中的近代研究方法

主要介绍了近 2 0年来电子显微技术、波谱技术、核磁共振技术、微波光导测试技术和离子电导测试技术等在卤化银晶体和潜影生成过程研究中的应用。     

Thermal and thermomechanical properties of poly(ethylene oxide) networks produced with silica and organic crosslinking agents

The thermal and thermomechanical properties of two series of poly(ethylene oxide) networks (NPEOs) were investigated as a function of the chain length between crosslink sites (M_c) and the concentration of LiClO₄ (C_L) in the NPEOs. The two series of networks were produced with silica and organic crosslinking agents and, therefore, had crosslink sites of different natures: one was an inorganic silicate network (silica NPEO), and the other was an organic polar group (organic NPEO). The crosslink sites in both series of networks were commonly covalently bonded to the poly(ethylene oxide) (PEO) phase through a urethane group in the NPEOs. The glass‐transition temperatures (T_g's) of the PEO phases in the NPEOs, according to differential scanning calorimetry, increased with a decrease in M_c and were higher in the silica NPEOs than in the organic NPEOs under the same M_c conditions. The difference in T_g between the two series of networks with the same M_c values increased with decreasing M_c. These results suggested that the interaction of crosslink sites with the PEO phase was stronger in the silica NPEOs than in the organic NPEOs. The addition of LiClO₄ to the NPEOs resulted in T_g of the PEO phase in the NPEOs being elevated and increased according to the increase in C_L. The increase of T_g of the PEO phase according to the increase of C_L in the NPEOs was retarded or saturated at high values of C_L, and this indicated that the limit of solubility of the salt in the polymer was attained. The retardation or saturation of the increase of T_g was also observed in dynamic mechanical analyses. The curves of the loss factor tan δ and temperatures from the dynamic mechanical analyses for the NPEOs with high values of C_L showed shoulders or double peaks indicating the existence of the second phase in the polymer networks. In the curves of tan δ for salt‐complexed NPEOs with high values of C_L, silica NPEOs showed a shoulder of low intensity, but organic NPEOs showed a distinguished second peak becoming stronger with increasing C_L. The results of the T_g behavior and tan δ curves suggested that the salt solubility in the NPEOs was limited and that the salt solubility of PEO in the silica NPEOs was higher than that in the organic NPEOs. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 270–277, 2003     

垂直矩形窄缝通道内气液两相流型的研究

本文研究了矩形窄缝通道内气液两相流的流型.用目测和摄影方法得到气液两相向上并流的流型.用x-y函数记录仪测得各种流型下的压差频谱图.作出了以1/X_(tt)～G_t和j_(?)～Re为坐标的流型图.作者还用Lockbart-Martinelli方法计算了矩形通道内气液两相流的压降,并与实测值进行了比较.     

酸、碱及盐对胶乳法氯化天然橡胶热稳定性的影响

采用热老化实验结合紫外光谱分析和热分析，分析了酸、碱及盐对胶乳法氯化天然橡胶(CNR)热稳定性的影响，并讨论了酸、碱及盐对CNR热降解的影响机理。研究结果表明：胶乳法CNR产品中含有酸、碱、盐时，对CNR的结构有不利的影响，其影响随含量增高而增大，其中又以碱对结构的不利影响最大。因此，在胶乳法生产CNR的生产工艺中，最后的酸碱中和、洗涤2道工序必须严格控制工艺条件，保证半成品的pH值和含盐量达到标准。